·1024· 北京科技大学学报 第36卷 Hu H Y,Zhu X F,Yang J K.Progress in the hydrometallurgical J Enriron Eng,2012,6(2)623 process for recovering lead from scrap lead-acid batteries.Chem (何东升，朱新锋，刘建文，等。废铅酸蓄电池铅膏柠檬酸浸 Ind Eng Prog,2009,28(9):1662 出动力学研究.环境工程学报，2012,6(2)：623) (胡红云，朱新锋，杨家宽.湿法回收废旧铅酸蓄电池中铅的 [8]Zhu X F,Li L,Sun X J,et al.Preparation of basic lead oxide 研究进展.化工进展，2009,28(9)：1662) from spent lead acid battery paste via chemical conversion.Hydro- B]Zhu X F,Liu WC,Yang H Y,et al.Preparation of ultrafine PbO metallurgy,2012,24(4):117 powders from lead paste in spent lead acid battery.Chin J Nonfer- 9]Shi J,Xu J N,Zhang P,et al.Hydrothermal synthesis and char- rous Met,2010,20(1):132 acterization of two coordination polymers of flexible acid and lead: (朱新锋，刘万超，杨海玉，等.以废铅酸电池铅膏制备超细 [Pb (HO)2 (cit)a]3H2O and Pb (tar)(H2O)2.Chem J Chin 氧化铅粉末.中国有色金属学报，2010,20(1)：132) Unim,2007,28(9):1617 4]Sonmez M S,Kumar R V.Leaching of waste battery paste compo- (石品，徐家宁，张萍，等.Ph6(H,0)2(ct):]3H20和Ph nents:Part 1.Lead citrate synthesis from PbO and PbO2.Hydro- (ta)·(H20)z两种柔性酸和铅的配位聚合物的水热合成与 metallurgy,2009,95(1/2）:53 表征.高等学校化学学报，2007,28(9)：1617) [5]Yang JK,Zhu X F,Liu WC.et al.Review of recovery technolo- [10]Li W Z,Li J,Wang X,et al.Influence of citric acid on photo- gy for lead paste from spent lead acid battery.Mod Chem Ind, electrochemical properties of WO,films obtained by polymeric 2009,29(3):32 precursor method./Cent South Unin Sci Technol,2012,43(5): (杨家宽，朱新锋，刘万超，等.废铅酸电池铅膏回收技术的 1638 研究进展.现代化工，2009,29(3)：32) (李文章，李洁，王旋，等.柠檬酸对聚合物前驱体法制备 Zhu X F.Study on Leaching Process of Spent Lead Battery Paste WO3薄膜光电性质的影响。中南大学学报：自然科学版， ith Organic Acid and Preparation of Ultrafine Lead Oxide by Cal- 2012,43(5):1638) cination at Lo Temperature [Dissertation].Wuhan:Huazhong [11]Bottari E,Vicedomini M.On the complex formation between lead University of Science Technology,2012 (II and citrate ions in acid solution.J Inorg Nucl Chem,1973, (朱新锋.废铅膏有机酸浸出及低温焙烧制备超细铅粉的基 35(4):1269 础研究[学位论文].武汉：华中科技大学，2012) [12]Bottari E,Vicedomini M.On the complex formation between lead He D S,Zhu X F,Liu J W,et al.Study on kinetics of leaching (Il)and citrate ions in alkaline solution.J Inorg Nucl Chem, lead paste in spent lead acid battery with citric acid solution.Chin 1973,35(7):2447北 京 科 技 大 学 学 报 第 36 卷 ［2］ Hu H Y，Zhu X F，Yang J K． Progress in the hydrometallurgical process for recovering lead from scrap lead-acid batteries． Chem Ind Eng Prog，2009，28( 9) : 1662 ( 胡红云，朱新锋，杨家宽． 湿法回收废旧铅酸蓄电池中铅的 研究进展． 化工进展，2009，28( 9) : 1662) ［3］ Zhu X F，Liu W C，Yang H Y，et al． Preparation of ultrafine PbO powders from lead paste in spent lead acid battery． Chin J Nonfer￾rous Met，2010，20( 1) : 132 ( 朱新锋，刘万超，杨海玉，等． 以废铅酸电池铅膏制备超细 氧化铅粉末． 中国有色金属学报，2010，20( 1) : 132) ［4］ Sonmez M S，Kumar Ｒ V． Leaching of waste battery paste compo￾nents: Part 1． Lead citrate synthesis from PbO and PbO2 ． Hydro￾metallurgy，2009，95( 1 /2) : 53 ［5］ Yang J K，Zhu X F，Liu W C，et al． Ｒeview of recovery technolo￾gy for lead paste from spent lead acid battery． Mod Chem Ind， 2009，29( 3) : 32 ( 杨家宽，朱新锋，刘万超，等． 废铅酸电池铅膏回收技术的 研究进展． 现代化工，2009，29( 3) : 32) ［6］ Zhu X F． Study on Leaching Process of Spent Lead Battery Paste with Organic Acid and Preparation of Ultrafine Lead Oxide by Cal￾cination at Low Temperature［Dissertation］． Wuhan: Huazhong University of Science ＆ Technology，2012 ( 朱新锋． 废铅膏有机酸浸出及低温焙烧制备超细铅粉的基 础研究［学位论文］． 武汉: 华中科技大学，2012) ［7］ He D S，Zhu X F，Liu J W，et al． Study on kinetics of leaching lead paste in spent lead acid battery with citric acid solution． Chin J Environ Eng，2012，6( 2) : 623 ( 何东升，朱新锋，刘建文，等． 废铅酸蓄电池铅膏柠檬酸浸 出动力学研究． 环境工程学报，2012，6( 2) : 623) ［8］ Zhu X F，Li L，Sun X J，et al． Preparation of basic lead oxide from spent lead acid battery paste via chemical conversion． Hydro￾metallurgy，2012，24 ( 4) : 117 ［9］ Shi J，Xu J N，Zhang P，et al． Hydrothermal synthesis and char￾acterization of two coordination polymers of flexible acid and lead: ［Pb6 ( H2O) 2 ( cit) 4］·3H2O and Pb( tar) ( H2O) 2 ． Chem J Chin Univ，2007，28( 9) : 1617 ( 石晶，徐家宁，张萍，等． ［Pb6 ( H2O) 2 ( cit) 4 ］·3H2O 和 Pb ( tar)·( H2O) 2 两种柔性酸和铅的配位聚合物的水热合成与 表征． 高等学校化学学报，2007，28( 9) : 1617) ［10］ Li W Z，Li J，Wang X，et al． Influence of citric acid on photo￾electrochemical properties of WO3 films obtained by polymeric precursor method． J Cent South Univ Sci Technol，2012，43( 5) : 1638 ( 李文章，李洁，王旋，等． 柠檬酸对聚合物前驱体法制备 WO3 薄膜光电性质的影响． 中南大学学报: 自然科学版， 2012，43( 5) : 1638) ［11］ Bottari E，Vicedomini M． On the complex formation between lead ( Ⅱ) and citrate ions in acid solution． J Inorg Nucl Chem，1973， 35( 4) : 1269 ［12］ Bottari E，Vicedomini M． On the complex formation between lead ( Ⅱ) and citrate ions in alkaline solution． J Inorg Nucl Chem， 1973，35( 7) : 2447 · 4201 ·