第8卷第4期 食品安全质量检测学报 Vol No 4 2017年4月 Journal of Food Safety and Quality Apr,2017 食品及食品包装材料中塑化剂的检测研究进展 陈满英邹旭凤2，刘杏宜1，廖桂福 (1.广东产品质量监督检验研究院，广州510330,2.广东华润顺峰药业有限公司，佛山528300) 摘要：食品和食品包装材料中朝化剂对人体的危去不可小觑。本文主要介绍了食品及食品包装材料中朝化 剂国内外检测标准、样品前处理方法及主要的检测方法。欧盟法规EUDN010/2011相对于以往的2002/门2/EC 对于迁移测试的要求整体趋于严格，生产企业有必要改进生产工艺以应对更新的测试规则。国家现有的标清 中对于食品和食品包装材料中塑化剂有一定的要求，目前最常见的研究大部分为食品和食品包装材料中邻苯 二甲酸砖类化合物。但对于其他类型的期化剂检测结果相对较少议也将是今后食品和食品包装材料中翔化 剂检测研究的一个主要方向 关键词：塑化剂；邻苯二甲酸酯：食品；食品包装材料：检测标准 Research progress on determination of plasticizers in food and food packaging materials CHEN Man-Ying",ZOU Xu-Feng'.LIU Xing-Yi',LIAO Gui-Fu' ABSTRACT:The dangers of plasticizers in food and food packaging materials on human body should not be overlooked.This study mainly testing standards of plasticizers info and food packaging materials sample pretreatment methodsas well as used detectionand analysis methods.The overall requirements fo migration testing in EU regulation No 10/2011 tend to be stricter when compared to the previous 2002/72/EC Improving the production process to meet the updated test rules should be concemed.The existing standards in the country have for in food and food packaging materials.Most com currently exist for phthalateesters in food and food packaging materials but the existing literatures for testing results of other types of plasticizers are relatively rare,which will be a main direction for studying plasticizers in food and food packagine materials in the future. KEY WORDS:plasticizer,phthalates,food,food packaging materials,testing standards 品中超标的添加剂或食品包装袋中的塑化剂易溶出迁移污 1引言 染食品进而对人体造成危害引。造成食品中塑化剂超标的 近年来，食品塑化剂污染事件引起社会高度关注。食 主要原因包括：加人添加剂在在随意性，导致溶剂残留总 基金项日：广东省自然科学基金项目(2015A030310165 on.Inspes n and Quar tc20130K284) 通讯作者：陈满英，博土，高级工程师，主要研究方向为化工和环保行业产品检测和科研标准化。Eml:103427809@q9c0m an-Yng Scotngncr.ungdone ine ns f oy superyn un 110. 21994-2017 China Academic Journal Electronic Publishing House.All rights reserved. http://www.enki.net 第 8 卷 第 4 期 食品安全质量检测学报 Vol. 8 No. 4 2017 年 4 月 Journal of Food Safety and Quality Apr. , 2017 基金项目: 广东省自然科学基金项目(2015A030310165)、国家质检总局科技计划项目(2013QK284) Fund: Supported by Guangdong Provincial Natural Science Foundation Project (2015A030310165) and State Administration of Quality Supervision, Inspection and Quarantine (2013QK284) *通讯作者: 陈满英, 博士, 高级工程师, 主要研究方向为化工和环保行业产品检测和科研标准化。E-mail: 103427809@qq.com *Corresponding author: CHEN Man-Ying, Ph.D, Senior Engineer, Guangdong Testing Institute of Product Quality Supervision, Guangzhou 510330, China. E-mail: 103427809@qq.com 食品及食品包装材料中塑化剂的检测研究进展 陈满英 1*, 邹旭凤 2 , 刘杏宜 1 , 廖桂福 1 (1. 广东产品质量监督检验研究院, 广州 510330; 2. 广东华润顺峰药业有限公司, 佛山 528300) 摘 要: 食品和食品包装材料中塑化剂对人体的危害不可小觑。本文主要介绍了食品及食品包装材料中塑化 剂国内外检测标准、样品前处理方法及主要的检测方法。欧盟法规(EU)No 10/2011 相对于以往的 2002/72/EC 对于迁移测试的要求整体趋于严格, 生产企业有必要改进生产工艺以应对更新的测试规则。国家现有的标准 中对于食品和食品包装材料中塑化剂有一定的要求, 目前最常见的研究大部分为食品和食品包装材料中邻苯 二甲酸酯类化合物, 但对于其他类型的塑化剂检测结果相对较少, 这也将是今后食品和食品包装材料中塑化 剂检测研究的一个主要方向。 关键词: 塑化剂; 邻苯二甲酸酯; 食品; 食品包装材料; 检测标准 Research progress on determination of plasticizers in food and food packaging materials CHEN Man-Ying1*, ZOU Xu-Feng2 , LIU Xing-Yi1 , LIAO Gui-Fu1 (1. Guangdong Testing Institute of Product Quality Supervision, Guangzhou 510330, China; 2. Guangdong CR Shunfeng Pharmaceutical Co., Ltd., Foshan 528300, China) ABSTRACT: The dangers of plasticizers in food and food packaging materials on human body should not be overlooked. This study mainly introduced testing standards of plasticizers in food and food packaging materials, sample pretreatment methods as well as commonly used detection and analysis methods. The overall requirements for migration testing in EU regulation No 10/2011 tend to be stricter when compared to the previous 2002/72/EC. Improving the production process to meet the updated test rules should be concerned. The existing standards in the country have certain requirements for plasticizers in food and food packaging materials. Most common studies currently exist for phthalate esters in food and food packaging materials, but the existing literatures for testing results of other types of plasticizers are relatively rare, which will be a main direction for studying plasticizers in food and food packaging materials in the future. KEY WORDS: plasticizer; phthalates; food; food packaging materials; testing standards 1 引 言 近年来, 食品塑化剂污染事件引起社会高度关注。食 品中超标的添加剂或食品包装袋中的塑化剂易溶出迁移污 染食品进而对人体造成危害[1-3]。造成食品中塑化剂超标的 主要原因包括: 加入添加剂存在随意性, 导致溶剂残留总