300 工程科学学报，第42卷，第3期 radioactive metal ions.Chem Soc Rev,2018,47:2322 removal of heavy metal ions from aqueous solution.Chem [27]Liu C,Yu L Q,Zhao Y T,et al.Recent advances in metal-organic Commun,2016,52:2831 frameworks for adsorption of common aromatic pollutants. [43]Zhang J,Xiong Z,Li C,et al.Exploring a thiol-functionalized Mikrochim Acta,2018,185:342 MOF for elimination of lead and cadmium from aqueous solution. [28]Ayati A,Shahrak M N,Tanhaei B,et al.Emerging adsorptive J Mol Liq,.2016,221:43 removal of azo dye by metal-organic frameworks.Chemosphere, [44]Rahimi E,Mohaghegh N.Removal of toxic metal ions from 2016,160:30 Sungun acid rock drainage using mordenite zeolite,graphene [29]Qiu J,Zhang X,Feng Y,et al.Modified metal-organic frameworks nanosheets,and a novel metal-organic framework.Mine Water as photocatalysts.Appl Catal B-Emviron,018,231:317 Environ,2016,35(1):18 [30]Peterson G W,Mahle J J,DeCoste J B,et al.Extraordinary NO2 [45]Tahmasebi E,Masoomi M Y,Yamini Y,et al.Application of removal by the metal-organic framework UiO-66-NH2.Angew mechanosynthesized azine-decorated zinc(II)metal-organic Chem1mEd,2016,55(21上：6235 frameworks for highly efficient removal and extraction of some [31]Jun B M,Kim S,Kim Y,et al.Comprehensive evaluation on heavy-metal ions from aqueous samples:a comparative study removal of lead by graphene oxide and metal organic framework. Inorg Chem,2014,54(2上：425 Chemosphere,2019,231:82 [46]Yuan G Y,Tian Y,Liu J,et al.Schiff base anchored on metal- [32]Huang Y,Zeng X F.Guo L L,et al.Heavy metal ion removal of organic framework for Co(ll)removal from aqueous solution. wastewater by zeolite-imidazolate frameworks.Sep Purif Technol, Chem Eng J,2017,326:691 2018,194:462 [47]Cheng X Q,Liu M,Zhang A F,et al.Size-controlled silver [33]Lee Y C,Yang J W.Self-assembled flower-like TiO,on exfoliated nanoparticles stabilized on thiol-functionalized MIL-53(Al) graphite oxide for heavy metal removal.J Ind Eng Chem,2012, frameworks.Nanoscale,2015,7(21):9738 18(3:1178 [48]Conde-Gonzalez J E,Pena-Mendez E M,Rybakova S,et al. [34]Tofighy M A,Mohammadi T.Adsorption of divalent heavy metal Adsorption of silver nanoparticles from aqueous solution on ions from water using carbon nanotube sheets.J Hazard Mater, copper-based metal organic frameworks (HKUST-1). 2011,185(1):140 Chemosphere,2016,150:659 [35]Luo X B.Ding L.Luo J M.Adsorptive removal of Pb(II)ions [49]Asgari P,Mousavi S H,Aghayan H,et al.Nd-BTC metal-organic from aqueous samples with amino-functionalization of metal- framework(MOF),synthesis,characterization and investigation on organic frameworks MIL-101(Cr).J Chem Eng Data,2015, its adsorption behavior toward cesium and strontium ions 60(6):1732 icrochem,J2019,150:104188 [36]Wang K,Gu J W,Yin N.Efficient removal of Pb(II)and Cd(II) [50]Pournara A D,Margariti A,Tarlas G D,et al.A Ca MOF using NH2-functionalized Zr-MOFs via rapid microwave- combining highly efficient sorption and capability for promoted synthesis.Ind Eng Chem Res,2017,56(7):880 voltammetric determination of heavy metal ions in aqueous media. [37]Yu C X,Shao Z C,Hou H W.A functionalized metal-organic J Mater Chem A,2019,7(25):15432 framework decorated with O groups showing excellent [51]Liu T,Che J X,Hu Y Z,et al.Alkenyl/thiol-derived metalorganic performance for lead(II)removal from aqueous solution.Chem frameworks (MOFs)by means of postsynthetic modification for Sci,2017,8:7611 effective mercury adsorption.Chem EurJ,2014,20(43):14090 [38]Wang Y,Ye G Q,Chen HH,et al.Functionalized metal-organic [52]Saleem H,Rafique U,Davies R P.Investigations on post- framework as a new platform for efficient and selective removal of synthetically modified