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A computa- solvent catalyzed by Ruh, L,[J].Organometallics tional perspective of olefins metathesis catalyzed by NｃｉｅｎｔａｎｄｒｅｃｙｃｌａｂｌｅｍｏｎｏｍｅｒｉｃａｎｄｄｅｎｄｒｉｔｉｃＲｕｂａｓｅｄ ｍｅｔａｔｈｅｓｉｓｃａｔａｌｙｓｔｓ［Ｊ］．Ｊ．Ａｍ．Ｃｈｅｍ．Ｓｏｃ．，２０００， １２２（３４）：８１６８－８１７９ ［１６］ ＳｔｅｐｈｅｎｓｏｎＴＡ，ＷｉｌｋｉｎｓｏｎＧ．Ｎｅｗｃｏｍｐｌｅｘｅｓｏｆｒｕｔｈｅｎｉ ｕｍ（ＩＩ）ａｎｄ（ＩＩＩ）ｗｉｔｈｔｒｉｐｈｅｎｙｌｐｈｏｓｐｈｉｎｅ，ｔｒｉｐｈｅｎｙ ｌａｒｓｉｎｅ， ｔｒｉｃｈｌｏｒｏｓｔａｎｎａｔｅ， ｐｙｒｉｄｉｎｅａｎｄ ｏｔｈｅｒｌｉｇａｎｄｓ ［Ｊ］．Ｊ．Ｉｎｏｒｇ．Ｎｕｃｌ．Ｃｈｅｍ．，１９６６，２８：９４５－９５６ ［１７］ ＨａｌｌｍａｎＰＳ，ＳｔｅｐｈｅｎｓｏｎＴＡ，ＷｉｌｋｉｎｓｏｎＧ．Ｔｅｔｒａｋｉｓ （Ｔｒｉｐｈｅｎｙｌｐｈｏｓｐｈｉｎｅ）ＤｉｃｈｌｏｒｏＲｕｔｈｅｎｉｕｍ（ＩＩ）ａｎｄＴｒｉｓ （Ｔｒｉｐｈｅｎｙｌｐｈｏｓｐｈｉｎｅ）Ｄｉｃｈｌｏｒｏｒｕｔｈｅｎｉｕｍ（ＩＩ）［Ｊ］．Ｉｎ ｏｒｇ．Ｓｙｎｔｈ．，１９７０，１２：２３７－２４０ ［１８］ ＹａｔｅｓＰ，ＳｈａｐｉｒｏＢＬ．Ｐｒｅｐａｒａｔｉｏｎｏｆｐｈｅｎｙｌｄｉａｚｏｍｅｔｈａｎｅ ［Ｊ］．Ｊ．Ｏｒｇ．Ｃｈｅｍ．，１９５８，２３：７５９－７６０ ［１９］ ＣｌｏｓｓＧＬ，ＭｏｓｓＲＡ．Ｃａｒｂｅｎｏｉｄｆｏｒｍａｔｉｏｎｏｆａｒｙｌｃｙｃｌｏ ｐｒｏｐａｎｅｓｆｒｏｍｏｌｅｆｉｎｓ，ｂｅｎｚａｌｂｒｏｍｉｄｅｓ，ａｎｄｏｒｇａｎｏｌｉｔｈｉ ｕｍｃｏｍｐｏｕｎｄｓａｎｄｆｒｏｍｐｈｏｔｏｌｙｓｉｓｏｆａｒｙｌｄｉａｚｏｍｅｔｈａｎｅｓ ［Ｊ］．Ｊ．Ａｍ．Ｃｈｅｍ．Ｓｏｃ．，１９６４，８６：４０４２－４０５３ ［２０］ ＭｉｚｏｂｅＹ，ＩｓｈｉｉＹ，ＨｉｄａｉＭ．Ｓｙｎｔｈｅｓｉｓａｎｄｒｅａｃｔｉｖｉｔｉｅｓｏｆ ｄｉａｚｏａｌｋａｎｅｃｏｍｐｌｅｘｅｓ［Ｊ］．Ｃｏｏｒｄ．Ｃｈｅｍ．Ｒｅｖ．