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Beak, P. (1992). “Determinations of transition-state geometries by the endocyclic restriction test: mechanisms of substitution at nonstereogenic atoms.” Acc. Chem. Res. 25: 215. The Primary Literature
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Stereoelectronic Effects-1 Anomeric and Related Effects Electrophilic & Nucleophilic Substitution Reactions The SN2 Reaction: Stereoelectronic Effects Olefin Epoxidation: Stereoelectronic Effects Baeyer-Villiger Reaction: Stereoelectronic Effects Olefin Bromination: Stereoelectronic Effects
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Prelog Strain: van der Waals interactions Baeyer Strain: bond angle distortion away from the ideal Pitzer Strain: torsional rotation about a sigma bond Baeyer Strain for selected ring sizes size of ring Ht of Combustion
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Advanced Organic Chemistry Handout-09A Synthetic Mechanistic Overview of Electrophilic Halogenation andy ratz Evans group seminar, May 7, 1992 Matthew d. shair
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Theory & Modeling of Stereoselective Organic Reactions (Handout) Epoxidation & Directed Epoxidation Hydrogenation Hydride Reduction
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Carey& Sundberg, Part A, CH 4, pp 187-250 Conformational Analysis-4 a Problems of the Day:(To be discussed) Conformational Analysis of C6 >Cg Rings continued Predict the stereochemical outcome of this reaction
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Evans Group Seminar, February 13, 1998 For a recent general review of the Simmons-Smith reaction see:
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Classification of Functional Groups Each substituent attached to carbon activates that carbon toward a polar reaction by either resonance or induction or both. Induction
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Recent Applications of the Prins Reaction in Stereoselective Synthesis Matthew D. Shair Monday
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The Aza-Cope Rearrangement. Background and Application to Alkaloid Synthesis Mike calter Evans group seminar
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