1.H3C-CH3 的命名。 解:7,7-二甲基-1-氯二环[2.2.1]庚烷

1、用氧化数法配平并完成下列氧化还原反应方程式 ① KMnO4+H2C2O4+H2SO4 —→ MnSO4+CO2+K2SO4 ② − − + BrO3 + Br + H —→Br2+H2O

5 Heteronuclear Correlation Spectroscopy H.C-COSY We will generally discuss heteronuclear correlation spectroscopy for x =C(in natura abundance!), since this is by far the most widely used application. However, all this can also be applied to other heteronuclear spins, like 3P, 5N, 1%F,etc In the heteronuclear case, there are some important differences that allow to

第7章有机金属化学(二) 1827年 Zeise盐[PtCl3C2H4 1952年G. Wilkinson Fe(5-C3Hs)2结构的测定 1955年 Fischer n66-芳基化合物 1973年. Wilkinson,分离出W(CH3)6

第一周作业参考答案 3.11011.011(B)=27.375(D)=33.3(O)=1B.6(H) 4.240.75(D)=110000.11(B)=360.6(O)=0.C(H) 5 E3(H)=11100011() E3(H)为原码时,x=-110011(B)=-99(D) E3(H)为反码时,[]原=10011100(B)(x=-11100=-28(D) E3(H)为补码时,[]原=10011101(B),(x=-11101=-29(D) E3(H)为无符号数时,X=E3(H)=227(D) 因为E3(H)的高4位E(H)=14(D)超出了0~9的范围,所以E3(H)不可能为压缩BCD码

利用高温高压反应釜模拟了N80钢在CO2分压1MPa、温度90℃、流速1m·s-1条件下地层水中不同时间的腐蚀行为,并应用SEM、EDS和XRD等微观分析手段研究了腐蚀产物膜的微观形貌、成分和结构特征,探讨了腐蚀产物膜的形成机制.结果表明:在腐蚀开始阶段(8h),腐蚀产物主要为Fe3C,并有少量的FeCO3形成.随着腐蚀的进行(72h后),腐蚀产物膜基本上为FeCO3.腐蚀产物膜由内外两层构成:内层膜是溶液中HCO3-不断透过膜进入膜/基界面与基体反应形成,并使膜/基界面不断向内推进;外层膜是由于溶液中Fe2+和CO32-的浓度超过FeCO3的容度积,FeCO3晶体在内层膜表面形核并长大而形成.外层膜的晶粒比较细小、致密.内层膜与外层膜的界面结合比较弱,而内层膜与基体的结合比较强

1．写出下列各酸的共轭碱：H2O，H2C2O4，H2PO4-，HCO3-，C6H5OH，C6H5NH3+，HS-，Fe(H2O)63+,R-NH+CH2COOH

High temperature corrosion tests in 75%Na2SO4-25%. NaCl molten salt have been conducted on waspalloy specimens plasma sprayed with Co-Cr-B-Si, Ni-Cr-B-Si-hCr3C2, X-40, X-40 + TiC and Ni/Al + Al2O3 coatings, test coupons were exposed isothermally at 750℃up to 200 h. After the corrosion tests, each sample was examined by OM, SEM and EMPA. It was found that X-40, X-40 + TiC and Ni/Al + Al2O3 were violently corroded by the molten salt due to cracking and spalling of the coatings, whereas Co-Cr-B-Si and Ni-Cr-B-Si + Cr3C2 exhibited superior corrosion resistance, which were thought to be related to the formation of chromium and silicon oxide film. A possible corrosion mechanism had been proposed and it is suggested that the excellent corrosion resistance and high hot-hardness of the two B-Si containing coatings may be of significance for applications in petroleum refining industry as

在700℃、3kg/cm2的恒压下进行下列反应 C4H10(A)→2C2H4(B)+H2(C) 反应开始时,系统中的含量为116kg, 当反应完成50%时,丁烷的分压以2.4kg/ cm2·s的速率发生变化,试求下列各项的 变化速率:(a)乙烯的分压;(b)的摩尔数; (c)丁烷的摩尔分率

8.1 Naming Alcohols, Phenols, and Ethers Alcohols Methyl(C has 3 Hs), primary (1 )(C has two Hs, one R), secondary(2)(C has one h twoRs), tertiary (3)(C has no H,3R's)