，１９９５， １３９：２８１－３１１ ［２１］ ＤａｒｔｉｇｕｅｎａｖｅＭ，ＭｅｎｕＭ Ｊ，ＤｅｙｄｉｅｒＥ，ｅｔａｌ．Ｃｒｙｓｔａｌ ａｎｄｍｏｌｅｃｕｌａｒｓｔｒｕｃｔｕｒｅｓｏｆｔｒａｎｓｉｔｉｏｎｍｅｔａｌｃｏｍｐｌｅｘｅｓ ｗｉｔｈＮａｎｄＣｂｏｎｄｅｄｄｉａｚｏａｌｋａｎｅｌｉｇａｎｄｓ［Ｊ］．Ｃｏｏｒｄ． Ｃｈｅｍ．Ｒｅｖ．，１９９８，１７８１８０：６２３－６６３ ［２２］ ＢｅｌｄｅｒｒａｉｎＴＲ，ＧｒｕｂｂｓＲＨ．Ｒｅａｃｔｉｏｎｂｅｔｗｅｅｎｒｕｔｈｅｎｉ ｕｍ（０）ｃｏｍｐｌｅｘｅｓａｎｄｄｉｈａｌｏｃｏｍｐｏｕｎｄｓ．Ａｎｅｗｍｅｔｈｏｄ ｆｏｒｔｈｅｓｙｎｔｈｅｓｉｓｏｆｒｕｔｈｅｎｉｕｍｏｌｅｆｉｎｍｅｔａｔｈｅｓｉｓｃａｔａｌｙｓｔｓ ［Ｊ］．Ｏｒｇａｎｏｍｅｔａｌｌｉｃｓ，１９９７，１６：４００１－４００３ ［２３］ ＩｔｏｈＫ，ＮａｇａｓｈｉｍａＨ，ＯｈｓｈｉｍａＴ，ｅｔａｌ．Ｂｉｓ（１３：５６η ｃｙｃｌｏｏｃｔａｄｉｅｎｙｌ）ｒｕｔｈｅｎｉｕｍ：ｐｒｅｐａｒａｔｉｏｎ，ＮＭＲｓｐｅｃｔｒｏｓ ｃｏｐｙ，ａｎｄｉｓｏｍｅｒｉｚａｔｉｏｎｔｏ（η６ １，３，５ｃｙｃｌｏｏｃｔａｔｒｉｅｎｅ） （１２：５６η１，５ｃｙｃｌｏｏｃｔａｄｉｅｎｅ）ｒｕｔｈｅｎｉｕｍｖｉａｔｈｅａｃｔｉ ｖａｔｉｏｎｏｆａＣＨ ｂｏｎｄ［Ｊ］．Ｊ．Ｏｒｇａｎｏｍｅｔ．Ｃｈｅｍ．， １９８４，２７２：１７９－１８８ ［２４］ ＦｒｏｓｉｎＫＭ，ＤａｈｌｅｎｂｕｒｇＬ．Ｔｈｅｒｅｄｕｃｔｉｏｎｏｆｈｙｄｒａｔｅｄｒｕ ｔｈｅｎｉｕｍ（ＩＩＩ）ｃｈｌｏｒｉｄｅｗｉｔｈｚｉｎｃｉｎｔｈｅｐｒｅｓｅｎｃｅｏｆｃｙ ｃｌｏｏｃｔａｄｉｅｎｅ：ｍｏｌｅｃｕｌａｒｓｔｒｕｃｔｕｒｅｏｆＲｕ（Ｃ８Ｈ１０）（Ｃ８Ｈ１２） ａｎｄｉｓｏｌａｔｉｏｎ ａｎｄ ｘｒａｙ ｓｔｒｕｃｔｕｒａｌｃｈａｒａｃｔｅｒｉｚａｔｉｏｎ ｏｆ Ｒｕ２Ｃｌ４（Ｃ８Ｈ１２）２，ＲｕＨ（Ｃ８Ｈ１１）（Ｃ６Ｈ６） ａｎｄＲｕ３Ｃｌ３ （ＯＣＨ３）（Ｃ８Ｈ１２）３［Ｊ］．Ｉｎｏｒｇ．Ｃｈｉｍ．Ａｃｔａ．，１９９０， １６７：８３－８９ ［２５］ ＣｈａｕｄｒｅｔＢ，ＰｏｉｌｂｌａｎｃＲ．Ｐｒｅｐａｒａｔｉｏｎｏｆｐｏｌｙｈｙｄｒｉｄｅ ｃｏｍｐｌｅｘｅｓｏｆｒｕｔｈｅｎｉｕｍｂｙｄｉｒｅｃｔｈｙｄｒｏｇｅｎａｔｉｏｎｏｆｚｅｒｏ ｖａｌｅｎｔｏｌｅｆｉｎｉｃｄｅｒｉｖａｔｉｖｅｓ．