Orienting effect Free radical substitution 合成邻硝基溴苯和间硝基溴苯的途径 CH,CI 06÷ 0aC微 Oxidation Reduction CH3 KMnOa COOH △ +3H2 N]高压 180-200℃ CH(CH).CH, COOH KMnO △ +2H- Na/NH3 EtOH C(CH) Exercises-1 Exercises-1 完成下列反应方程式 CH,CH-CH2 CH.CH.CH (3) Br2 FeBr; (1) Br2 Fe CH,CH,CH (2) 77 Prepared by Yang R. L. NO2 NO2 Br HNO3 H2SO4 Br2 Fe Br Br NO2 Br O2N Br2 Fe HNO3 H2SO4 + Orienting effect 合成邻硝基溴苯和间硝基溴苯的途径 Prepared by Yang R. L. CH3 CH2Cl Cl2 hv Free radical substitution Prepared by Yang R. L. CH3 KMnO4 COOH CH(CH2 ) 5CH3 KMnO4 COOH KMnO4 C(CH3 ) 3 Oxidation Prepared by Yang R. L. + 3H2 [Ni]高压 180-200°C + 2[H] Na/NH3 EtOH Reduction Prepared by Yang R. L. CH2CH2CH3 (1) Br2 Fe CH2CH2CH3 (2) Cl2 hv Exercises-1 完成下列反应方程式 Prepared by Yang R. L. CH2 CH=CH2 (3) Br2 FeBr3 Br2 hv Br2 CCl4 Exercises-1