10 工程科学学报，第44卷，第X期 144(9):3164 [27]Mou J R,Deng Y L,He L H,et al.Critical roles of semi- [13]Ceder G,Chiang Y M,Sadoway D R,et al.Identification of conductive LaFeO;coating in enhancing cycling stability and rate cathode materials for lithium batteries guided by first-principles capability of 5 V LiNio.sMn5O cathode materials. calculations.Nature,1998,392(6677):694 Electrochimical Acta,2018,260:101 [14]Gopukumar S,Jeong Y,Kim K B.Synthesis and electrochemical [28]Dong H,Zhang Y,Zhang S,et al.Improved high temperature performance of tetravalent doped LiCoO,in lithium rechargeable performance of a spinel LiNio.sMnsO cathode for high-voltage cells.Solid State Ion,2003,159(3-4):223 lithium-ion batteries by surface modification of a flexible [15]Zhang J N,Li Q H,Ouyang C Y,et al.Trace doping of multiple conductive nanolayer.ACS Omega,2019,4(1):185 elements enables stable battery cycling of LiCoO,at 4.6 V.Nar [29]Jurng S,Heiskanen S K,Chandrasiri K,et al.Minimized metal Energy,2019,4(7)：小594 dissolution from high-energy nickel cobalt manganese oxide [16]Morimoto H,Awano H,Terashima J,et al.Preparation of lithium cathodes with Al2O;coating and its effects on electrolyte ion conducting solid electrolyte of NASICON-type LiAl,Tiz decomposition on graphite anodes.J Electrochem Soc,2019, (PO3(x-0.3)obtained by using the mechanochemical method 166(13):A2721 and its application as surface modification materials of LiCoO [30]Park BC.Kim H B.Myung S T,et al.Improvement of structural cathode for lithium cell.Power Sources,2013,240:636 and electrochemical properties of AlF:-coated [17]Yano A,Shikano M,Ueda A,et al.LiCoOz Degradation behavior Li[NiusCou3Mni]O2 cathode materials on high voltage region.J in the high-voltage phase transition region and improved Power Sources,2008,178(2):826 reversibility with surface coating.J Electrochem Soc,2016, [31]Liu W J,Sun X Z,Zhang X,et al.Structural evolution of 164(1):A6116 mesoporous graphene/LiNiCouMnO2 composite cathode for [18]Jayasree SS,Nair S,Santhanagopalan D.Ultrathin TiOz coating Li-ion battery.Rare Met,2021,40(3):521 on LiCoOz for improved electrochemical performance as Li-ion [32]Liu W J,Li C,Sun X Z,et al.Improvement of the high-rate battery cathode.Chem Select,2018,3(10):2763 capability of LiNiCoLMnO2 cathode by adding highly [19]Zhang J N.LiQ H,Wang Y,et al.Dynamic evolution of cathode electroconductive and mesoporous graphene.J Alloys Compd, electrolyte interphase (CEl)on high voltage LiCoO2 cathode and 2018,758:206 its interaction with Li anode.Energy Storage Mater,2018,14:1 [33]Sun X Z,Zhang X,Wang K,et al.Lithium ion hybrid capacitor [20]Hong S K,Mho S I,Yeo I H,et al.Structural and electrochemical with high energy density.J Electrochem,2017,23(5):586 characteristics of morphology-controlled Li[Nio.sMn.s]O (孙现众，张熊，王凯，等.高能量密度的锂离子混合型电容器 cathodes.Electrochim Acta,2015,156:29 电化学，2017,23(5)：586) [21]Fergus J W.Recent developments in cathode materials for lithium [34]Sun X Z,Zhang X,Huang B,et al.(LiNio.sCop2MnoO AC)/ ion batteries./Power Sources,2010,195(4):939 graphite hybrid energy storage device with high specific energy [22]Chen LQ.Research progress in cathode materials of Li-ion and high rate capability.Power Sources,2013,243:361 battery.Battery Bimonthly 2002,32(S1),6 [35]Sun X Z,Zhang X,Zhang H T,et al.High performance lithium- (陈立泉.锂离子电池正极材料的研究进展.