《工程科学学报》录用稿，htps:/doi.org/10.13374/i,issn2095-9389.2021.09.28.003©北京科技大学2020 用于木质素转化制备生物质燃料多功能催化 剂的研究进展 曲俊聪，史成香，张香文，潘伦，邹吉军四 天津大学化工学院先进燃料与化学推进剂教有部重点实验室，天津300072 ☒通信作者，E-mail:i_zou@ju.edu.cm 摘要木质素具有芳香结构，可用于生产高价值生物质燃料，但由于木质素结构非常复杂以其为原料生 产生物质燃料的过程涉及多种化学反应和多种催化剂，需经过多次分离，导致最终燃料的收率较低。多功 能催化剂可以同时催化两种或两种以上的化学反应，因而可以简化制备过程提篇产物收率。本文综述了 木质素加氢解聚、解聚单体加氢脱氧和单体升级为多环高价值产品等过程中所使的多功能催化剂的研究 进展，包括硫化物催化剂、单质贵金属催化剂、单质和合金非贵金属催化剂和磷化物催化剂等。强调了加 氢催化剂(Ru、Pt、Pd、Co、Mo和Ni等)和酸催化剂(AlO,、ZrO:NbOPO:、沸石和介孔硅酸盐等) 在加氢裂解、加氢脱氧和（加氢）烷基化反应中的协同作用。在位基础上总结了当前反应过程的一些难点， 并对下一步的技术发展方向进行了展望。未来需要开发水热稳定性更好价格更加低廉的高活性催化剂， 降低氢气用量，同时考虑天然木质素的一锅法转化，为业化制备生物质燃料奠定基础。 关键词木质素：生物质燃料：多功能催化剂：加氢裂解 加氢脱氧：烷基化 分类号TQ426.8,TQ517.2 Research advances of multifunctional catalysts for the conversion of lignin to biomass fuels QU Jun-cong.SHI Chenig-xiang.ZHANG Xiang-wen,PAN Lun.ZOU Ji-jun Key Laboratory for Advanced Fuel and Chemical Propellant of Ministry of Education,Tianjin University,Tianjin 300072,China Corresponding author,E-mail ji_zou@tju.edu.cn ABSTRACT The development of biomass fuels is of great significance for reducing the excessive dependence on fossil resources and global warming.Lignin is a complex aromatic biopolymer which is abundant in nature and can be used to produce high-value biomass fuels.However,due to the complex structure,using lignin to produce biomass fuels needs a variety of chemical reactions and catalysts,and intermediates and products need to be separated for many times,which results in low yield of the products.Multifunctional catalysts can catalyze two or more chemical reactions at the same time,so using them can simplify the preparation process and increase the yield of the products.In this paper,we reviewed the research progress of multifunctional catalysts used in the process of lignin hydrocracking,monomer hydrodeoxygenation and monomer upgrading to polycyclic high-value products,including sulfide catalysts,elemental noble metal catalysts,elemental and alloy non-noble metal 收篇日期2021-11-01用于木质素转化制备生物质燃料多功能催化 剂的研究进展 曲俊聪，史成香，张香文，潘伦，邹吉军 天津大学化工学院 先进燃料与化学推进剂教育部重点实验室，天津 300072  通信作者，E-mail: jj_zou@tju.edu.cn. 摘 要 木质素具有芳香结构，可用于生产高价值生物质燃料，但由于木质素结构非常复杂，以其为原料生 产生物质燃料的过程涉及多种化学反应和多种催化剂，需经过多次分离，导致最终燃料的收率较低。多功 能催化剂可以同时催化两种或两种以上的化学反应，因而可以简化制备过程，提高产物收率。本文综述了 木质素加氢解聚、解聚单体加氢脱氧和单体升级为多环高价值产品等过程中所使用的多功能催化剂的研究 进展，包括硫化物催化剂、单质贵金属催化剂、单质和合金非贵金属催化剂和磷化物催化剂等。强调了加 氢催化剂（Ru、Pt、Pd、Co、Mo 和 Ni 等）和酸催化剂（Al2O3、ZrO2、NbOPO4、沸石和介孔硅酸盐等） 在加氢裂解、加氢脱氧和（加氢）烷基化反应中的协同作用。在此基础上总结了当前反应过程的一些难点， 并对下一步的技术发展方向进行了展望。未来需要开发水热稳定性更好、价格更加低廉的高活性催化剂， 降低氢气用量，同时考虑天然木质素的一锅法转化，为工业化制备生物质燃料奠定基础。 关键词 木质素；生物质燃料；多功能催化剂；加氢裂解；加氢脱氧；烷基化 分类号 TQ426.8; TQ517.2 Research advances of multifunctional catalysts for the conversion of lignin to biomass fuels QU Jun-cong, SHI Cheng-xiang, ZHANG Xiang-wen, PAN Lun, ZOU Ji-jun  Key Laboratory for Advanced Fuel and Chemical Propellant of Ministry of Education, Tianjin University, Tianjin 300072, China  Corresponding author, E-mail: jj_zou@tju.edu.cn. ABSTRACT The development of biomass fuels is of great significance for reducing the excessive dependence on fossil resources and global warming. Lignin is a complex aromatic biopolymer which is abundant in nature and can be used to produce high-value biomass fuels. However, due to the complex structure, using lignin to produce biomass fuels needs a variety of chemical reactions and catalysts, and intermediates and products need to be separated for many times, which results in low yield of the products. Multifunctional catalysts can catalyze two or more chemical reactions at the same time, so using them can simplify the preparation process and increase the yield of the products. In this paper, we reviewed the research progress of multifunctional catalysts used in the process of lignin hydrocracking, monomer hydrodeoxygenation and monomer upgrading to polycyclic high-value products, including sulfide catalysts, elemental noble metal catalysts, elemental and alloy non-noble metal 收稿日期:2021-11-01 1 《工程科学学报》录用稿，https://doi.org/10.13374/j.issn2095-9389.2021.09.28.003 ©北京科技大学 2020 录用稿件，非最终出版稿