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·1036 工程科学学报，第43卷，第8期 (郑敏辉，甄秀欣，赵志刚.SCeO3基高温质子导体的制备与性 sensor auxiliary electrodes based on the CaFz-SiOz system.Chin 能测定.北京科技大学学报，1993,15(3)：310) JEng,2016,38(4):476 [5]Zhou Y.Guan X,Zhou H,et al.Strongly correlated perovskite fuel (鞠靓辰，李杨，满文宽，等.CF2一SiO2型硅传感器辅助电极的 cells.Nae,2016,534(7606):231 制备及其定硅性能.工程科技学报，2016,38(4)：476) [6]Bi L.Da'As E H.Shafi S P.Proton-conducting solid oxide fuel cell [16]Zhu Z W,Guo E Y,Wei Z L,et al.Tailoring Ba CaLIsNb1.82O- (SOFC)with Y-doped BaZrO electrolyte.Electrochem Commun, with Nio as electrolyte for proton-conducting solid oxide fuel 2017,80:20 cells.J Power Sources,2018,373:132 [7]Xie D.Ling A.Yan D.et al.A comparative study on the [17]Jaiswal S K,Yoon K J,Son J W,et al.Synthesis and investigation composite cathodes with proton conductor and oxygen ion con- on stability and electrical conductivity of Ti-doped Ba;CaTa ductor for proton-conducting solid oxide fuel cell.Electrochimica Ti,O (0x1.0)complex oxides.J Alloys Compd,2019,775:736 Acta,2020,344:136143 [18]Wang S W.Chen Y.Fang S M.et al.Novel chemically stable [8]Tong Y C,Wang Y,Cui C S,et al.Preparation and characte- BaCa1.1sNb1.82-Y,0-s proton conductor:Improved proton rization of symmetrical protonic ceramic fuel cells as electro- conductivity through tailored cation ordering.Chem Mater,2014, chemical hydrogen pumps.J Power Sources,2020,457:228036 26(6):2021 [9]Ishiyama T,Kishimoto H,Develos-Bagarinao K,et al.Correlation [19]Ananyev M V,Farlenkov A S,Kurumchin E K.Isotopic exchange between dissolved protons in nickel-doped BaZro.Ceo.7Yo. between hydrogen from the gas phase and proton-conducting Ybo.O and its electrical conductive properties.Inorg Chem, oxides:Theory and experiment.Int J Hydrog Energy,2018, 2017,56(19):11876 43(29):13373 [10]Tong Y C,Meng X,Luo T,et al.Protonic ceramic electrochemical [20]Sazinas R,Einarsrud M A,Grande T.Toughening of Y-doped cell for efficient separation of hydrogen.ACS Appl Mater BaZrO3 proton conducting electrolytes by hydration.J Mater Interfaces,2020,12(23):25809 Chem A,2017,5(12:5846 [11]Montaleone D.Mercadelli E.Escolastico S.et al.All-ceramic [21]Bohn H G,Schober T,Mono T,et al.The high temperature proton asymmetric membranes with superior hydrogen permeation.J conductor BaCa1.IsNb1s20-.I.Electrical conductivity.Solid Mater Chem A,2018,6(32):15718 Sate1onic3,1999,117(3-4):219 [12]Morejudo S H,Zanon R,Escolastico S,et al.Direct conversion of [22]Liang K C.Du Y,Nowick A S.Fast high-temperature proton methane to aromatics in a catalytic co-ionic membrane reactor transport in nonstoichiometric mixed perovskites.Solid Stare Science,2016,353(6299):563 1omic3,1994,69(2):117 [13]Li Y,Wang CZ,Zhang Z L,et al.A hydrogen sensor using [23]Ding YS,Li Y,Huang WL.Influence of grain interior and grain SrCeo.95YboosO3 as proton conductor and YH+YH2-as boundaries on transport properties of scandium-doped calcium reference electrode for determining hydrogen pressure in solid zirconate.J Am Ceram Soc,2020,103(4):2653 steel.J Mater Sci Technol,2010,26(10):957 [24]Ding YS,Li Y,Zhang C J,et al.Effect of grain interior and grain [14]Kalyakin A S.Lyagaeva J G,Chuikin A Y,et al.A high- boundaries on transport properties of Sc-doped CaHfO:.JAlloys temperature electrochemical sensor based on CaZro.sSco.osO3- Compd,.2020,834:155126 for humidity analysis in oxidation atmospheres.J Solid State [25]Frade J R.Theoretical behaviour of concentration cells based on Electrochem,2019,23(1):73 ABO;perovskite materials with protonic and oxygen ion [15]Ju L C,L Y,Man W K,et al.Preparation and property of silicon conduction.Solid State lonics,1995,78(1-2):87（郑敏辉, 甄秀欣, 赵志刚. SrCeO3基高温质子导体的制备与性 能测定. 