尹升华等：细粒层对浸矿表面形貌及钝化的影响 .917· 间的相互影响.中南大学学报（自然科学版），2015,46(9)： during heap leaching.Hydrometallurgy,2009,95(1-2):76 3176) [20]Yin S H,Wang L M,Xie FF,et al.Effect of heap structure on [13]Yao G C.Wen J K,Gao HZ,et al.Chalcopyrite bioleaching by column leaching of secondary copper sulfide.Chin Nonferrous moderate thermophilic bacteria and surface passivation.Central M.2017,27(11):2340 S Unig Sci Technol,2010,41(4):1234 (尹升华，王雷鸣，谢芳芳，等.堆体结构对次生硫化铜矿柱 (姚国成，温建康，高焕芝，等.中等嗜热菌浸出黄铜矿及其 浸的影响.中国有色金属学报，2017,27(11)：2340) 表面钝化的研究.中南大学学报（自然科学版），2010,41 [21]Yin S H.Wang L M,Pan C Y,et al.Secondary copper sulfide (4):1234) bioleaching experiments.Chin J Eng,2017,39(10):1498 [14]Sheikhzadeh G A,Mehrabian M A,Mansouri S H,et al.Com- (尹升华，王雷鸣，潘晨阳，等.次生疏化铜矿微生物浸出实 putational modelling of unsaturated flow of liquid in heap leac- 验.工程科学学报，2017,39(10)：1498) hing-using the results of column tests to calibrate the model. [22]Wang S Y,Wu A X,Wang H J,et al.Craft of wash-classifica- Int J Heat Mass Transfer,2005,48(2):279 tion of heap leaching used in high-clay copper oxide ore.Chin J [15]Fu K B,Lin H,Mo X L,et al.Passivation of different genetic Nonferrous Met,2013,23(1):229 types of chalcopyrite bioleaching./Central S Unir Sci Technol, (王少勇，吴爱祥，王洪江，等.高含泥氧化铜矿水洗-分级 2011,42(11):3245 堆浸工艺.中国有色金属学报，2013,23(1)：229) (傅开彬，林海，莫晓兰，等.不同成因类型黄铜矿细菌浸出 [23]Yin S H,Wang L.M,Pan C Y,et al.Fluid flowing characteris- 钝化.中南大学学报（自然科学版），2011,42(11)：3245) tics in ore granular with fine interlayers existed.Chin Nonfer- [16]Yin S H,Wang L M,Chen X,et al.Effect of ore size and heap rous Met,2017,27(3):574 porosity on capillary process inside leaching heap.Trans Nonfer- (尹升华，王雷鸣，潘晨阳，等.细粒层存在条件下矿岩散体 rous Met Soc China,2016,26(3):835 内的溶液流动特性.中国有色金属学报，2017,27(3)：574) [17]Erguler G K,Erguler Z A,Akcakoca H,et al.The effect of col- [24]Cariaga E,Concha F,Sepalveda M.Flow through porous media umn dimensions and particle size on the results of kinetic column with applications to heap leaching of copper ores.Chem Eng / test used for acid mine drainage (AMD)prediction.Miner Eng, 2005,111(2-3):151 2014,55:18 [25]Agate A D,Korezynski M S,Lundgren D G.Extracellular com- [18]Yin S H,Wang L M,Chen X.Effect of ore particle sizes on plex from the culture filtrate of Ferrobacillus ferrooxidans.Can J leaching regularities of secondary copper sulfide.J Central S Microbiol..1969,15(3):259 Unin Sci Technol,2015,46(8):2771 [26]Zhao X Q,Wang R C,Lu X C,et al.Bioleaching of chalcopy- (尹升华，王雷鸣，陈勋.矿石粒径对次生硫化铜矿浸出规 rite by Acidithiobacillus ferrooxidans.Miner Eng,2013,53:184 律的影响.中南大学学报（自然科学版），2015,46(8)： [27]Panda S,Parhi P K,Nayak B D,et al.Two step meso-acido- 2771) philic bioleaching of chaleopyrite containing ball mill spillage and [19]Wu A X,Yin S H,Qin WQ,et al.The effect of preferential removal of the surface passivation layer.Bioresour Technol, flow on extraction and surface morphology of copper sulphides 2013.130:332尹升华等: 细粒层对浸矿表面形貌及钝化的影响 间的相互影响. 