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How are molecular structures determined? One way is though the use of spectroscopic methods. Spectroscopy is the study of the interaction of energy with matter. When energy is applied to matter it can be absorbed, emitted, cause a chemical change, or be transmitted
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1. The experimental conditions — temperature and acid concentration — that are required to being about dehydration are closely related to the structure of the individual alcohol. The relative ease with which alcohols undergo dehydration is in the following order:
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First order overall (一级反应) The reaction is a unimolecular nucleophilic substitution(单分子亲核取代反应)
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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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Energy and the Relative Stability Kinetic energy is the energy an object has because of its motion. Potential energy is stored energy. It exists only when an attractive or repulsive force exists between objects
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Carbon’s ability to form strong covalent bonds to other carbon atoms is the single property of the carbon atom that — more than any other—accounts for the existence of a field of study called organic chemistry. Carbon’s ability to form as many as four strong bonds to other carbon atoms, and to form strong bonds to hydrogen, oxygen, sulfur, and nitrogen atoms as well
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Phenols are like alcohols in being able to form strong intermolecular hydrogen bonds. Phenols have higher boiling points than hydrocarbons of the same molecular weight. A modest solubility in water
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The reactivity of organometallic compounds increases with the percent ionic character of the carbon-metal bond. RLi and RMgX are of great importance in organic synthesis
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A hydrocarbon whose molecules contain two double bonds is called an alkadiene(alkatriene for three double bonds); A hydrocarbon with two triple bonds is called an alkadiyne; A hydrocarbon with a double and triple bond is called an alkenyne
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