陈港欣等：高功率锂离子电池研究进展 9 (a) (d) ↑NCM+ACypre-doped Li foil ag (NCM+ACyGraphite Graphite Charging Charging Seperator Limetal (b)L Separator Cathode Activated carbon Anode Cathode (e)45 um Listripes Final seal Soaked 10 min Roller SLMP (after rolling) 181 Hard carbon -Copper 图6高功率锂离子电池预嵌锂方法示意图.(a)预嵌锂效果图，：(b)负极掺杂锂和正极摻杂锂示意图叫：(c)钝化锂粉(SLMP)方法预嵌锂s乳， (d)电化学方法预嵌锂叫，(e)锂金属接触方法预嵌锂网 Fig.Schematic diagram of pre-lithiation method for high power LIBs:(a)potential changes before and after pre-lithiation(b)pre-lithiation approaches of Li foil and cathode additives (c)SLMP powder pre-lithiation method(d)electrochemical pre-lithiation method(e)Li metal contact prelithiation method Is1 离子电导率的电解液、具有快速脱/嵌锂特性的 [6]Zhang J B,Lian F,Gao X P,et al.Advance of lithium ion 正负极材料、薄的电极片和高效导电添加剂等来 batteries:The 16th International Meeting on Lithium Batteries.Sci 实现 Sin Chimica 2012,42(8):1252 (张剑波，连芳，高学平，等.锂离子电池及材料发展前瞻一第 参考文献 16届国际锂电会议评述.中国科学：化学，2012,42(8)：1252) [1]Tarascon J M,Armand M.Issues and challenges facing [7]Wang Y.Cao G Z.Developments in nanostructured cathode rechargeable lithium batteries.Nature,2001,414(6861):359 materials for high-performance lithium-ion batteries.Adv Mater, [2]Ministry of Industry and Information Technology,People 's 2008,20(12):2251 Republic of China.GB/T 31486-2015 Electrical Performance [8] Zhang J N.Failure Analysis and Modification Research on High Requirements and Test Methods for Traction Battery of Electric Voltage LiCoO [Dissertation].Beijing:University of Chinese Vehicle.Beijing:China Standards Press,2015 Academy of Sciences (Institute of Physics,CAS),2018 (中华人民共和国工业和信息化部.GB/T31486一2015电动汽 (张杰男.高电压钻酸锂的失效分析与改性研究学位论文].北 车用动力蓄电池电性能要求及试验方法.北京：中国标准出版 京：中国科学院大学（中国科学院物理研究所），2018) 社，2015) [9] Gong Y,Zhang J N,Jiang L W,et al.In situ atomic-scale [3]Li C,Zhang X,Lv Z,et al.Scalable combustion synthesis of observation of electrochemical delithiation induced structure graphene-welded activated carbon for high-performance evolution of LiCoO,cathode in a working all-solid-state battery.J supercapacitors.Chem Eng J,2021,414:128781 4 n Chem Soc,2017,139(12片：4274 [4]Zhao S H,Wu F,Wang Z D.et al.Study on the different test [10]Zhang J N,Li Q H,Li Q,et al.Improved electrochemical methods for power density of power batteries.Acta Armamentarii, performances of high voltage LiCoO,with tungsten doping.Chin 2009,30(6):764 PhsB,2018,27(8):088202 (赵淑红，吴锋，王子冬，等.动力电池功率密度性能测试评价方 [11]Yang Q,Huang J,Li Y J,et al.Surface-protected LiCoO with 法的比较研究.兵工学报，2009,30(6)：764) ultrathin solid oxide electrolyte film for high-voltage lithium ion [5]Zhang J,Liu J W,Liu Q B.Research on ultra-high power Li-ion batteries and lithium polymer batteries.JPower Sources,2018. battery.Chin J Power Sources,2016,40(5):973 388:65 (张健，刘建文，刘全兵.超高功率锂离子电池研究.电源技术， [12]Tukamoto H,West A R.Electronic conductivity of LiCoOz and its 2016.40(5):973) enhancement by magnesium doping.J Electrochem Soc,1997,离子电导率的电解液、具有快速脱/嵌锂特性的 正/负极材料、薄的电极片和高效导电添加剂等来 实现. 参    考    文    献 Tarascon  J  M,  Armand  M.  Issues  and  challenges  facing rechargeable lithium batteries. 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J Electrochem Soc,  1997, [12] Charging Charging Potential Potential (NCM+AC)/Graphite (NCM+AC)/pre-doped Graphite (a) (c) (b) Separator Anode Li+ Li+ Li2MoO3 Limetal Cathode Current collector Blade SLMP SLMP (after rolling) Roller Hard carbon Copper Roller e − Soft carbon Activated carbon (d) (e) Li+ diffusion Li foil Anode Charger Seperator Cathode 45 μm Li stripes Final seal Soaked 10 min 20 min 30 min 1 h 5 h 18 h 图 6    高功率锂离子电池预嵌锂方法示意图. （a）预嵌锂效果图[33] ；（b）负极掺杂锂和正极掺杂锂示意图[82] ；（c）钝化锂粉 (SLMP) 方法预嵌锂[83] ； （d）电化学方法预嵌锂[84] ；（e）锂金属接触方法预嵌锂[85] Fig.6     Schematic  diagram  of  pre-lithiation  method  for  high  power  LIBs:  (a)  potential  changes  before  and  after  pre-lithiation [33] ； (b)pre-lithiation approaches  of  Li  foil  and  cathode  additives[82] ； (c)  SLMP  powder  pre-lithiation  method [83] ； (d)electrochemical  pre-lithiation  method [84] ； (e)  Li  metal contact prelithiation method [85] 陈港欣等： 高功率锂离子电池研究进展 · 9 ·