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.844. 工程科学学报,第41卷,第7期 (吴文远,孙金治,海力,等.氧化钕在氟盐体系中的溶解 Interfacial Electrochem,1974,54(1):25 度.稀土,1991,12(3):34) [39]Castrillejo Y,Bermejo R,Martinez A M,et al.Application of [24]Guo R,Zhai X J.Zhang T A.Dissolution of Sc2O in nNaF. electrochemical techniques in pyrochemical processes-Electro- AlF-LiF molten salt.J Mater Metall,2008,7(4):264 chemical behaviour of rare earths at W,Cd,Bi and Al elec (郭瑞,程秀静,张廷安.氧化钪在冰品石-氟化锂体系中的 trodes.J Nucl Mater,2007,360(1):32 溶解性能.材料与冶金学报,2008,7(4):264) [40]Castrillejo Y,Vega A,Vega M,et al.Electrochemical formation [25]Lu G M,Liu X S.Dissolution of Se,0 in fluoride molten salt. of Se-Al intermetallic compounds in the eutectie LiCl-KCl.De- Chin J Nonferrous Met,1999,9(3):624 termination of thermodynamic properties.Electrochim Acta, (路贵民,刘学山.氧化钪在nNaF·AlF,-ScF,熔盐体系中的 2014.118:58 溶解.中国有色金属学报,1999,9(3):624) [41]Castrillejo Y,Fernandez P,Bermejo M R,et al.Electrochemis- [26]Yang S,Li Q,Gu S Q.Solubility of Se2O3 in nNaF.AlF3-Al2 try of thulium on inert electrodes and electrochemical formation of 0 melts.Chin J Rare Met,2003,27(3):418 a Tm-Al alloy from molten chlorides.Electrochim Acta,2009, (杨昇,李强,顾松青.氧化抗在冰品石-氧化铝体系中的溶 54(26):6212 解性能研究.稀有金属,2003,27(3):418) [42]Castrillejo Y,Fernandez P,Medina J,et al.Electrochemical ex- [27]Shen X Q,Shen S Y.The influence of valence and properties of traction of samarium from molten chlorides in pyrochemical rare earth metalls on its solubility in the cryolite-alumina molten processes.Electrochim Acta,2011,56(24):8638 salt.Chin Rare Earths,1990(1):59 [43]Bermejo M R,Barrado E,Martinez A M,et al.Electrodeposi- (沈祥清,沈时英.稀土原料的价态与性质对它在冰品石-氧 tion of Lu on W and Al electrodes:Electrochemical formation of 化铝系熔体中溶解度的影响.稀土,1990(1):59) Lu-Al alloys and oxoacidity reactions of Lu(Ill)in the eutectic [28]Jentoftsen T E,Lorentsen OA,Dewing E W,et al.Solubility of LiCl-KCI.J Electroanal Chem,2008,617(1):85 some transition metal oxides in cryolite-alumina melts:Part II. 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Chem,2005.579(2):343 Forsch Ingenieunwes,1992,58(4):103 [50]Castrillejo Y,Bermejo M R,Barrado E,et al.Electrodeposition [35]Knacke 0,Kubaschewski 0,Hesselmann K.Thermochemical Properties of Inorganic Substances.Forschung im Ingenieurwesen, of Ho and electrochemical formation of Ho-Al alloys from the eu- 1992,58(4):103 tectic LiCl-KCl.J Electrochem Soc,2006,153(10):C713 [36]Barin I,Platzki G.Thermochemical Data of Pure Substances.3rd [51]Zhang Y X.Study on Preparation and Mechanism of Al-Sc and Ed.Weinheim:VCH Verlag,1995 Mg-Li Based Alloys by Electrolysis in Molten Salt Dissertation ] [37]Adzic R,Yeager E,Cahan B D.Optical and electrochemical Harbin:Harbin Engineering University,2011 studies of underpotential deposition of lead on gold evaporated (张艳霞.铝钪与镁锂基合金的熔盐电解制备及机理研究 and single-crystal electrodes.J Electrochem Soc,1974,121(4): [学位论文].