电池2002,32(S1): ion hybrid capacitors with pre-lithiated hard carbon anodes and 6) bifunctional cathode electrodes.JPower Sources,2014,270:318 [23]Jia GL,Jiao CM,Xue WJ,et al.Improvement in electrochemical [36]Du T,Liu Z E,Sun X Z,et al.Segmented bi-material cathodes to performance of calcined LiNio.sMnsO/GO.Solid State Ion,2016, boost the lithium-ion battery-capacitors.Power Sources,2020, 292:15 478:228994 [24]Fang X,ShenCF,Ge MY,et al.High-power lithium ion batteries [37]Luo F,Chu G,Huang J,et al.Fundamental scientific aspects of based on flexible and light-weight cathode of LiNiosMn.sO/ lithium batteries()-Anode electrode materials.Energy Storage carbon nanotube film..Nano Energy,2015,12:43 Sci Technol,2014,3(2):146 [25]Chang Q.Wei A J,Li W,et al.Structural and electrochemical (罗飞，褚赓，黄杰，等.锂离子电池基础科学问题（Ⅷ）一一负极 characteristics of Al2O:-modified LiNiosMn.sO cathode 材料.储能科学与技术，2014,3(2)：146) materials for lithium-ion batteries.Ceram /nt,2019,45(4):5100 [38]Li Z,Sun X Z,Liu W J,et al.A comparative study of pre-lithiated [26]Zhu R N,Zhang S J,Guo QX,et al.More than just a protection hard carbon and soft carbon as anodes for lithium-ion capacitors./ layer:Inducing chemical interaction between Li;BO;and Electrochem,2019,25(1):122 LiNio.sMn150 to achieve stable high-rate cycling cathode [39]Pan G H,Zhao Y B,Zhang K Z,et al.High power soft/hard materials.Electrochimical Acta,2020,342:136074 carbon composite anode for rechargeable lithium-ion battery.144（9）: 3164 Ceder  G,  Chiang  Y  M,  Sadoway  D  R,  et  al.  Identification  of cathode  materials  for  lithium  batteries  guided  by  first-principles calculations. Nature, 1998, 392（6677）: 694 [13] Gopukumar S, Jeong Y, Kim K B. Synthesis and electrochemical performance of tetravalent doped LiCoO2 in lithium rechargeable cells. Solid State Ion, 2003, 159（3-4）: 223 [14] Zhang J N, Li Q H, Ouyang C Y, et al. Trace doping of multiple elements  enables  stable  battery  cycling  of  LiCoO2 at  4.6  V. Nat Energy, 2019, 4（7）: 594 [15] Morimoto H, Awano H, Terashima J, et al. Preparation of lithium ion  conducting  solid  electrolyte  of  NASICON-type  Li1+xAlxTi2−x (PO4 )3 (x=0.3)  obtained  by  using  the  mechanochemical  method and  its  application  as  surface  modification  materials  of  LiCoO2 cathode for lithium cell. J Power Sources, 2013, 240: 636 [16] Yano A, Shikano M, Ueda A, et al. LiCoO2 Degradation behavior in  the  high-voltage  phase  transition  region  and  improved reversibility  with  surface  coating. J Electrochem Soc,  2016, 164（1）: A6116 [17] Jayasree S S, Nair S, Santhanagopalan D. Ultrathin TiO2 coating on  LiCoO2 for  improved  electrochemical  performance  as  Li–ion battery cathode. Chem Select, 2018, 3（10）: 2763 [18] Zhang J N, Li Q H, Wang Y, et al. Dynamic evolution of cathode electrolyte interphase (CEI) on high voltage LiCoO2 cathode and its interaction with Li anode. Energy Storage Mater, 2018, 14: 1 [19] Hong S K, Mho S I, Yeo I H, et al. Structural and electrochemical characteristics  of  morphology-controlled  Li[Ni0.5Mn1.5]O4 cathodes. Electrochim Acta, 2015, 156: 29 [20] Fergus J W. Recent developments in cathode materials for lithium ion batteries. J Power Sources, 2010, 195（4）: 939 [21] Chen  L  Q.  Research  progress  in  cathode  materials  of  Li-ion battery. Battery Bimonthly 2002, 32(S1), 6 （ 陈立泉. 锂离子电池正极材料的研究进展. 