The difference betWeen the systems of CaO-SiO2-H2O and CaO-SiO2-Al(OH)3-H2O, was studied,especially the effect of Al3+ on the crystallinity of tobermorite was focussed. As a result, in the system of CaO-SiO2-H2O, tobermorite formed early, howevey, with reaction time forward, tobermorite was replaced by xonotlite. So far as CaO-SiO2-Al(OH)3-H2O was concemed, hydrothermal reaction was carried out under the same condition as CaO-SiO2-H2O to study the morphological changes of tobermorite crystals. It was found that Al3+ accelerated the crystal growth of tobermorite to some extent and was in favor of platy crystals. Moreover, with the Al3+ content increasing in the starting material, the morphology of tobermorite did not change magnificently, but platy crystals became more and more eminent. As soon as the Al2O3
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REVIEWS The Art and Science of Total Synthesis at the Dawn of the Twenty-First Century** K. C. Nicolaou, Dionisios Vourloumis, Nicolas Winssinger, and Phil S. Baran Dedicated to Professor E. J. Corey for his outstanding contributions to organic synthesis At the dawn of the twenty-first cen-of the most exciting and important covery and invention of new synthetic tury, the state of the art and science of discoveries of the twentieth century in strategies and technologies; and explo- vnth
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Nobel Lecture december 13. 1946 The history of the discovery of the exclusion principle m, for which I have received the honor of the Nobel Prize award in the year 1945, goes back to my students days in Munich. While, in school in Vienna, I had already ob- tained some knowledge of classical physics and the then new Einstein rel- ativity theory, it was at the University of Munich that I was introduced by Sommerfeld to the structure of the atom- somewhat strange from the point of view of classical physics. I was not spared the which every
