Adiabatic process In Fig. PⅤ: In reversible process the work A(ply done (below the line ab) is Blp: l: big than the work done (below the line ac)in adiabatic C(:'V,) reversible process
3.1 Common feature of spontaneous change 3.2 The second law of thermodynamics 3.3 Carnot cycle and Carnot principle 3.4 Definition of entropy 3.5 Clausius inequality ; principle of increase of entropy 3.6 Calculate the change of entropy 3.7 Statistical view of entropy 3.9 Direction of change and conditions in equilibrium 3.10 Calculate of G 3.11 Relations of thermodynamic functions 3.12 Clapeyron equation 3.13 The third law and conventional entropy 3.8 Helmholtz function and Gibbs function
4.1 Introduction 4.2 Expressions of concentration 4.3 Partial molar properties 4.4 Two empirical laws in dilute liquid solutions 4.5 Chemical potential of each component in gaseous mixtures 4.6 Liquid mixtures 4.11 Distribution law 4.10 Non-ideal liquid solutions 4.9 Gibbs-Duhem relations 4.8 Colligative properties in dilute liquid solutions 4.7 Chemical potential of each component in dilute liquid solutions