UiO-66-NH,for the adsorptive removal of cadmium (II)from aqueous solution.J Mater Chem A,2015, heavy metal ions from aqueous solution.Microporous Mesoporous 3(29):15292 Maer,2016,221:238 [39]Zou F,Yu R H,Li R G,et al.Microwave-assisted synthesis of [53]Luo F,Chen JL,Dang LL,et al.High-performance Hg"*removal HKUST-1 and functionalized HKUST-1-@HPW2O:Selective from ultra-low-concentration aqueous solution using both adsorption of heavy metal ions in water analyzed with synchrotron acylamide-and hydroxyl-functionalized metal-organic framework. radiation.ChemPhysChem,2013,14(12):2825 J Mater Chem A,2015,3(18):9616 [40]Yin N,Wang K,Xia Y A,et al.Novel melamine modified metal- [54]Yee KK,Reimer N,Liu J,et al.Effective mercury sorption by organic frameworks for remarkably high removal of heavy meta thiol-laced metal-organic frameworks:in strong acid and the vapor Pb(II).Desalination,2018,430:120 phase.JAm Chem Soc,2013,135(21):7795 [41]Lei C,Gao J,Ren W,et al.Fabrication of metal-organic [55]Luo X B,Shen TT,Ding L,et al.Novel thymine-functionalized frameworks@cellulose aerogels composite materials for removal MIL-101 prepared by post-synthesis and enhanced removal of of heavy metal ions in water.Carbohydr Polym,2019,205:35 Hg"*from water.J Hazard Mater,2016,306:313 [42]Chakraborty A,Bhattacharyya S,Hazra A,et al.Post-synthetic [56]Song HX,Liu Y G,Xu W H,et al.Simultaneous Cr(VI)reduction metalation in an anionic MOF for efficient catalytic activity and and phenol degradation in pure cultures of Pseudomonasradioactive metal ions. Chem Soc Rev, 2018, 47: 2322 Liu C, Yu L Q, Zhao Y T, et al. Recent advances in metal-organic frameworks  for  adsorption  of  common  aromatic  pollutants. Mikrochim Acta, 2018, 185: 342 [27] Ayati  A,  Shahrak  M  N,  Tanhaei  B,  et  al.  Emerging  adsorptive removal  of  azo  dye  by  metal-organic  frameworks. Chemosphere, 2016, 160: 30 [28] Qiu J, Zhang X, Feng Y, et al. Modified metal-organic frameworks as photocatalysts. Appl Catal B-Environ, 2018, 231: 317 [29] Peterson G W, Mahle J J, DeCoste J B, et al. Extraordinary NO2 removal  by  the  metal-organic  framework  UiO-66-NH2 . Angew Chem Int Ed, 2016, 55（21）: 6235 [30] Jun  B  M,  Kim  S,  Kim  Y,  et  al.  Comprehensive  evaluation  on removal of lead by graphene oxide and metal organic framework. Chemosphere, 2019, 231: 82 [31] Huang Y, Zeng X F, Guo L L, et al. Heavy metal ion removal of wastewater by zeolite-imidazolate frameworks. Sep Purif Technol, 2018, 194: 462 [32] Lee Y C, Yang J W. Self-assembled flower-like TiO2 on exfoliated graphite  oxide  for  heavy  metal  removal. J Ind Eng Chem,  2012, 18（3）: 1178 [33] Tofighy M A, Mohammadi T. Adsorption of divalent heavy metal ions  from  water  using  carbon  nanotube  sheets. J Hazard Mater, 2011, 185（1）: 140 [34] Luo  X  B,  Ding  L,  Luo  J  M.  Adsorptive  removal  of  Pb(II)  ions from  aqueous  samples  with  amino-functionalization  of  metal￾organic  frameworks  MIL-101(Cr). J Chem Eng Data,  2015, 60（6）: 1732 [35] Wang K, Gu J W, Yin N. Efficient removal of Pb(II) and Cd(II) using  NH2 -functionalized  Zr-MOFs via rapid  microwave￾promoted synthesis. Ind Eng Chem Res, 2017, 56（7）: 880 [36] Yu  C  X,  Shao  Z  C,  Hou  H  W.  A  functionalized  metal-organic framework  decorated  with  O− groups  showing  excellent performance  for  lead(II)  removal  from  aqueous  solution. Chem Sci, 2017, 8: 7611 [37] Wang Y, Ye G Q, Chen H H, et al. Functionalized metal-organic framework as a new platform for efficient and selective removal of cadmium  (II)  from  aqueous  solution. J Mater Chem A,  2015, 3（29）: 15292 [38] Zou  F,  Yu  R  H,  Li  R  G,  et  al.  