《物理化学实验》课程教学资源（书籍文献）Handbook of Electrochemical Constants.pdf_大学文库

CONTENTSBUTTERWORTHS PUBLICATIONSLTDFUNDAMENTAL CONSTANTS AND PROPERTIES OF8SKINGSWAY,LONDON,W.C.2IONS,SALTS AND SOLVENTSPageAFRICA:BUTTERWORTH&CO.(AFRICA)LTD1.Values of Important ConstantsDURBAN:33/35BeachGrove".2.Ionio Radii and Ionization Potentials2BUTTERWORTH&CO.(AUSTRALLA)LTDAUSTRALIAtt...SYDNEY:8O'Connell Street3.Electron Afinities of the Atoms6...MELBOURNE:430BourkoStreet4.Work of Extraction of an Electronfrom Various Metals6BRISBANE:240QueenStreet5.Lattico Energiesof Saltsof Univalont Cations7......CANADA:BUTTERWORTH&CO.(OANADA)LTD6.LattioeEnergies ofSalts of Polyvalent Cations7.....TORONTO:1367DanforthAvenue7.Phyaical Properties of Water..8+NEWZEALAND:BUTTERWORTH&CO.(AUSTRALIA)LTD8.Properties of SomeOrganicSolvents9WELLINGTON:49/51BallanceStreet9.Dielootric Constants of Mixtures of Water and Organic Solvents ..10AUCKLAND:35HighStreet10.Dieloctric Constants of Methanol+Water Mixtures11....U.S.A.Editionpublished by1l.Paramoters for the Equation logio eA-Bt111...ACADEMIC PRESSINC.PUBLISHERS12.DiolectricConstante of Some Inorganic Solvents12·IIIFIFTHAVENUENEWYORK3,NEWYORKNUMERICALVALUESOFSOMEFUNCTIONSUSEDINh6866133THE THEORY OF ELECTROLYTES13.Theoretical Coofficients for Uni-uni-valent Eloctrolytes in WaterCOLLEGEHARRISandValuesof RTIn10/F1314.The Parameter for Use in Equationsfor Extrapolation of ApparentPRESTONMolel Volumes and ApparentMolal Heat Contents15.15.TheFuoss Extrapolation Function..17PA.++..$4137L16.TheShodlovskyExtrepolationFunetion18......I7.Bjerrum'sFunction19......802018.Extended Terms of the Dobye-Hickel Theory19..++福ACTIVITYCOEFFICIENTS19.Stoichiometrie Mean Molal Activity Coefficients for AquoousInorganicElectrolytes at 25°C20..20.Stoichiometrio Mean Molal Activity Coefficients for AqueousCSolutions of Salts of OrganieAcids at25°C26Butterworths Publications Limited2l.Stoichiometrie Monn Molal Activity Coefficients for Concentrated1959AqueousInorganioElectrolytesat25°C2822. Tho Ionic Activity Function of Water nyon/ango in Salt Solutions3023.Values of theConstantsnand 3024.Values of the Constants a,B and D.3125.Stoichiometric Mean Molal Aotivity Coofficients at 25°CforSolutions of Hydrochlorie Acid in Non-aquoous Solvents andAqueous-non-aqueous Mixtures3126.Stoichiometrio Mean Molal ActivityCoefficionts for H,SO4 inMadeand printedinGreatBrilainNon-aqueous Solvents and Aqueous-non-aqueous Mixtures atby William Clowes and Sons,Limited,London and Beccles25°03327,Stoichiometric Mean Molal Activity Coefficienta of Salte in Methanol+WaterMixturesat25°C33..1