电池 2002, 32(S1): 6） [22] Jia G L, Jiao C M, Xue W J, et al. Improvement in electrochemical performance of calcined LiNi0.5Mn1.5O4 /GO. Solid State Ion, 2016, 292: 15 [23] Fang X, Shen C F, Ge M Y, et al. High-power lithium ion batteries based  on  flexible  and  light-weight  cathode  of  LiNi0.5Mn1.5O4 / carbon nanotube film.. Nano Energy, 2015, 12: 43 [24] Chang  Q,  Wei  A  J,  Li  W,  et  al.  Structural  and  electrochemical characteristics  of  Al2O3 -modified  LiNi0.5Mn1.5O4 cathode materials for lithium-ion batteries. Ceram Int, 2019, 45（4）: 5100 [25] Zhu R N, Zhang S J, Guo Q X, et al. More than just a protection layer:  Inducing  chemical  interaction  between  Li3BO3 and LiNi0.5Mn1.5O4 to  achieve  stable  high-rate  cycling  cathode materials. Electrochimical Acta, 2020, 342: 136074 [26] Mou  J  R,  Deng  Y  L,  He  L  H,  et  al.  Critical  roles  of  semi￾conductive LaFeO3 coating in enhancing cycling stability and rate capability  of  5  V  LiNi0.5Mn1.5O4 cathode  materials. Electrochimical Acta, 2018, 260: 101 [27] Dong  H,  Zhang  Y,  Zhang  S,  et  al.  Improved  high  temperature performance  of  a  spinel  LiNi0.5Mn1.5O4 cathode  for  high-voltage lithium-ion  batteries  by  surface  modification  of  a  flexible conductive nanolayer. ACS Omega, 2019, 4（1）: 185 [28] Jurng  S,  Heiskanen  S  K,  Chandrasiri  K,  et  al.  Minimized  metal dissolution  from  high-energy  nickel  cobalt  manganese  oxide cathodes  with  Al2O3 coating  and  its  effects  on  electrolyte decomposition  on  graphite  anodes. J Electrochem Soc,  2019, 166（13）: A2721 [29] Park B C, Kim H B, Myung S T, et al. Improvement of structural and  electrochemical  properties  of  AlF3 -coated Li[Ni1/3Co1/3Mn1/3]O2 cathode materials on high voltage region. J Power Sources, 2008, 178（2）: 826 [30] Liu  W  J,  Sun  X  Z,  Zhang  X,  et  al.  Structural  evolution  of mesoporous  graphene/LiNi1/3Co1/3Mn1/3O2 composite  cathode  for Li–ion battery. Rare Met, 2021, 40（3）: 521 [31] Liu  W  J,  Li  C,  Sun  X  Z,  et  al.  Improvement  of  the  high-rate capability  of  LiNi1/3Co1/3Mn1/3O2 cathode  by  adding  highly electroconductive  and  mesoporous  graphene. J Alloys Compd, 2018, 758: 206 [32] Sun X Z, Zhang X, Wang K, et al. Lithium ion hybrid capacitor with high energy density. J Electrochem, 2017, 23（5）: 586 （孙现众, 张熊, 王凯, 等. 高能量密度的锂离子混合型电容器. 电化学, 2017, 23（5）：586） [33] Sun X Z, Zhang X, Huang B, et al. (LiNi0.5Co0.2Mn0.3O2 + AC)/ graphite  hybrid  energy  storage  device  with  high  specific  energy and high rate capability. J Power Sources, 2013, 243: 361 [34] Sun X Z, Zhang X, Zhang H T, et al. High performance lithium￾ion  hybrid  capacitors  with  pre-lithiated  hard  carbon  anodes  and bifunctional cathode electrodes. J Power Sources, 2014, 270: 318 [35] Du T, Liu Z E, Sun X Z, et al. Segmented bi-material cathodes to boost  the  lithium-ion  battery-capacitors. J Power Sources,  2020, 478: 228994 [36] Luo  F,  Chu  G,  Huang  J,  et  al.  Fundamental  scientific  aspects  of lithium batteries(Ⅷ)—Anode electrode materials. Energy Storage Sci Technol, 2014, 3（2）: 146 （罗飞, 褚赓, 黄杰, 等. 锂离子电池基础科学问题(Ⅷ)——负极 材料. 储能科学与技术, 2014, 3（2）：146） [37] Li Z, Sun X Z, Liu W J, et al. A comparative study of pre-lithiated hard carbon and soft carbon as anodes for lithium-ion capacitors. J Electrochem, 2019, 25（1）: 122 [38] Pan  G  H,  Zhao  Y  B,  Zhang  K  Z,  et  al.  High  power  soft/hard carbon  composite  anode  for  rechargeable  lithium-ion  battery. [39] · 10 · 工程科学学报，第 44 卷，第 X 期