哈尔滨:哈尔滨工程大学,2011) 474 [52]Chen HH,Chen B X,Lin L J.Preparing Al-Ti-B-RE medium [38]Kolb D M,Przasnyski M,Gerischer H.Underpotential deposi- alloys by electrolysis.Jiangxi Nonferrous Met,2001.15(4):15 tion of metals and work function differences.J Electroanal Chem (陈辉煌,陈本孝,林立杰.电解法制取铝钛爾中间合金.江工程科学学报,第 41 卷,第 7 期 (吴文远, 孙金治, 海力, 等. 氧化钕在氟盐体系中的溶解 度. 稀土, 1991, 12(3): 34) [24] Guo R, Zhai X J, Zhang T A. Dissolution of Sc2 O3 in nNaF· AlF3 鄄鄄LiF molten salt. J Mater Metall, 2008, 7(4): 264 (郭瑞, 翟秀静, 张廷安. 氧化钪在冰晶石鄄鄄氟化锂体系中的 溶解性能. 材料与冶金学报, 2008, 7(4): 264) [25] Lu G M, Liu X S. Dissolution of Sc2 O3 in fluoride molten salt. Chin J Nonferrous Met, 1999, 9(3): 624 (路贵民, 刘学山. 氧化钪在 nNaF·AlF3 鄄鄄 ScF3 熔盐体系中的 溶解. 中国有色金属学报, 1999, 9(3): 624) [26] Yang S, Li Q, Gu S Q. Solubility of Sc2 O3 in nNaF·AlF3 鄄鄄Al2 O3 melts. Chin J Rare Met, 2003, 27(3): 418 (杨昇, 李强, 顾松青. 氧化钪在冰晶石鄄鄄氧化铝体系中的溶 解性能研究. 稀有金属, 2003, 27(3): 418) [27] Shen X Q, Shen S Y. The influence of valence and properties of rare earth metalls on its solubility in the cryolite鄄alumina molten salt. Chin Rare Earths, 1990(1): 59 (沈祥清, 沈时英. 稀土原料的价态与性质对它在冰晶石鄄鄄氧 化铝系熔体中溶解度的影响. 稀土, 1990(1): 59) [28] Jentoftsen T E, Lorentsen O A, Dewing E W, et al. Solubility of some transition metal oxides in cryolite鄄alumina melts: Part II. Solubility of TiO2 . Metall Mater Trans B, 2002, 33(6): 909 [29] Weill D F. Stability relations in the Al2O3 鄄鄄SiO2 system calculat鄄 ed from solubilities in the Al2O3 鄄鄄Na3AlF6 system. Geochim Cos鄄 mochim Acta, 1966, 30(2): 223 [30] Lorentsen O A, Jentoftsen T E, Dewing E W, et al. The solubil鄄 ity of some transition metal oxides in cryolite鄄alumina melts: Part III. Solubility of CuO and Cu2 O. Metall Mater Trans B, 2007, 38(5): 833 [31] Lemaire G, Hebant P, Picard G S. DFT analysis of interfacial processes occurring in the first steps of electrodeposition of nickel from chloride melt. J Mol Struct, 1997, 419(1鄄3): 1 [32] Zhou Z Y, Wu B, Dou S S, et al. Thermodynamic properties of elements and compounds in Al鄄鄄 Sc binary system from Ab initio calculations based on density functional theory. Metall Mater Trans A, 2014, 45(4): 1720 [33] Ar覦kan N, Charifi Z, Baaziz H, et al. Electronic structure, phase stability, and vibrational properties of Ir鄄based intermetallic compound IrX ( X = Al, Sc, and Ga). J Phys Chem Solids, 2015, 77: 126 [34] Baehr H D. Thermochemical properties of inorganic substances. Forsch Ingenieurwes, 1992, 58(4): 103 [35] Knacke O, Kubaschewski O, Hesselmann K. Thermochemical Properties of Inorganic Substances. Forschung im Ingenieurwesen, 1992, 58(4):103 [36] Barin I, Platzki G. Thermochemical Data of Pure Substances. 