第2期 赵会芳等.热分析技术在芳纶结构性能研究中的应用 [2]刘晓艳,于伟东.芳纶的热光老化降解研究[高科技纤 D A tam r force m icrosco py and in frared spectroscopy studies 维与应用,200530(4):31-36 f the them al degradation of nomex arm i fibers[ J Chem [3]朱诚身.聚合物结构分析[M].北京:科学出版社,2004201 Maer200113(11):4297-4304 [15 V illarRodils Paredes J 1, M art inerA bnso [4] Bmw n J R Enn i B C Them al analys i ofN am ex and Kevhr ning them al analysis w ih other techn iques to monitor the de- bers[ JI Text Res I 1977. 47( 1): 62-66 cam pos itin of pol( m-pheny lene ioph halan ie)[J. J [5] H indeleh A M, Abdo Sh M. Effcts of annealing on the cry sta+ Then Anal Calorim, 2002 70( 1): 37-43 lin ity and m rrmparacrystall ie s ze ofKev hr 49 fibes[ J). Po b-[ 16]LiX G, Huang M R Them al degradation of Kev ar fber by 1989 h gores ht in them ogravimetryI J). JApplPolym Sci 1999 l 6 H indeleh A M, Abdo Sh M. RelatInship betw een crystalline 71(4):565-571 structre and m ech an ral pmp erties in Kevlar49 fares[小}[陆赵情.芳纶1313纤维造纸技术研究及产品开发[D].西 Pok如 m Camm un19893(6):184-186 安:陕西科技大学,2004 [7] Janes D James i Newell. Characterization of stm dural[B8]王宜,胡健,雷以超,等.Noex纸基材料关键技术的分析 changes in term ally enh anced Kevlr29 fber J]. A ppl Polm ]造纸科学与技术,200423(3):33-36 sci20049l:417-424 19]何方,张美云,张素风.热压光对纸基芳纶纤维结构的影响 [8] Perepekin K E, PakshverE A, Andreeva I V. Them al carae J.陕西科技大学学报,200826(1):34-37 tristis of h strength and hem stable am at i fibres[ JI[]储长流,李龙,张茂林.PP及芳纶/PP结品性能的分析研究 F bre Chen 210537(5346-35 [.纤维复合材料,2003(1):24-26 [9郯志清,钱咸彧,吴小红,等.芳纶1313的结构与性能[J[21]曾翠霞,顾平.芳纶1313混纺织物耐热性能的测试研究 合成纤维工业,199B16(6):18-21 ]上海纺织科技,200937(3):47-48 ⑩o赵稼祥.美国Kla布性能测试分析[J.纤维复合材料,[2 Kunugil. W tanabe H. H ashmob M. Dynam ie m echan ial 199411(2):32-39 pmperties of pol( p-pheny leneere ph thalm ie)fber J1. J I ll Yang W, Yu H, Zhu M E. Pol(m -pheny bne iopb A ppI Obm Sci197924(4:103-1051 halm ie)uhrafne fibers from an in ic liuid sautin by dry [33 ] Rao Y. W addon A I Famis R I Stmcture poperty reltion jew eteleetmsp inn ing[ J]. J M acrm ol Sci Phys 2006 45 po b( p-pheny bne terephthalm ile)(PPTA )fber[ J]. Polr (4):573-579 [12]何方,张美云,张素风.纸基芳纶纤维结构与热裂解性能研24RaoY. W A I FarisR I The evoh tin of struct re and 究[小中华纸业,200829(18):25-28 pmperties in pol( p-pheny lenetereph thalm ile) fber[ JH I 13] V illarRodil s M artinerA hns A, Tascon JM I Std ies on Po加mer200142(13):5925-5935 pymlysis ofN amex po karam i fibers[ JL J Anal Appl Pyoly 25) Ro jtaczer S Cohn D, M amm G. Them al ex pans in ofk evlar A is200L58(59):105-115 bers and cm posites[ J]. J Mater Sci Lett 1985 194(10 [14 V ilbrRodils Paredes J I M ar neaA bnso A, Tasoon JM 1233-1236 App lication of therm al ana lysis techniques in aram id fber structure and properties research Zhao h u ifang, Zhang M eiyun, Zhang Su feng (1 College of Pub and Per Engineer ig. Shaanxi University of Science& Technology, A 710021: 2 Zhejiang