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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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An acid is a substance that can donate (or lose) a proton, A base is a substance that can accept (or remove) a proton
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Phenols are like alcohols in being able to form strong intermolecular hydrogen bonds. Phenols have higher boiling points than hydrocarbons of the same molecular weight. A modest solubility in water
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Quinones are an interesting and valuable class of compounds because of their oxidation-reduction, or redox, properties. The redox properties of quinones are important to the functioning of living cells, where compounds called ubiquinones(泛醌) act as biochemical oxidizing agents to mediate the electro-transfer processes involved in energy production
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17.1 The Acidity of the α Hydrogens of Carbonyl Compounds: Enolate Anions 17.2 Keto and Enol Tautomers 17.3 Reactions via Enols and Enolate Anions
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Aldehydes are named by replacing the terminal –e of the corresponding alkane name with –al. The longest chain selected as the base name must contain the –CHO group, and the –CHO carbon is always numbered as carbon 1
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三维图形在科学研究和工程技术中有着广泛的应用。在CAD中,需 要对所设计的作品从不同的角度进行审视。计算机几何造型就是 用计算机系统来表示、控制、分析和输出三维形体。所以几何造 型是计算机图形学中一个十分重要的应用领域,它是CAD/CAM和 CIMS系统的核心技术,也是用来实现计算机辅助设计的基本手段
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More reactive than benzene toward electrophilic substitution NO2 An deactivating group Less reactive than benzene toward electrophilic substitution Ortho-para director Meta director
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The most characteristic reactions of benzenoid arenes are the substitution reactions that occur when they react with electrophilic reagents. The electrophiles are either a positive ion (E+) or some other electron-deficient species with a large partial positive charge
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A UV-Vis spectrophotometer measures the amount of light absorbed at each wavelength of the UV and visible regions of the electromagnetic spectrum. λmax— the wavelength of maximum absorption
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