Microwave-assisted  synthesis  of HKUST-1  and  functionalized  HKUST-1-@H3PW12O40:  Selective adsorption of heavy metal ions in water analyzed with synchrotron radiation. ChemPhysChem, 2013, 14（12）: 2825 [39] Yin N, Wang K, Xia Y A, et al. Novel melamine modified metal￾organic frameworks for remarkably high removal of heavy metal Pb(II). Desalination, 2018, 430: 120 [40] Lei  C,  Gao  J,  Ren  W,  et  al.  Fabrication  of  metal-organic frameworks@cellulose  aerogels  composite  materials  for  removal of heavy metal ions in water. Carbohydr Polym, 2019, 205: 35 [41] Chakraborty  A,  Bhattacharyya  S,  Hazra  A,  et  al.  Post-synthetic metalation  in  an  anionic  MOF  for  efficient  catalytic  activity  and [42] removal  of  heavy  metal  ions  from  aqueous  solution. Chem Commun, 2016, 52: 2831 Zhang  J,  Xiong  Z,  Li  C,  et  al.  Exploring  a  thiol-functionalized MOF for elimination of lead and cadmium from aqueous solution. J Mol Liq, 2016, 221: 43 [43] Rahimi  E,  Mohaghegh  N.  Removal  of  toxic  metal  ions  from Sungun  acid  rock  drainage  using  mordenite  zeolite,  graphene nanosheets,  and  a  novel  metal-organic  framework. Mine Water Environ, 2016, 35（1）: 18 [44] Tahmasebi  E,  Masoomi  M  Y,  Yamini  Y,  et  al.  Application  of mechanosynthesized  azine-decorated  zinc(II)  metal-organic frameworks  for  highly  efficient  removal  and  extraction  of  some heavy-metal  ions  from  aqueous  samples:  a  comparative  study. Inorg Chem, 2014, 54（2）: 425 [45] Yuan  G  Y,  Tian  Y,  Liu  J,  et  al.  Schiff  base  anchored  on  metal￾organic  framework  for  Co(II)  removal  from  aqueous  solution. Chem Eng J, 2017, 326: 691 [46] Cheng  X  Q,  Liu  M,  Zhang  A  F,  et  al.  Size-controlled  silver nanoparticles  stabilized  on  thiol-functionalized  MIL-53(Al) frameworks. Nanoscale, 2015, 7（21）: 9738 [47] Conde-González  J  E,  Peña-Méndez  E  M,  Rybáková  S,  et  al. Adsorption  of  silver  nanoparticles  from  aqueous  solution  on copper-based  metal  organic  frameworks  (HKUST-1). Chemosphere, 2016, 150: 659 [48] Asgari P, Mousavi S H, Aghayan H, et al. Nd-BTC metal-organic framework (MOF); synthesis, characterization and investigation on its  adsorption  behavior  toward  cesium  and  strontium  ions. Microchem J, 2019, 150: 104188 [49] Pournara  A  D,  Margariti  A,  Tarlas  G  D,  et  al.  A  Ca2+ MOF combining  highly  efficient  sorption  and  capability  for voltammetric determination of heavy metal ions in aqueous media. J Mater Chem A, 2019, 7（25）: 15432 [50] Liu T, Che J X, Hu Y Z, et al. Alkenyl/thiol-derived metalorganic frameworks  (MOFs)  by  means  of  postsynthetic  modification  for effective mercury adsorption. Chem Eur J, 2014, 20（43）: 14090 [51] Saleem  H,  Rafique  U,  Davies  R  P.  Investigations  on  post￾synthetically modified UiO-66-NH2 for the adsorptive removal of heavy metal ions from aqueous solution. Microporous Mesoporous Mater, 2016, 221: 238 [52] Luo F, Chen J L, Dang L L, et al. High-performance Hg2+ removal from  ultra-low-concentration  aqueous  solution  using  both acylamide- and hydroxyl-functionalized metal-organic framework. J Mater Chem A, 2015, 3（18）: 9616 [53] Yee  K  K,  Reimer  N,  Liu  J,  et  al.  Effective  mercury  sorption  by thiol-laced metal-organic frameworks: in strong acid and the vapor phase. J Am Chem Soc, 2013, 135（21）: 7795 [54] Luo X B, Shen T T, Ding L, et al. Novel thymine-functionalized MIL-101  prepared  by  post-synthesis  and  enhanced  removal  of Hg2+ from water. J Hazard Mater, 2016, 306: 313 [55] Song H X, Liu Y G, Xu W H, et al. Simultaneous Cr(VI) reduction and  phenol  degradation  in  pure  cultures  of  Pseudomonas [56] · 300 · 工程科学学报，第 42 卷，第 3 期