University f Science and Technology, H angzhou 310023) Abstract The appliation of them al ana lys is techn iques in he aram il fiber struc ure and properties research was itroduced inc hiding hem al grav im etric analysis d ifferential them al analyss dynam i than al analys s them am echanical ana lys is Itw as pointed out hat for the pupose of offering the strategy i them aterial design structure and properties lesearch of aram i fb nd the deve bpm ent and appliation of aram i fber products he them al properties research of aram i fber shou H attach m ore attentin to he com b ned appliatin of themal analys is techniques and other stucture ana ls s techn iues, the exploratin of the crys ta l ne stncture and the legu lar ity ofm olecular chain m ovem ent n amorphous area he relat ionsh ip between he structure of aram il fber and the perfm ance of arm i fber products i China Key words them al analys is technique aram i fber stucture propert poduct developm ent application o1994-2013ChinaAcademicJournalElectronicPublishingHouse.Allrightsreservedhttp://www.cnki.net[ 2] 刘晓艳,于伟东. 芳纶的热光老化降解研究 [ J]. 高科技纤 维与应用, 2005, 30 ( 4): 31 - 36. [ 3 ] 朱诚身. 聚合物结构分析 [M ]. 北京: 科学出版社, 2004: 201 - 204. [ 4] B row n J R, Enn is B C. Therm al analysis ofNom ex and Kevlar fibers[ J]. Text Res J, 1977, 47 ( 1): 62 - 66. [ 5] H indelehA M, Abdo ShM. E ffects of annealing on the crysta-l lin ity and m icroparacrystallite size ofKev lar 49 fibres[ J]. Po ly￾m er, 1989, 30 ( 2): 218- 224. [ 6] H ind eleh A M, Abdo ShM. Relationsh ip betw een crystalline structu re and m ech an ical prop erties in Kevlar 49 fibres[ J]. Polym C omm un, 1989, 30 ( 6): 184- 186. [ 7] Jam esW D, Jam es J, New ellA. Characterization of stru ctural changes in th erm ally enh anced Kevlar-29 fiber[ J]. Appl Polym S c,i 2004, 91: 417- 424. [ 8] Perepelk in K E, Pakshver E A, Andreeva I V. Therm al ch arac￾teristics of h igh-strength and th erm ostable arom atic fibres[ J]. F ibre Chem 2005, 37( 5 ): 346- 351. [ 9] 郯志清,钱咸彧, 吴小红, 等. 芳纶 1313的结构与性能 [ J]. 合成纤维工业, 1993, 16 ( 6): 18 - 21. [ 10 ] 赵稼祥. 美国 K evlar布性能测试分析 [ J]. 纤维复合材料, 1994, 11 ( 2): 32- 39. [ 11 ] Yang W, Yu H, Zhu M F. Poly ( m -pheny len e isoph￾th alam ide) u ltrafine fib ers from an ion ic liquid solu tion by dry￾jet-w et-electrosp inn ing [ J]. J M acrom ol Sc:i Phys, 2006, 45 ( 4): 573 - 579. [ 12 ] 何方, 张美云, 张素风. 纸基芳纶纤维结构与热裂解性能研 究 [ J]. 中华纸业, 2008, 29( 18 ): 25- 28. [ 13 ] V illar-Rod il S, M artinez-A lon so A , T ascoin JM D. S tud ies on pyrolysis ofN om ex po lyaram id fib ers[ J]. J Anal Appl Pyroly￾sis, 2001, 58 ( 59): 105 - 115. [ 14 ] V illar-Rod il S, Paredes J I, M artinez-A lonso A, Tascoin JM D. A tom ic force m icroscopy and in frared sp ectroscopy studies of the therm al degradation of nom ex aram id fib ers[ J]. Chem M ater, 2001, 13 ( 11 ): 4297- 4304. [ 15 ] V illar-Rod ilS, Paredes J I, M artinez-A lon so A , et a.l Com b-i n ing th erm al analysis w ith oth er techn iqu es to monitor the de￾com position of poly ( m -phenylene isoph thalam ide) [ J]. J Therm Anal Calorim, 2002, 70( 1): 37- 43. [ 16 ] L i X G, H uang M R. Therm al degradation of Kev lar fib er by h igh-reso lution therm ogravim etry[ J]. JApplPolym Sc,i 1999, 71( 4): 565- 571. [ 17 ] 陆赵情. 