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黄秀兵等:钯掺杂a-MO,无溶剂下催化氧化苯甲醇的性能 ·237· 但也应考虑掺杂催化剂对催化反应的转化率和选择 Mater,2010,22(20):5695 性的平衡. 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A polymer supported Cu( II) catalyst for oxidative amidation of benzyl alcohol and substituted amines in TBHP / H2O. Catal Commun, 2018, 104: 71 [7] Hong Y L, Jiang X L, Huang J L, et al. Biosynthesized bimetallic Au鄄鄄Pd nanoparticles supported on TiO2 for solvent鄄free oxidation of benzyl alcohol. ACS Sustainable Chem Eng, 2014, 2(7): 1752 [8] Galvanin F, Sankar M, Cattaneo S, et al. On the development of kinetic models for solvent鄄free benzyl alcohol oxidation over a gold鄄 palladium catalyst. Chem Eng J, 2018, 342: 196 [9] Li T B, Liu F, Tang Y, et al. Maximizing the number of interfa鄄 cial sites in single鄄atom catalysts for the highly selective, solvent鄄 free oxidation of primary alcohols. Angew Chem Int Ed, 2018, 57 (26): 7795 [10] Weerachawanasak P, Hutchings G J, Edwards J K, et al. Sur鄄 face functionalized TiO2 supported Pd catalysts for solvent鄄free se鄄 lective oxidation of benzyl alcohol. Catal Today, 2015, 250: 218 [11] Xin P Y, Li J, Xiong Y, et al. Revealing the active species for aerobic alcohol oxidation by using uniform supported palladium catalysts. Angew Chem Int Ed, 2018, 57(17): 4642 [12] Enache D I, Edwards J K, Landon P, et al. Solvent鄄free oxida鄄 tion of primary alcohols to aldehydes using Au鄄鄄 Pd / TiO2 cata鄄 lysts. Science, 2006, 311(5759): 362 [13] Zhu Y, Zhang S R, Shan J J, et al. In situ surface chemistries and catalytic performances of ceria doped with palladium, plati鄄 num, and rhodium in methane partial oxidation for the production of syngas. ACS Catal, 2013, 3(11): 2627 [14] Jin Z, Nackashi D, Lu W, et al. Decoration, migration, and ag鄄 gregation of palladium nanoparticles on graphene sheets. Chem Mater, 2010, 22(20): 5695 [15] Biswas S, Dutta B, Mullick K, et al. Aerobic oxidation of amines to imines by cesium鄄promoted mesoporous manganese ox鄄 ide. ACS Catal, 2015, 5(7): 4394 [16] Dutta B, Biswas S, Sharma V, et al. Mesoporous manganese ox鄄 ide catalyzed aerobic oxidative coupling of anilines to aromatic azo compounds. Angew Chem Int Ed, 2016, 55(6): 2171 [17] Li Z, Wang L, Yun L, et al. Activity and antitoxic properties of Cr鄄鄄MnOx / TiO2 鄄鄄ZrO2 for low鄄temperature selective catalytic re鄄 duction of NO. Chin J Eng, 2015, 37(8): 1049 (李哲, 汪莉, 贠丽, 等. Cr鄄鄄 MnOx / TiO2 鄄鄄 ZrO2 低温选择催 化还原 NO 的活性及抗毒性能. 工程科学学报, 2015, 37 (8): 1049) [18] Alhumaimess M, Lin Z J, He Q, et al. Oxidation of benzyl alco鄄 hol and carbon monoxide using gold nanoparticles supported on MnO2 nanowire microspheres. Chem Eur J, 2014, 20(6): 1701 [19] Ragupathy P, Park D H, Campet G, et al. Remarkable capacity retention of nanostructured manganese oxide upon cycling as an electrode material for supercapacitor. J Phys Chem C, 2009, 113 (15): 6303 [20] Ousmane M, Perrussel G, Yan Z, et al. Highly selective direct amination of primary alcohols over a Pd / K鄄鄄 OMS鄄鄄 2 catalyst. J Catal, 2014, 309: 439 [21] Hegde M S, Bera P. 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