PREFACE t is our hope that in writing this Study Guide and Solutions Manual we will make the study of or- ganic chemistry more meaningful and worthwhile. To be effective, a study guide should be more than just an answer book. What we present here was designed with that larger goal in mind
The triacylglycerol shown in text Figure 26.2a, with an oleyl group at C-2 of the glycerol unit and two ste earyl groups at C-I and C-3, yields stearic and oleic acids in a 2 I molar ratio on hydrolysis. A constitutionally isomeric structure in which the oleyl group is attached to C-1 of glycerol would yield the same hydrolysis products
SOLUTIONS TO TEXT PROBLEMS 24.(b) A benzyl group(C., CH2) is ortho to the phenolic hydroxyl group in o-benzylphenol. OH CH2C.Hs (c)Naphthalene is numbered as shown. 3-Nitro-I-naphth has a hydroxyl group at C-1 and a nitro group
22.2 N,N-Dimethylcycloheptylamine may also be named as a dimethyl derivative of cycloheptanamine. -N(CH3)2 N,N-Dimethylcycloheptanamine 22.3 Three substituents are attached to the nitrogen atom; the amine is tertiary. In alphabetical order, the s substituents present on the aniline nucleus are ethyl, isopropyl, and methyl. Their positions are
20.1 () Carboxylic aci id anhydrides bear two acyl groups on oxygen, as in RCOCR. They are named as derivatives of carboxylic acids. Q CH:CH2CHCOH CH,CH,CHCOCCHCH_CH3 C6H C. C. 2-Phenylbutanoic acid 2-Phenylbutanoic anhydride (c) Butyl 2-phenylbutanoate is the butyl ester of 2-phenylbutanoic acid. CH,CH,CHCOCH,CH,CH2CH