芳纶 1313纤维造纸技术研究及产品开发 [ D ]. 西 安: 陕西科技大学, 2004. [ 18 ] 王宜, 胡健, 雷以超, 等. Nomex纸基材料关键技术的分析 [ J]. 造纸科学与技术, 2004, 23( 3 ): 33- 36. [ 19 ] 何方, 张美云, 张素风. 热压光对纸基芳纶纤维结构的影响 [ J]. 陕西科技大学学报, 2008, 26 ( 1): 34- 37. [ 20 ] 储长流, 李龙, 张茂林. PP及芳纶 /PP结晶性能的分析研究 [ J]. 纤维复合材料, 2003( 1 ): 24- 26. [ 21 ] 曾翠霞, 顾平. 芳纶 1313混纺织物耐热性能的测试研究 [ J]. 上海纺织科技, 2009, 37( 3 ): 47- 48. [ 22 ] Kunug iT, W atanabe H, H ash im oto M. Dynam ic m echan ical p roperties of poly( p-phenylenetere ph th alam ide) fib er[ J]. J A pp l Polym Sc,i 1979, 24( 4 ): 1039 - 1051. [ 23 ] Rao Y, W addon A J, Farris R J. S tru cture-prop erty relation in po ly( p -pheny lene terephthalam ide) ( PPTA ) fibers[ J]. Poly￾m er, 2001, 42( 13): 5937- 5946. [ 24] Rao Y, WaddonA J, FarrisR J. The evolu tion of structu re and p roperties in poly ( p -phenylenetereph thalam ide) fibers[ J]. Polym er, 2001, 42 ( 13): 5925- 5935. [ 25] Ro jstaczer S, C ohn D, M arom G. Th erm al expansion ofK evlar f-i b ers and com posites[ J]. J Mater Sci Lett, 1985, 194 ( 10 ): 1233- 1236. Application of therm al analysis techniques in aram id fiber structure and properties research ZhaoHu ifang 1, 2 , ZhangM eiyun 1 , Zhang Su feng 1 ( 1. Co llege of Pulp and P ap er E ngineering, Shaanx i University of Science & Technology, X ican 710021; 2. Zhejiang University of Science and T echnology, H angzhou 310023) Abstract: The application o f therm al ana lysis techn iques in the aram id fibe r struc ture and properties research w as introduced, inc luding therm a l g rav im etric analysis, d ifferential therm a l ana ly sis, dynam ic them al ana lysis, therm om echanical ana lysis. Itw as po inted out that for the purpose o f offering the strategy in them a terial design, structure and properties research o f aram id fiber and the deve lopm ent and applica tion o f aram id fiber products, the therm al properties research o f aram id fiber shou ld attach m ore attention to the com b ined application o f therma l analysis techniques and o the r structure ana lysis techn iques, the exploration o f the crysta lline structure and the regularity o fm olecular chain m ovem ent in amo rphous area, the relationsh ip between the structure o f aram id fiber and the perfo rm ance of a ram id fiber products in Ch ina. K ey words: therm a l analysis technique; aram id fiber; structure; prope rty; product developm ent; applica tion 第 2期 赵会芳等. 热分析技术在芳纶结构性能研究中的应用 41