viCONTENTSCONTENTSviTHERMODYNAMIC PROPERTIES OF HCI ANDNaOHMOLALVOLUMES OF ELECTROLYTES AND THEIRPage28.Thermodynamic Properties of Hydrochloric Acid Solutions inTEMPERATURE ANDPRESSUREDEPENDENCEPageWater...34605l.ApparentMolal Volumes inAqueous Solution29.Thermodynamic Properties of Sodium Hydroxide Solutions in52.Apparent Molal Expansibility and Integral Coeficients of ExWater..3761..pansion inAqueous Solutionsat25°C andIatm......53.Integral Coefficient of Expansion and Apparent Molal Thermal61ExpansibilityinAqueousSolutionatatm:6254.ApparentMolalCompressibilityinAqueousSolution at25°CTHERMALPROPERTIES OFELECTROLYTES6255.ApparentMolalVolumesinAqueousSolutionat25°C30.RelativePartial Molal Heat Content of SolutesinAqueous Solutionsat25°℃..4031.Thermal Properties of Solvent and Solute for CeCly and NdCly atMOLTENSALTS25°04163..56:Conductivityof MoltenSaltMixtures232.Rolative Partial Molal Heat Content for Cd Salt Solutions416457.Rational Activity Coefficients for Salts in Molten Salt Mixtures33.Heat Content and Heat CapacityDataforNaClinAqueous Solution6558.E.M.F.of Colls Containing MoltenSalts..+++...atVariousTemperatures416559.ConductanceofPureMoltenSalts..34.Thermal Properties of Solvent and Solute for LaCly and La2(SO4)3at25°℃42.35.Hent Content andHeat CapacityforAqucousHBrat25°C42EQUILIBRIUMPROPERTIESOFELECTRODES36.Integral Heats of Solution of Rare Earth Chlorides at 25°C inWater6660.ThermodynanicFunctions forIons in Aqueous Solution4237.Heat Content and Heat Capacity Data for Aqueous Solutions of6l.Thermodynamic Functions for Ions inLiquid Ammonia68HFat25°C4262.Thermodynamie Functions for Ions inMethanol +Water38.Constants fortheEquations L-L2(0°)+at+βe andJ2α+βl6843Mixtures39.Relative Partial Molal Heat Content for H,SO,(L2)in iso-Propanol63.Standard ElectrodePotentials (Reduction Potentials)for Inorganic+WaterMixtures6943Systemsat25°C40.ConstantsfortheEquationsL2-α+βTeandJ2=2βTand LzandJ264. Standard Electrode Potentials (Roduction Potentials) in Non-at25°073aqueous Solutions at 25°℃C..41. Relative Partial Molal Heat Content of Solute and Solvent in65.Standard E.M.F.on MolalitySeale of the Cell H2/HCl/AgCl, Ag inAqueousSolutionsof AminoAcidsat25°C74Various Solvents at Various Temperatures45....66,Standard E.M.F.on Molality Scale for Various Cells at Various75Temperatures67.pH Values for Steandard Solutions at 25°C75...75EQUILIBRIUM CONSTANTS IN SOLUTION68.pHValuesforStandardSolutionsfrom0°Cto60°C69.Potential of Zero ChargeforVarious Electrode Materials inAqueous42.ThermodynamieAcid Dissociation Constants4676SolutionsatRoomTemperature43.Dissociation Constants of Inorganic Acids in Aqueous Solution at.25°C52...44.IonicProductforD,OinpureDO53VISCOSITY ANDDIFFUSIONIN ELECTROLYTES45.Average Thermodynamic Dissociation Constants for Ion pairs at25°CinAqueous Solution7670.ViscosityofMethanoliSaltSolutions54..46.Average Thermodynamic Disaociation Constants of Ion pairs in777l,Viscosityof Aqueous Salt Solutions*+...Aqueous-non-aquoous Mixtures and Non-aqueous Solution at72.Differential Diffusion Cocficients forDilute Aquoous Solutions7825°05673. Ionie Diffusion Coefficients and Activation Energies for Diffusion47.SolubilityProducts in Aqueous Solution at25C5679forthe Infinitely Dilute Aqueous Solution.48.SolubilityProducts in Non-aqueous Mixtures at25°C5874.Differential Self-diffusion Coofficients of Ions in Aqueous Solutions.49.SolubilityProducts forSilver Halides inAqueous Solution6980ofSaltsat25°0..50.The Effect of Pressure upon the Equilibrium Constants of Some8075.IntegralDiffusionCoefficients for AqueousKCl at 25°C...Ionic Roactions in Aqueous Solution598176. Conductance in Dilute Aqueous Solutions.......+

