彭科波等：钒资源现状及有机磷类萃取剂萃钒的研究进展 609· 针对钒的浸出液中杂质较多的特点，改进或 metal production process:A case study of vanadium oxide 研发选择性高、适应性强的萃取剂是一个重要方 production in China.J Clean Prod,2020,256:120217 向，对于中心原子为P的萃取剂，空间效应以及基 [10]Qin Z F,Zhang G Q,Luo D M,et al.Separation of titanium from vanadium and iron in leach solutions of vanadium slag by solvent 团种类的影响是重要参考因素. extraction with trioctyl tertiary amine (N235).Hydrometallurgy, 除了对新型萃取剂的改进外，利用萃取剂的 2019,188:216 协同效应，不仅兼具高萃取率与高分离性能，还能 [11]Chen D H.Nnual evaluation for vanadium industry in 2018.Hebei 提高萃取效率，因此在原萃取剂的基础上利用协 Metall,.2019(8):5 同效应，探索新的萃取剂组合方式，也是萃取工艺 (陈东辉.钒产业2018年年度评价.河北治金，2019(8)：5) 重要的发展方向之一 [12]Petranikova M,Tkaczyk A H,Bartl A,et al.Vanadium 在萃取工艺方面，乳液膜萃取、树脂离子交换 sustainability in the context of innovative recycling and sourcing 等新方法逐渐成为新的研究方向，但是萃取剂与 development.Waste Manage,2020,113:521 [13]Mahandra H,Singh R,Gupta B.Recovery of vanadium(V)from 工艺的适应性也很重要，新型萃取剂与新工艺的 synthetic and real leach solutions of spent catalyst by solvent 结合也会成为提钒工艺的重要方法之一. extraction using Cyphos IL 104.Hydrometallurgy,2020,196: 105405 参考文献 [14]Gilligan R,Nikoloski A N.The extraction of vanadium from [1]Li H Y,Wang C J,Yuan Y H,et al.Magnesiation roasting-acid titanomagnetites and other sources.Miner Eng,2020,146:106106 leaching:A zero-discharge method for vanadium extraction from [15]Zou J X,Zhou L H,Peng F C.Vanadium Titanium Functional vanadium slag.J Clean Prod,2020,260:121091 Materials.Beijing:Metallurgical Industry Press,2019 [2]Zhu X B,Li W,Zhang C X.Extraction and removal of vanadium (邹建新，周兰花，彭富昌.钒钛功能材料.北京：冶金工业出版 by adsorption with resin 201*7 from vanadium waste liquid. 社，2019) Environ Res,,2020,180:108865 [16]Chen K H,He Y,Srinivasakannan C,et al.Characterization of the [3]Teng A J,Xue X X.A novel roasting process to extract vanadium interaction of rare earth elements with P507 in a microfluidic and chromium from high chromium vanadium slag using a extraction system using spectroscopic analysis.Chem Eng,2019 NaOH-NaNO,binary system.JHaard Mater,019,379:120805 356:453 [4]Xu ZZ,Liang J L,Li H,et al.Research status and prospects of [17]Li H L,Feng Y L,Wang H J,et al.Separation of V (V)and Mo vanadium recovery in vanadium containing wastes.Mullipurpose (VI)in roasting-water leaching solution of spent Util Miner Resour,2020(3):8 hydrodesulfurization catalyst by co-extraction using P507-N235 (徐正震，梁精龙，李慧，等.含钒废弃物中钒的回收研究现状及 extractant.Sep Purif Technol,2020,248:117135 展望.矿产综合利用2020(3)：8) [18]Karmakar A K,Biswas R K.A study on the kinetics of extraction [5]Liu Z S,Zhang Y M,Dai Z L,et al.Recovery of vanadium from of Ti(IV)from sulphate medium by Cyanex302.Sep Purif vanadium-bearing wastewater of vanadium-titanium magnetite Technol.2019.221:331 with solvent extraction by N235.Nonferrous Met (Extract Metall), [19]Kim H I,Moon G,Choi I,et al.Hydrometallurgical process 2019(11):87 development for the extraction,separation and recovery of (刘子帅，张一敏，戴子林，等.N235萃取法从钒钛磁铁矿沉钒废 vanadium from spent desulfurization catalyst bio-leach liquors./ 水中回收钒有色金属（治炼部分），2019(11)：87) Clean Prod,2018,187:449 [6]Luo D S,Huang J,Zhang Y M,et al.Study on separation [20]Zhang Y,Zhang T A,Dreisinger D,et al.Chelating extraction of performance of vanadium in N235-kerosene supported liquid vanadium(V)from low pH sulfuric acid solution by Mextral 973H. membrane system.Nonferrous Met (Extract Metall),2018(6):33 Sep Purif Technol,2018,190:123 (罗大双，黄品，张一敏，等.N235煤油支撑液膜体系中钒萃取 [21]Truong H T,Nguyen T H,Lee M S.Separation of 分离性能研究.有色金属（冶炼部分），2018(6)：33) molybdenum(VI),rhenium(VIl),tungsten(VD),and vanadium(V) [7]Yang X.Zhang Y M,Bao S X,et al.Separation and recovery of by solvent extraction.Hydromerallurgy,2017,171:298 vanadium from a sulfuric-acid leaching solution of stone coal by [22]Li W,Zhang Y M,Liu T,et al.Comparison of ion exchange and solvent extraction using trialkylamine.Sep Purif Technol,2016, solvent extraction in recovering vanadium from sulfuric acid leach 164:49 solutions of stone coal.Hydrometallurgy,2013,131-132:1 [8]Wang H J,Feng Y L,Li H L,et al.Recovery of vanadium from [23]Amesh P,Suneesh A S,Venkatesan K A,et al.Preparation and ion acid leaching solutions of spent oil hydrotreating catalyst using exchange studies of cesium and strontium on sodium iron titanate. solvent extraction with D2EHPA (P204).Hydrometallurgy,2020. 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