北京科技大学学报, 1993, 15（3）：310） Zhou Y, Guan X, Zhou H, et al. Strongly correlated perovskite fuel cells. Nature, 2016, 534（7606）: 231 [5] Bi L, Da'As E H, Shafi S P. Proton-conducting solid oxide fuel cell (SOFC) with Y-doped BaZrO3 electrolyte. Electrochem Commun, 2017, 80: 20 [6] Xie D, Ling A, Yan D, et al. A comparative study on the composite cathodes with proton conductor and oxygen ion conductor for proton-conducting solid oxide fuel cell. Electrochimica Acta, 2020, 344: 136143 [7] Tong Y C, Wang Y, Cui C S, et al. Preparation and characterization of symmetrical protonic ceramic fuel cells as electrochemical hydrogen pumps. J Power Sources, 2020, 457: 228036 [8] Ishiyama T, Kishimoto H, Develos-Bagarinao K, et al. Correlation between dissolved protons in nickel-doped BaZr0.1Ce0.7Y0.1 Yb0.1O3−δ and its electrical conductive properties. Inorg Chem, 2017, 56（19）: 11876 [9] Tong Y C, Meng X, Luo T, et al. Protonic ceramic electrochemical cell for efficient separation of hydrogen. ACS Appl Mater Interfaces, 2020, 12（23）: 25809 [10] Montaleone D, Mercadelli E, Escolástico S, et al. All-ceramic asymmetric membranes with superior hydrogen permeation. J Mater Chem A, 2018, 6（32）: 15718 [11] Morejudo S H, Zanón R, Escolástico S, et al. Direct conversion of methane to aromatics in a catalytic co-ionic membrane reactor. Science, 2016, 353（6299）: 563 [12] Li Y, Wang C Z, Zhang Z L, et al. A hydrogen sensor using SrCe0.95Yb0.05O3−α as proton conductor and YHx+YH2−z as reference electrode for determining hydrogen pressure in solid steel. J Mater Sci Technol, 2010, 26（10）: 957 [13] Kalyakin A S, Lyagaeva J G, Chuikin A Y, et al. A hightemperature electrochemical sensor based on CaZr0.95Sc0.05O3−δ for humidity analysis in oxidation atmospheres. J Solid State Electrochem, 2019, 23（1）: 73 [14] [15] Ju L C, L Y, Man W K, et al. Preparation and property of silicon sensor auxiliary electrodes based on the CaF2—SiO2 system. Chin J Eng, 2016, 38（4）: 476 （鞠靓辰, 李杨, 满文宽, 等. CaF2—SiO2型硅传感器辅助电极的 制备及其定硅性能. 工程科技学报, 2016, 38（4）：476） Zhu Z W, Guo E Y, Wei Z L, et al. Tailoring Ba3Ca1.18Nb1.82O9−δ with NiO as electrolyte for proton-conducting solid oxide fuel cells. J Power Sources, 2018, 373: 132 [16] Jaiswal S K, Yoon K J, Son J W, et al. Synthesis and investigation on stability and electrical conductivity of Ti-doped Ba3CaTa2−x TixO9 (0≤x≤1.0) complex oxides. J Alloys Compd, 2019, 775: 736 [17] Wang S W, Chen Y, Fang S M, et al. Novel chemically stable Ba3Ca1.18Nb1.82−xYxO9−δ proton conductor: Improved proton conductivity through tailored cation ordering. Chem Mater, 2014, 26（6）: 2021 [18] Ananyev M V, Farlenkov A S, Kurumchin E K. Isotopic exchange between hydrogen from the gas phase and proton-conducting oxides: Theory and experiment. Int J Hydrog Energy, 2018, 43（29）: 13373 [19] Sažinas R, Einarsrud M A, Grande T. Toughening of Y-doped BaZrO3 proton conducting electrolytes by hydration. J Mater Chem A, 2017, 5（12）: 5846 [20] Bohn H G, Schober T, Mono T, et al. The high temperature proton conductor Ba3Ca1.18Nb1.82O9−δ . I. Electrical conductivity. Solid State Ionics, 1999, 117（3-4）: 219 [21] Liang K C, Du Y, Nowick A S. Fast high-temperature proton transport in nonstoichiometric mixed perovskites. Solid State Ionics, 1994, 69（2）: 117 [22] Ding Y S, Li Y, Huang W L. Influence of grain interior and grain boundaries on transport properties of scandium-doped calcium zirconate. J Am Ceram Soc, 2020, 103（4）: 2653 [23] Ding Y S, Li Y, Zhang C J, et al. Effect of grain interior and grain boundaries on transport properties of Sc-doped CaHfO3 . J Alloys Compd, 2020, 834: 155126 [24] Frade J R. Theoretical behaviour of concentration cells based on ABO3 perovskite materials with protonic and oxygen ion conduction. Solid State Ionics, 1995, 78（1-2）: 87 [25] · 1036 · 工程科学学报，第 43 卷，第 8 期