viliCONTENTSCONDUCTIVITY OF ELECTROLYTES1.VALUESOF IMPORTANT CONSTANTSPage77.Specific Conductivity of Standard Aqueous Potassium Chloride(N, F and R for the chemical mole)82Solution.-+tt8378.Conductance in Dilute Non-aqueous Solutions...1AVOGADRO'SNUMBER8579.Limiting IonicMobilities in Aqueous Solution...N=(6-0230±0-0002)x1023mole-18680.Limiting IonicMobilities in Methanol...486SlConstantsfortheEauationt=B+A/e1.CHARGE ON THE ELIECTRON82.Cation Transport Numbers at 25°C in Aqueous Solution ande-(4-80294±0-00008)×10-10e.s.u86ConstantsfortheLimitingEquationt+=t,+AVc=160209±0-00003)×10-20e.m.18783.CationTransportNumbersforH,SO,in AqueousSolution(1-60209±0·00003)×10-19coulomb8784.Cation Transport Numbers in Aqueous Solution8785.CationTransportNumbersat25°C..FARADAY CONSTANT88S6.CationTransportNumbersinWater at25°C：..F=(9,649-3±0-2)e.m.u.equivalent-188$7.CationTransport Numbers in Anhydrous H,SO4at 25°C..(96,493±2)coulombequivalont-1Ss.Cation Transport Numbors for HCl in Water and Dioxan+89WaterMixturesGAS CONSTANT89.Cation TransportNumbers in Anhydrous Aootic Acid at25°C90R=(8-3147± 0-00005)joule deg.-1mole-1=(1-9872±0-00001)cal.deg.-1mole-1KINETICPROPERTIES OF ELECTRODES=(0-082057±0-0000005) 1.atm.deg.-1mole190. Polarographic Half-wane Potentials of Some Cations in Various91Solutions...BOLTZMANN'S OONSTANT9391,Anodic Depolarization Potentials.++ +k=(1-38049±0-00005)×10-16ergdeg.-19392.Inorganic Oxidation ReductionPotentials...9493.PolarographieReductionPotentialsof Inorganic CompoundsICR POINT94.Tafel Constantaand Heats of ActivationforHydrogenEvolutionToC=(273-1500±0-0002)K95from Agueous Solution95.Tafel Constants and Heats of Activation forHydrogen EvolutionVELOCITY OFLIGHTfrom Non-aqueous Solution97C=(2-997928±0-000004)×1010cmsec-196.Parameters for the Deposition of Metals on a Substrate of the SameMetal atRoomTemperaturefromAqueous Solution97PLANCE'S OONSTANT97.ParametersfortheEvolutionofVariousGasesatInert Electrodesh=(6-6254±0-0002)×10-27org.8ec98in Aqueous Solution..98.Parameters for the Deposition of Metals from 10-3r Aqueous SaltSTANDARD ATMOSPHEBE98Solution in Iar Supporting Solution on toDiluteAmalgam at 20°C1 atm.=1,013,250 dynecm-299.Parameters for Oxidation-Reduction Reactions at Electrodes in98AqueousSolutionSTANDARD GRAVITATIONALACCELEBATION9o=980·665cm:so~1SURFACE TENSION,DIELECTRIC CONSTANT ANDREERAOTIVITYDEFINED CALORIEloo.SurfaceTensionandApparentRelativeSurfaceTensionofAqucous1cnl.=4-1840joules99Salt Solutions..101.Dielectric Conatant of Aqueous Solutions at 25°C101RRLATION BETWICEN CHEMICAL AND PHYSICAL MOLE102.EquivalentRefractionof IonsinInfinitelyDiluteAqueousSolution1 phys.mole =1.000 275.chem.mole101at25℃..RELATIONBETWEEN LITREAND CUBIC CENTIMETREAPPENDIX11.=(1,000-028±0-004)cm102103.Properties of Inorganic Compounds and Molten Salts..1i11104.Electrical and Magnetic Units