Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical ChemistryInorganic and Analytical ChemistryS/N:10421040Classification: Specialized Basic CourseApplicable to: Chemical Engineering and TechnicsFood Science and EngineeringPharmaceutical EngineeringMaterials Science andBiological EngineeringEngineeringTotal Hours for Theory: 68Credit Points: 68Requirements on Foundation Course:Advanced MathematicsWritten by: Zhang LiqingA.Characteristics and StatusAs the first compulsory basic course of chemistry for majors of chemical engineering and technics, foodscience and engineering,biological engineering,pharmaceutical engineering, materials science andengineering and so on in the institutions of higher learning, inorganic and analytical chemistry is not onlyan important component ofcultivating integral knowledge structureandcapability structure ofengineeringand technicaltalentsofthe said majors,but also afoundationforthe subsequent specializedcoursesB. Teaching TargetsThe course aimstoenable students to master basictheories of substance structure,basicprinciples and application of chemical reaction, basic knowledge of element chemistry,knowledge of and relations among structure, equilibrium, characteristic and application, toresolve general problems of inorganic and analytical chemistry with its theories, to select testapproaches of analytical chemistry, estimate and express test results correctly, and to layfoundation for resolving real problems existing in production and scientific researchesthrough classroom lecturing and close combination with test course of inorganic andanalytical chemistry. Furthermore, through the establishment of strict concept of “quantity",this course also aims to cultivate students'good learning habits, rigorous scholarship,practical and realistic attitude toward science and ability of analyzing and resolving problemsso that students will acquire scientific qualities necessary to scientific and technical personnelgradually.C.Teaching Contents, Basic Requirements and Time AllocationIntroductionTo find out major contents of the course of inorganic and analytical chemistry and theirmutual relations, master learning approaches of this course, understand requirements onlearning this course, learn about targets and characteristics of inorganic and analyticalchemistry, and find out the classification and evolvement of analytical approaches.MajorContentso.1Objectsandcontentsofchemicalresearch-
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 1 Inorganic and Analytical Chemistry S/N: 10421040 Classification: Specialized Basic Course Applicable to: Chemical Engineering and Technics Food Science and Engineering Biological Engineering Pharmaceutical Engineering Materials Science and Engineering Total Hours for Theory: 68 Credit Points: 68 Requirements on Foundation Course: Advanced Mathematics Written by: Zhang Liqing A. Characteristics and Status As the first compulsory basic course of chemistry for majors of chemical engineering and technics, food science and engineering, biological engineering, pharmaceutical engineering, materials science and engineering and so on in the institutions of higher learning, inorganic and analytical chemistry is not only an important component of cultivating integral knowledge structure and capability structure of engineering and technical talents of the said majors, but also a foundation for the subsequent specialized courses. B. Teaching Targets The course aims to enable students to master basic theories of substance structure, basic principles and application of chemical reaction, basic knowledge of element chemistry, knowledge of and relations among structure, equilibrium, characteristic and application, to resolve general problems of inorganic and analytical chemistry with its theories, to select test approaches of analytical chemistry, estimate and express test results correctly, and to lay foundation for resolving real problems existing in production and scientific researches, through classroom lecturing and close combination with test course of inorganic and analytical chemistry. Furthermore, through the establishment of strict concept of “quantity”, this course also aims to cultivate students’ good learning habits, rigorous scholarship, practical and realistic attitude toward science and ability of analyzing and resolving problems, so that students will acquire scientific qualities necessary to scientific and technical personnel gradually. C. Teaching Contents, Basic Requirements and Time Allocation Introduction To find out major contents of the course of inorganic and analytical chemistry and their mutual relations, master learning approaches of this course, understand requirements on learning this course, learn about targets and characteristics of inorganic and analytical chemistry, and find out the classification and evolvement of analytical approaches. Major Contents 0.1 Objects and contents of chemical research