3rd Ed. Weinheim: VCH Verlag, 1995 [37] Adzic R, Yeager E, Cahan B D. Optical and electrochemical studies of underpotential deposition of lead on gold evaporated and single鄄crystal electrodes. J Electrochem Soc, 1974, 121(4): 474 [38] Kolb D M, Przasnyski M, Gerischer H. Underpotential deposi鄄 tion of metals and work function differences. J Electroanal Chem Interfacial Electrochem, 1974, 54(1): 25 [39] Castrillejo Y, Bermejo R, Mart侏nez A M, et al. Application of electrochemical techniques in pyrochemical processes鄄Electro鄄 chemical behaviour of rare earths at W, Cd, Bi and Al elec鄄 trodes. J Nucl Mater, 2007, 360(1): 32 [40] Castrillejo Y, Vega A, Vega M, et al. Electrochemical formation of Sc鄄鄄Al intermetallic compounds in the eutectic LiCl鄄鄄KCl. De鄄 termination of thermodynamic properties. Electrochim Acta, 2014, 118: 58 [41] Castrillejo Y, Fern佗ndez P, Bermejo M R, et al. Electrochemis鄄 try of thulium on inert electrodes and electrochemical formation of a Tm鄄鄄 Al alloy from molten chlorides. Electrochim Acta, 2009, 54(26): 6212 [42] Castrillejo Y, Fern佗ndez P, Medina J, et al. Electrochemical ex鄄 traction of samarium from molten chlorides in pyrochemical processes. Electrochim Acta, 2011, 56(24): 8638 [43] Bermejo M R, Barrado E, Martinez A M, et al. Electrodeposi鄄 tion of Lu on W and Al electrodes: Electrochemical formation of Lu鄄鄄Al alloys and oxoacidity reactions of Lu( III) in the eutectic LiCl鄄鄄KCl. J Electroanal Chem, 2008, 617(1): 85 [44] Bermejo M R, Gomez J, Medina J, et al. The electrochemistry of gadolinium in the eutectic LiCl鄄鄄 KCl on W and Al electrodes. J Electroanal Chem, 2006, 588(2): 253 [45] Kononov A, Polyakov E. High鄄temperature electrochemical syn鄄 thesis and properties of intermetallic compounds of the Ni鄄鄄Sc sys鄄 tem. Part 1. Electrochemical behaviour of Sc( III) in chloride鄄 fluoride melts. J Alloys Compd, 1996, 239(2): 103 [46] Liu Q C, Xue J L, Zhu J, et al. Preparing aluminium鄄scandium inter鄄alloys during reduction process in KF鄄鄄AlF3 鄄鄄SC2O3 melts / / TMS 2012 Annual Meeting and Exhibition. Orlando, 2012: 685 [47] Nohira T, Kambara H, Amezawa K, et al. Electrochemical for鄄 mation and phase control of Pr鄄鄄Ni alloys in a molten LiCl鄄鄄KCl鄄鄄 PrCl3 system. J Electrochem Soc, 2005, 152(4): C183 [48] Ji D B, Yan Y D, Zhang M L, et al. Study on electrochemical behavior of La(III) and preparation of Al鄄鄄 La intermetallic com鄄 pound whiskers in chloride melt. J Electrochem Soc, 2016, 163 (2): D1 [49] Castrillejo Y, Bermejo M R, Arocas P D, et al. The electro鄄 chemical behaviour of the Pr(III) / Pr redox system at Bi and Cd liquid electrodes in molten eutectic LiCl鄄鄄 KCl. J Electroanal Chem, 2005, 579(2): 343 [50] Castrillejo Y, Bermejo M R, Barrado E, et al. Electrodeposition of Ho and electrochemical formation of Ho鄄鄄Al alloys from the eu鄄 tectic LiCl鄄鄄KCl. J Electrochem Soc, 2006, 153(10): C713 [51] Zhang Y X. Study on Preparation and Mechanism of Al鄄鄄 Sc and Mg鄄鄄 Li Based Alloys by Electrolysis in Molten Salt [Dissertation]. Harbin: Harbin Engineering University, 2011 (张艳霞. 铝钪与镁锂基合金的熔盐电解制备及机理研究 [学位论文]. 哈尔滨: 哈尔滨工程大学, 2011) [52] Chen H H, Chen B X, Lin L J. Preparing Al鄄鄄Ti鄄鄄B鄄鄄RE medium alloys by electrolysis. Jiangxi Nonferrous Met, 2001, 15(4): 15 (陈辉煌, 陈本孝, 林立杰. 电解法制取铝钛硼中间合金. 江 ·844·
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