ｍｏｎｏｎｕｃｌｅａｒｃｏｍｐｌｅｘｅｓｏｆｔｈｅ ｔｙｐｅＲｕＨ６Ｌ２ ａｎｄＲｕＨ４Ｌ３．ｓｐｏｎｔａｎｅｏｕｓｈｙｄｒｏｇｅｎｄｅｕｔｅ ｒｉｕｍ ｅｘｃｈａｎｇｅｂｅｔｗｅｅｎｔｈｅｐｈｏｓｐｈｉｎｅｐｒｏｔｏｎｓａｎｄｔｈｅ ｓｏｌｖｅｎｔｃａｔａｌｙｚｅｄ ｂｙ ＲｕＨ４Ｌ３ ［Ｊ］． Ｏｒｇａｎｏｍｅｔａｌｌｉｃｓ， １９８５，４（１０）：１７２２－１７２６ ［２６］ ＧｒüｎｗａｌｄＣ，ＧｅｖｅｒｔＯ，ＷｏｌｆＪ，ｅｔａｌ．Ｆｉｖｅｃｏｏｒｄｉｎａｔｅ １６ｅｌｅｃｔｒｏｎｃａｒｂｅｎｅａｎｄｖｉｎｙｌｉｄｅｎｅｒｕｔｈｅｎｉｕｍ（ＩＩ）ｃｏｍ ｐｌｅｘｅｓｐｒｅｐａｒｅｄｆｒｏｍ［ＲｕＣｌ２（Ｃ８Ｈ１２）］ｎｏｒｆｒｏｍｔｈｅｎｅｗ ｄｉｈｙｄｒｉｄｏｒｕｔｈｅｎｉｕｍ（ＩＶ）ｃｏｍｐｏｕｎｄ［ＲｕＨ２Ｃｌ２（Ｐｉ Ｐｒ３）２］ ［Ｊ］．Ｏｒｇａｎｏｍｅｔａｌｌｉｃｓ，１９９６，１５（８）：１９６０－１９６２ ［２７］ ＷｉｌｈｅｌｍＴＥ，ＢｅｌｄｅｒｒａｉｎＴＲ，ＧｒｕｂｂｓＲＨ．Ｒｅａｃｔｉｖｉｔｙｏｆ Ｒｕ（Ｈ）（Ｈ２）Ｃｌ（ＰＣｙ３）２ ｗｉｔｈｐｒｏｐａｒｇｙｌａｎｄｖｉｎｙｌｃｈｌｏ ｒｉｄｅｓ：Ｎｅｗｍｅｔｈｏｄｏｌｏｇｙｔｏｇｉｖｅｍｅｔａｔｈｅｓｉｓａｃｔｉｖｅｒｕｔｈｅｎｉ ｕｍ ｃａｒｂｅｎｅｓ［Ｊ］．Ｏｒｇａｎｏｍｅｔａｌｌｉｃｓ，１９９７，１６（１８）： ３８６７－３８６９ ［２８］ ＷｏｌｆＪ，ＳｔüｅｒＷ，ＳｃｈｕｌｚＭ，ｅｔａｌ．Ｒｕｔｈｅｎｉｕｍ ｔｒｉｃｈｌｏ ｒｉｄｅ，ｔｒｉｃｙｃｌｏｈｅｘｙｌｐｈｏｓｐｈａｎｅ，１ａｌｋｙｎｅｓ，ｍａｇｎｅｓｉｕｍ， ｈｙｄｒｏｇｅｎ，ａｎｄｗａｔｅｒＩｎｇｒｅｄｉｅｎｔｓｏｆａｎｅｆｆｉｃｉｅｎｔｏｎｅｐｏｔ ｓｙｎｔｈｅｓｉｓｏｆｒｕｔｈｅｎｉｕｍ ｃａｔａｌｙｓｔｓｆｏｒｏｌｅｆｉｎ ｍｅｔａｔｈｅｓｉｓ ［Ｊ］．Ａｎｇｅｗ．Ｃｈｅｍ．Ｉｎｔ．Ｅｄ．，１９９８，３７（８）：１１２４－ １１２６ ［２９］ ｖａｎｄｅｒＳｃｈａａｆＰＡ，ＫｏｌｌｙＲ，ＨａｆｎｅｒＡ．Ａ１４ｅｌｅｃｔｒｏｎ ｒｕｔｈｅｎｉｕｍｈｙｄｒｉｄｅ：ｔｈｅｋｅｙｉｎｔｅｒｍｅｄｉａｔｅｉｎｔｈｅｓｙｎｔｈｅｓｉｓ ｏｆｒｕｔｈｅｎｉｕｍｃａｒｂｅｎｅｃｏｍｐｌｅｘｅｓ；Ｘｒａｙｓｔｒｕｃｔｕｒｅｏｆ［Ｒｕ ＨＣｌ（ＰＰｒｉ ３）２］［Ｊ］．