中南大学学报(自然科学版), 2015, 46(9): 3176) [13] Yao G C, Wen J K, Gao H Z, et al. Chalcopyrite bioleaching by moderate thermophilic bacteria and surface passivation. J Central S Univ Sci Technol, 2010, 41(4): 1234 (姚国成, 温建康, 高焕芝, 等. 中等嗜热菌浸出黄铜矿及其 表面钝化的研究. 中南大学学报(自然科学版), 2010, 41 (4): 1234) [14] Sheikhzadeh G A, Mehrabian M A, Mansouri S H, et al. Com鄄 putational modelling of unsaturated flow of liquid in heap leac鄄 hing———using the results of column tests to calibrate the model. Int J Heat Mass Transfer, 2005, 48(2): 279 [15] Fu K B, Lin H, Mo X L, et al. Passivation of different genetic types of chalcopyrite bioleaching. J Central S Univ Sci Technol, 2011, 42(11): 3245 (傅开彬, 林海, 莫晓兰, 等. 不同成因类型黄铜矿细菌浸出 钝化. 中南大学学报(自然科学版), 2011, 42(11): 3245) [16] Yin S H, Wang L M, Chen X, et al. Effect of ore size and heap porosity on capillary process inside leaching heap. Trans Nonfer鄄 rous Met Soc China, 2016, 26(3): 835 [17] Erguler G K, Erguler Z A, Akcakoca H, et al. The effect of col鄄 umn dimensions and particle size on the results of kinetic column test used for acid mine drainage (AMD) prediction. Miner Eng, 2014, 55: 18 [18] Yin S H, Wang L M, Chen X. Effect of ore particle sizes on leaching regularities of secondary copper sulfide. J Central S Univ Sci Technol, 2015, 46(8): 2771 (尹升华, 王雷鸣, 陈勋. 矿石粒径对次生硫化铜矿浸出规 律的影响. 中南大学学报( 自然科学版), 2015, 46 (8 ): 2771) [19] Wu A X, Yin S H, Qin W Q, et al. The effect of preferential flow on extraction and surface morphology of copper sulphides during heap leaching. Hydrometallurgy, 2009, 95(1鄄2): 76 [20] Yin S H, Wang L M, Xie F F, et al. Effect of heap structure on column leaching of secondary copper sulfide. Chin J Nonferrous Met, 2017, 27(11): 2340 (尹升华, 王雷鸣, 谢芳芳, 等. 堆体结构对次生硫化铜矿柱 浸的影响. 中国有色金属学报,2017, 27(11): 2340) [21] Yin S H, Wang L M, Pan C Y, et al. Secondary copper sulfide bioleaching experiments. Chin J Eng, 2017, 39(10): 1498 (尹升华, 王雷鸣, 潘晨阳, 等. 次生硫化铜矿微生物浸出实 验. 工程科学学报, 2017, 39(10): 1498) [22] Wang S Y, Wu A X, Wang H J, et al. Craft of wash鄄classifica鄄 tion of heap leaching used in high鄄clay copper oxide ore. Chin J Nonferrous Met, 2013, 23(1): 229 (王少勇, 吴爱祥, 王洪江, 等. 高含泥氧化铜矿水洗鄄鄄 分级 堆浸工艺. 中国有色金属学报, 2013, 23(1): 229) [23] Yin S H, Wang L M, Pan C Y, et al. Fluid flowing characteris鄄 tics in ore granular with fine interlayers existed. Chin J Nonfer鄄 rous Met, 2017, 27(3): 574 (尹升华, 王雷鸣, 潘晨阳, 等. 细粒层存在条件下矿岩散体 内的溶液流动特性. 中国有色金属学报, 2017, 27(3): 574) [24] Cariaga E, Concha F, Sep俨lveda M. Flow through porous media with applications to heap leaching of copper ores. Chem Eng J, 2005, 111(2鄄3): 151 [25] Agate A D, Korczynski M S, Lundgren D G. Extracellular com鄄 plex from the culture filtrate of Ferrobacillus ferrooxidans. Can J Microbiol, 1969, 15(3): 259 [26] Zhao X Q, Wang R C, Lu X C, et al. Bioleaching of chalcopy鄄 rite by Acidithiobacillus ferrooxidans. Miner Eng, 2013, 53: 184 [27] Panda S, Parhi P K, Nayak B D, et al. Two step meso鄄acido鄄 philic bioleaching of chalcopyrite containing ball mill spillage and removal of the surface passivation layer. Bioresour Technol, 2013, 130: 332 ·917·