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Esters, like aldehydes and ketones, are weakly acidic. When an ester with an alpha hydrogen is treated with one equivalent of a base such as sodium ethoxide, a reversible condensation reaction occurs to yield a β−keto ester product. This reaction between two ester components is known as the Claisen condensation reaction
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Compounds were classified as being either aliphatic or aromatic in the latter part of the nineteenth century. To be classified as aliphatic meant then that the chemical behavior of a compound was “fatlike”. To be classified as aromatic meant then that the compound had a low hydrogen/carbon ratio and that it was “fragrant
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A UV-Vis spectrophotometer measures the amount of light absorbed at each wavelength of the UV and visible regions of the electromagnetic spectrum. λmax— the wavelength of maximum absorption
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A hydrocarbon whose molecules contain two double bonds is called an alkadiene(alkatriene for three double bonds); A hydrocarbon with two triple bonds is called an alkadiyne; A hydrocarbon with a double and triple bond is called an alkenyne
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Conjugated unsaturated systems have a p orbital on a carbon adjacent to a double bond The p orbital can come from another double or triple bond The p orbital may be the empty p orbital of a carbocation or a p orbital with a single electron in it (a radical)
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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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Cycloalkanes with only one ring are named by attaching the prefix cyclo- to the names of the alkanes possessing the same number of carbon atoms
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第一节 裂解过程的化学反应 第二节 裂解原料及产品 第三节 烃类裂解技术 第四节 裂解过程的工艺参数 第五节 管式裂解炉工艺过程 第六节 生产乙烯和丙烯的其他方法 第七节 烃类裂解生产乙炔
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The primary source of alkanes is petroleum Natural gas consists chiefly of methane, but ethane, propane, butane, and isobutane are also present. Petroleum is a complex mixture of hydrocarbons that must be refined into different fraction before it can be used
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Energy and the Relative Stability Kinetic energy is the energy an object has because of its motion. Potential energy is stored energy. It exists only when an attractive or repulsive force exists between objects
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