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalyticalChemistry0.2 Major contents of the course of inorganic and analytical chemistry0.3 Learning approaches for the course of inorganic and analytical chemistry0.4Requirementsonlearningthecourseof inorganicand analytical chemistryKeyPoints1. Learning approaches for the course of inorganic and analytical chemistry2.Requirements on learning the course of inorganic and analytical chemistryNodusKnowledge of and relations among structure, equilibrium, characteristic and applicationinteaching contents of inorganic and analytical chemistryChapter 1 Chemometrics and Error and Data ProcessingTo find out basic steps of general analytical course (sampling,pre-processing, measurementand result calculation),to establish the concept of “quantity"clearly, to master basicknowledge of error,causes of error and ways of reduction and avoiding,basic approaches ofdata processing, application of significant data, rejection of doubtful data and correctformulation of analytical results, to learn about concepts of confidence level and confidenceinterval.to master basic concepts of titrimetric analysis.application oftitrimetricanalysis andcalculation methods of titrimetric analysis, and to learn about the evolvement of titrimetricanalysis.Major Contents1.1 Measurement and stoichiometric calculation in chemical reaction1.1.1 Measurement in chemistry and International System of Units1.1.2Introductiontotitrimetric analysis1.1.3Measuringrelations and stoichiometric calculation inchemicalreaction1.2Error and significant figure1.2.1Classification oferror1.2.2 Reduction and avoiding of error1.2.3Formulation of Error1.3Significant figure1.4Processingoftestdata1.4.1 Formulation of testing results1.4.2Confidence level andconfidence intervalKeyPoints:1. Basic steps of general analytical course (sampling, pre-processing, measurement andresultcalculation)2.Basicknowledge oferror3. Causes of error and ways of reduction and avoiding, and basic methods of dataprocessing4.Basic concepts and calculation methods oftitrimetric analysis5. Application of significant data, rejection of doubtful data and correct formulation ofanalytical resultsNodus:1. Rejection of doubtful data and correct formulation of analytical results2.Confidencelevel and confidence interval2
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 2 0.2 Major contents of the course of inorganic and analytical chemistry 0.3 Learning approaches for the course of inorganic and analytical chemistry 0.4 Requirements on learning the course of inorganic and analytical chemistry Key Points: 1. Learning approaches for the course of inorganic and analytical chemistry 2. Requirements on learning the course of inorganic and analytical chemistry Nodus: Knowledge of and relations among structure, equilibrium, characteristic and application in teaching contents of inorganic and analytical chemistry Chapter 1 Chemometrics and Error and Data Processing To find out basic steps of general analytical course (sampling, pre-processing, measurement and result calculation), to establish the concept of “quantity” clearly, to master basic knowledge of error, causes of error and ways of reduction and avoiding, basic approaches of data processing, application of significant data, rejection of doubtful data and correct formulation of analytical results, to learn about concepts of confidence level and confidence interval, to master basic concepts of titrimetric analysis, application of titrimetric analysis and calculation methods of titrimetric analysis, and to learn about the evolvement of titrimetric analysis. Major Contents 1.1 Measurement and stoichiometric calculation in chemical reaction 1.1.1 Measurement in chemistry and International System of Units 1.1.2 Introduction to titrimetric analysis 1.1.3 Measuring relations and stoichiometric calculation in chemical reaction 1.2 Error and significant figure 1.2.1 Classification of error 1.2.2 Reduction and avoiding of error 1.2.3 Formulation of Error 1.3 Significant figure 1.4 Processing of test data 1.4.1 Formulation of testing results 1.4.2 Confidence level and confidence interval Key Points: 1. Basic steps of general analytical course (sampling, pre-processing, measurement and result calculation) 2. Basic knowledge of error 3. Causes of error and ways of reduction and avoiding, and basic methods of data processing 4. Basic concepts and calculation methods of titrimetric analysis 5. Application of significant data, rejection of doubtful data and correct formulation of analytical results Nodus: 1. Rejection of doubtful data and correct formulation of analytical results 2. Confidence level and confidence interval
