华南农业大学理学院：《无机及分析化学 Inorganic and analytical chemistry》教案 第二章 化学反应的能量和方向 第三章 化学反应的速率和限度

❑§1-1 分散系 ❑§1-2 溶液的浓度 ❑§1-3 稀溶液的依数性

he relationship between structure and function reaches its ultimate expression in the chemistry of amino acids, peptides, and protein Amino acids are carboxylic acids that contain an amine function. Under cer- tain conditions the amine group of one molecule and the carboxyl group of a second can react, uniting the two amino acids by an amide bond. Amide(peptide)bond

ou have already had considerable experience with carbanionic compounds and rgani their applications in synthetic organic chemistry. The first was acetylide ion in Chapter 9, followed in Chapter 14 by organometallic compounds-Grignard reagents, for example-that act as sources of negatively polarized carbon. In Chapter 18 you learned that enolate ions-reactive

rganometallic compounds are compounds that have a carbon-metal bond; they lie at the place where organic and inorganic chemistry meet. You are already familiar with at least one organometallic compound, sodium acetylide (NaC=CH), which has an ionic bond between carbon and sodium. But just because a compound contains both a metal and carbon isn't enough to classify it as organometal-

the preceding chapter you learned that nucleophilic addition to the carbonyl group is one of the fundamental reaction types of organic chemistry. In addition to its own reactivity, a carbonyl group can affect the chemical properties of aldehydes and ketones in other ways. Aldehydes and ketones are in equilibrium with their enol isomers

itrogen-containing compounds are essential to life. Their ultimate source is atmo- spheric nitrogen which, by a process known as nitroge. nitrogen fixation, is reduce ced to ammonia, then converted to organic nitrogen compounds. This chapter describes the chemistry of amines, organic derivatives of ammonia. Alkylamines have their nitro- gen attached to sp'-hybridized carbon; arylamines have their nitrogen attached to an sp2-hybridized carbon of a benzene or benzene-like ring

CONTENTS Preface xxv INTRODUCTION he Origins of Organic Chemistry 1 Berzelius, Wohler. and vitalism 1 The Structural Theory 3 Electronic Theories of Structure and Reactivity 3

PREFACE t is our hope that in writing this Study Guide and Solutions Manual we will make the study of or- ganic chemistry more meaningful and worthwhile. To be effective, a study guide should be more than just an answer book. What we present here was designed with that larger goal in mind

复旦大学：《物理化学》课程教学大纲 Physical Chemistry（国家级精品课程）