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Cycloalkanes with only one ring are named by attaching the prefix cyclo- to the names of the alkanes possessing the same number of carbon atoms
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Isomers are different compounds that have the same molecular formula. Constitutional isomers are isomers that differ because their atoms are connected in a different order. Stereoisomers differ only in arrangement of their atoms in space.Stereoisomers are not constitutional isomers. Enantiomers are stereoisomers whose molecules are nonsuperposable mirror images of each other. Diastereomer are stereoisomers whose molecules are not mirror images of each other
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Before 1951 only relative configurations of chiral molecules were known. Configurations of chiral molecules were related to each other through reactions of known stereochemistry. The standard compound was glyceraldehyde
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An equimolar mixture of two enantiomers is called a racemic form (either a racemate or a racemic mixture). A racemic form shows no rotation of plane￾polarized light
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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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The primary source of alkanes is petroleum Natural gas consists chiefly of methane, but ethane, propane, butane, and isobutane are also present. Petroleum is a complex mixture of hydrocarbons that must be refined into different fraction before it can be used
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Functional groups The structural features that make it possible to classify compounds by reactivity are called functional groups. A functional group is a part of a larger molecule and is composed of an atom or a group of atoms that have a characteristic chemical behavior. The Chemistry of every organic molecules
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社会历史发展到今天,其管理模式也发生了根本性的变化,即由“统治”(government)到“治理”(governance)的转变。政府统治的权力运行方向是自上而下的,它运用政府的政治权力,通过发号施令,对社会公共事务实行单向度的管理。与此相反,治理则是一个上下互动的管理过程,它主要通过合作、协商、伙伴关系、确立认同和共同目标等方式来实现对社会公共事务的管理,所以治理的权力向度是多元的、相互的。这种“治理”就是公民社会的自治
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Quinones are an interesting and valuable class of compounds because of their oxidation-reduction, or redox, properties. The redox properties of quinones are important to the functioning of living cells, where compounds called ubiquinones(泛醌) act as biochemical oxidizing agents to mediate the electro-transfer processes involved in energy production
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17.1 The Acidity of the α Hydrogens of Carbonyl Compounds: Enolate Anions 17.2 Keto and Enol Tautomers 17.3 Reactions via Enols and Enolate Anions
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