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A mass spectrometer produces a spectrum of masses based on the structure of a molecule. It is a spectrum or plot of the distribution of ion masses corresponding to the formula weight of a molecule, fragments derived from the molecule, or both
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These spectra are often called carbon magnetic resonance (CMR) spectra or 13C NMR spectra. In some important ways 13C spectra are usually les complex and easier to interpret than proton (1H) NMR spectra
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How are molecular structures determined? One way is though the use of spectroscopic methods. Spectroscopy is the study of the interaction of energy with matter. When energy is applied to matter it can be absorbed, emitted, cause a chemical change, or be transmitted
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There is a group of compounds in which carbon forms only two bonds. These neutral divalent carbon compounds are called carbenes. Most carbenes are highly unstable compounds that are capable of only fleeting existence. Soon after carbenes are formed they usually react with another molecule
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7.1 芳香烃的分类 结构及命名 Classification, Structures and Nomenclature of Aromatic Compounds 7.2 芳香烃的来源及物理性质 Sources and Physical Properties of Aromatic Hydrocarbons
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In the addition of HX to an unsymmetrically substituted alkene, the hydrogen atom adds to the carbon atom of the double bond that already has the greater number of hydrogen atoms and that the X group adds to the carbon having more alkyl substituents. Markovnikov’s rule can be restated by saying that, in the addition of HX to an alkene, the more stable carbocation intermediate is formed
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配位聚合物由金属离子(或金属离子簇)和有机桥连配体通过配位键组装形成,具有一至三维无限结构,可以看做广义的无机一有机杂化材料,可以兼具无机材料和有机材料的一些特点,既有良好的牢固性,又有一定的柔软性
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1. The experimental conditions — temperature and acid concentration — that are required to being about dehydration are closely related to the structure of the individual alcohol. The relative ease with which alcohols undergo dehydration is in the following order:
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10.7 The Geometry of Alkyl Radicals 10.8 Reactions That Generate Tetrahedral Stereocenters 10.9 Radical Addition to Alkenes: TheAnti-Markovnikov Addition ofHydrogen Bromide
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SN2 reactions are highly useful in organic synthesis because they enable use to convert one functional group into another —— functional group transformation (functional group interconversion)
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