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Absolute configuration(Section 7.5): The three-dimensional Activating substituent (Sections 12.10 and 12.12): A group rrangement of atoms or groups at a stereogenic center. that when present in place of a hydrogen causes a particular Acetal(Section 17.8): Product of the reaction of an aldehyde or reaction to occur faster. Term is most often applied to a ketone with two moles of an alcohol according to the substituents that increase the rate of electrophilic aromatic
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SOLUTIONS TO TEXT PROBLEMS 6.1 Catalytic hydrogenation converts an alkene to an alkane having the same carbon skeleton. Since 2-methylbutane is the product of hydrogenation, all three alkenes must have a four-carbon chain with a one-carbon branch. The three alkenes are therefore:
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Chlorotoluene Benzyl chloride Of this group only benzyl chloride is not an aryl halide; its halogen is not attached to the aromatic ring but to an sp-hybridized carbon. Benzyl chloride has the weakest carbon-halogen bond, its measured carbon-chlorine bond dissociation energy being only 293 kJ/mol (70 kcal/mol). Homolytic cleavage of this bond produces a resonance-stabilized benzyl radical
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Dyspnea is defined as an awareness of difficulty in breathing It is therefore a symptom, usually described by the patient as \shortness of breath,\whether the sensation is due to actual difficulty in breathing or is essentially an awareness of hyperventilation. If the symptom becomes striking, it always companies with dilatation of nares, cyanosis, use of accessory muscles of respiration and abnormalities of respiratory rate, depth or rhythm
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Coughing is an essential defense mechanism that it prevents the airways from the foreign substance and clear the excretion of respiratory tract. Coughing is a reflex. permanent and frequent coughing indicates an abnormality
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The packaging sector is an important global industry, representing about 2% of the Gross National Product (GNP) of the developed countries. The value of the packaging industry is about 345 million euros worldwide, of which Europe represents a third. Fifty per cent of this market is packaging for food. Forecasts suggest that the sector will continue to grow in size and importance Many cooking and preservation processes still largely depend on effective packaging, for example canning, aseptic, sous vide and baking processes. Processes such as drying and freezing would be lost without protective packaging after processing to control product exposure to the effects of oxygen light, water vapour, bacterial and other contaminants. However, modern food packaging no longer has just a passive role in protecting and marketing the product. It increasingly has an active role in processing, preservation
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Definition: Dyspnea is defined as an awareness of difficulty in breathing It is therefore a symptom, usually described by the patient as \short of breath,\ whether the sensation is due to actual difficulty in breathing or is essentially an awareness of hyperventilation. If the symptom becomes striking, it always companies with dilatation of nares, cyanosis, use of accessory muscles of respiration and abnormalities of respiratory rate, depth or rhythm
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The PD Process coordinates the specific research activities such as product design, process development, engineering plant design, marketing strategy and desig with the aim of producing an integrated approach to the development of new products. The overall aim is to create a product that an individual consumer or a food manufacturing company or food service organisation will buy. The two parts of product development-the knowledge of the consumer's needs/wants and the knowledge of modern scientific discoveries and technological
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In this chapter we will introduce an important frequency is that network function or parameter reaches a maximum value. In certain simple a networks, this occurs when an impedance or admittance is purely real-a condition known as resonance
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In the chapter we shall introduce the study of circuits characterized by a single energy-storage element--a capacitor or a inductor. It will be shown that the equations describing such a circuit may be put in a form involving an unknown variable and its first derivative. Such an equation is referred to as a first-order differential equation, thus we shall refer to circuits which contain only a single energy-storage element as first-order circuits
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