Ｃｈｅｍ．Ｃｏｍｍｕｎ．，２０００，１０４５－ １０４６ ［３０］ ＧａｎｄｅｌｍａｎＭ，ＲｙｂｔｃｈｉｎｓｋｉＢ，ＭｉｌｓｔｅｉｎＤ，ｅｔａｌ．Ａｎｅｗ ｇｅｎｅｒａｌｍｅｔｈｏｄｆｏｒｔｈｅｐｒｅｐａｒａｔｉｏｎｏｆｍｅｔａｌｃａｒｂｅｎｅｃｏｍ ｐｌｅｘｅｓ［Ｊ］．Ｊ．Ａｍ．Ｃｈｅｍ．Ｓｏｃ．，２００１，１２３：５３７２－ ５３７３ ［３１］ ＧａｎｄｅｌｍａｎＭ，ＮａｉｎｇＫＭ，ＭｉｌｓｔｅｉｎＤ，ｅｔａｌ．Ａｇｅｎｅｒａｌ ｍｅｔｈｏｄｆｏｒｐｒｅｐａｒａｔｉｏｎｏｆｍｅｔａｌｃａｒｂｅｎｅｓｖｉａｓｏｌｕｔｉｏｎａｎｄ ｐｏｌｙｍｅｒｂａｓｅｄａｐｐｒｏａｃｈｅｓ［Ｊ］．Ｊ．Ａｍ．Ｃｈｅｍ．Ｓｏｃ．， ２００５，１２７：１５２６５－１５２７２ ［３２］ ＰｏｖｅｒｅｎｏｖＥ，ＤａｖｉｄＭ．Ｆｏｒｍａｔｉｏｎｏｆｔｒａｎｓｉｔｉｏｎｍｅｔａｌ ｃａｒｂｅｎｅｓｕｓｉｎｇｈａｌｏａｌｋｙｌｚｉｎｃｒｅａｇｅｎｔｓ［Ｊ］．Ｃｈｅｍ．Ｃｏｍ ｍｕｎ．，２００７，３１８９－３１９１ ［３３］ ＤｏｒｔａＲ，ＫｅｌｌｙＩＩＩＲＡ，ＮｏｌａｎＳＰ．Ｃｒｏｓｓｍｅｔａｔｈｅｓｉｓａｌ ｌｏｗｉｎｇｔｈｅｃｏｎｖｅｒｓｉｏｎｏｆａｒｕｔｈｅｎｉｕｍ ｉｎｄｅｎｙｌｉｄｅｎｅｃｏｍ ｐｌｅｘｉｎｔｏＧｒｕｂｂｓ＇Ｃａｔａｌｙｓｔ［Ｊ］．Ａｄｖ．Ｓｙｎｔｈ．Ｃａｔａｌ．， ２００４，３４６（８）：９１７－９２０ ［３４］ ＢｅｎｈａｍｏｕＬ，ＣｈａｒｄｏｎＥ，ＣéｓａｒＶ，ｅｔａｌ．Ｓｙｎｔｈｅｔｉｃ ｒｏｕｔｅｓｔｏＮｈｅｔｅｒｏｃｙｃｌｉｃｃａｒｂｅｎｅｐｒｅｃｕｒｓｏｒｓ［Ｊ］．Ｃｈｅｍ． Ｒｅｖ．，２０１１，１１１（４）：２７０５－２７３３ ［３５］ ＪｉａｎｇＬａｎ（姜 岚），ＬｉＺｈｅｎｇｎｉｎｇ（李争宁），ＺｈａｏＤｅ ｆｅｎｇ（赵德峰）．ＳｙｎｔｈｅｓｉｓｏｆＮｈｅｔｅｒｏｃｙｃｌｉｃｃａｒｂｅｎｅｓａｎｄ ｍｅｔａｌｃｏｍｐｌｅｘｅｓ（Ｎ杂环卡宾及其金属络合物的合 成）［Ｊ］．ＰｒｏｇｒｅｓｓｉｎＣｈｅｍｉｓｔｒｙ（化学进展），２００９，６ （２１）：１２２９－１２４０ ［３６］ ＣｒｅｄｅｎｄｉｎｏＲ，ＰｏａｔｅｒＡ，ＣａｖａｌｌｏＬ，ｅｔａｌ．Ａｃｏｍｐｕｔａ ｔｉｏｎａｌｐｅｒｓｐｅｃｔｉｖｅｏｆｏｌｅｆｉｎｓｍｅｔａｔｈｅｓｉｓｃａｔａｌｙｚｅｄｂｙＮ ５７４ 分 子 催 化 第 ２６卷