1. 熟悉配位化合物的基本概念、组成和命名； 2. 熟悉配位化合物的价键理论，会进行一般配离子结构判断和磁性计算； 3. 理解晶体场理论的要点，弄清八面体场、四面体场和平面四边形场中 d 轨道的分裂；理解分裂能和晶体场稳定化能概念; 4. 了解配位化合物顺反异构和旋光异构概念，初步学会上述两种异构体的判断； 5. 熟悉配位实体热力学稳定性中的有关概念。 7.1 相关的定义和命名 The relating definitions and nomenclature 7.2 配合物的化学键理论 Chemical bond theory of coordination compound 7.3 配位化合物的异构现象 Isomerism of coordination compound 7.4 配位实体的热力学稳定性 Thermodynamic stability of the coordination entity 7.5 配位实体的某些动力学问题 Some kinetic questions of the coordination entity

5. 1 The Government Bond Market 5.1.1 when the government runs a deficit, it has to get the funds. There are three ways for the government to get funds

Homoannular Heteroannular (cisoid) (transoid 1=214nm Parent 1=253nm 217(acyclic) Increments for Double bond extending conJugation

4.1 Addition of hx to Alkenes. p100 Hydrohalogenation General reaction mechanism: electrophilic addition Attack of electrophile(such as hBr)on T bond of alkene Produces carbocation and bromide ion Carbocation is an electrophile, reacting with nucleophilic bromide ion

What is an alkyl halide An organic compound containing at least one carbon-halogen bond (C-X) X(F, Cl, Br, Replaces h Can contain many C-X bonds

Definitions Conjugated double bonds are separated by one single bond. Example: 1, 3-pentadiene. Isolated double bonds are separated by two or more single bonds. 1, 4-pentadiene. Cumulated double bonds are on adjacent carbons. Example: 1, 2-pentadiene

To determine reaction''s mechanism, look at: Equilibrium constant Free energy change Enthalpy Entropy Bond dissociation energy Kinetics >Activation energy

一、什么是蛋白质? 蛋白质(protein)是由许多氨基酸 amino acids)通过肽键(peptide bond)相连形成的高分子含氮化合物