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalyticalChemistryChapter 2Basic Principles ofChemical ReactionTo learn about concepts of rate equation of chemical reaction (law of mass action) andreaction orders, to master factors of influencing rate of chemical reaction, and to know waysof formulating the influence of concentration, partial pressure, temperature and activatortoward rate of reaction by using concepts of activation energy and molecule.To master rules of chemical equilibrium and equilibrium movement, to be capable ofcalculating the components of equilibrium with equilibrium constant (k°), and to understandthe factorsneeds calculating syntheticallyfor rate of reactionand chemical equilibrium inpractical use.Major Contents:2.1Rateofchemicalreactionanditsaffectingfactors2.1.1 Rate of chemical reaction2.1.2 Affecting factors of rate of chemical reaction2.2 Processing limit of chemical reaction2.2.1Chemical equilibrium and equilibrium constant2.2.2 Movement of chemical equilibriumKeyPoints:1. Rules of chemical equilibrium and equilibrium movement and to be capable ofcalculating the components of equilibrium with equilibrium constant (k°)2.Concepts of rate equation of chemical reaction (lawof mass action)and reaction orders3.Affecting factors of rate ofchemical reactionNodus:1.Formulatingthe influence of concentration,partial pressure,temperature andactivatortoward rate of reaction by using concepts of activation energy and molecule2. Processing and calculation concerned with chemical equilibriumChapter3Acid-base Equilibrium&Acid-base TitrationInthischapterwecanlearnthebasicnotionofthetheoryofBronsted-Lowry,theconceptofthe activity,status of the strong electrolytesolution,understand thecontents and correlativecalculations of dissociationdegreeof weak electrolyte,dilutionlaw,acidity of solution andpH, dissociation equilibrium (include grade dissociation equilibrium), common ion effect,buffer solution and so on, master the principle of method oftitration, titration curve, end pointjudge , end point error and so on ,understand the law of pH changing in various processes ofacid-base titration and the way of choosing the right indicator.MajorContents:3.1Theory of Bronsted-Lowry and acid-base equilibrium3.1.1 Acid-base dissociation equilibrium and constant of dissociation equilibrium3.1.2Relation between Ka &Kb of conjugated pair of acid-base3.2 Moving of acid-base dissociation equilibrium3.2.1 Dilution law3.2.2 Common ion effect,3.2.3 Activity, ionic strength and salt effect3.3Distributing of constituents in acid-base dissociation equilibrium and the calculationoftheconcentration3
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 3 Chapter 2 Basic Principles of Chemical Reaction To learn about concepts of rate equation of chemical reaction (law of mass action) and reaction orders, to master factors of influencing rate of chemical reaction, and to know ways of formulating the influence of concentration, partial pressure, temperature and activator toward rate of reaction by using concepts of activation energy and molecule. To master rules of chemical equilibrium and equilibrium movement, to be capable of calculating the components of equilibrium with equilibrium constant (Kș ), and to understand the factors needs calculating synthetically for rate of reaction and chemical equilibrium in practical use. Major Contents: 2.1 Rate of chemical reaction and its affecting factors 2.1.1 Rate of chemical reaction 2.1.2 Affecting factors of rate of chemical reaction 2.2 Processing limit of chemical reaction 2.2.1 Chemical equilibrium and equilibrium constant 2.2.2 Movement of chemical equilibrium Key Points: 1. Rules of chemical equilibrium and equilibrium movement and to be capable of calculating the components of equilibrium with equilibrium constant (Kș ) 2. Concepts of rate equation of chemical reaction (law of mass action) and reaction orders 3. Affecting factors of rate of chemical reaction Nodus: 1. Formulating the influence of concentration, partial pressure, temperature and activator toward rate of reaction by using concepts of activation energy and molecule 2. Processing and calculation concerned with chemical equilibrium Chapter 3 Acid-base Equilibrium & Acid-base Titration In this chapter we can learn the basic notion of the theory of Brønsted-Lowry, the concept of the activity, status of the strong electrolyte solution, understand the contents and correlative calculations of dissociation degree of weak electrolyte, dilution law, acidity of solution and pH, dissociation equilibrium (include grade dissociation equilibrium ) , common ion effect, buffer solution and so on, master the principle of method of titration, titration curve, end point judge , end point error and so on ,understand the law of pH changing in various processes of acid-base titration and the way of choosing the right indicator. Major Contents: 3.1 Theory of Brønsted-Lowry and acid-base equilibrium 3.1.1 Acid-base dissociation equilibrium and constant of dissociation equilibrium 3.1.2 Relation between Ka & Kb of conjugated pair of acid-base 3.2 Moving of acid-base dissociation equilibrium 3.2.1 Dilution law 3.2.2 Common ion effect, 3.2.3 Activity, ionic strength and salt effect 3.3 Distributing of constituents in acid-base dissociation equilibrium and the calculation of the concentration
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry3.3.1Distribution factoranddistributioncurve3.3.2 Calculation about equilibrium concentrations of constituents3.4Calculation of solution acidity3.4.1Confirmation of proton balance equation3.4.2Calculationofacidityofweakmono-acid(alkali)3.4.3 Calculation of acidity of ampholyteric compound solution3.5 Control and detection of the solution acidity3.5.1 Acid-base buffer solution3.5.2 Acid-base indicator3.6Acid-basetitration3.6.1 Strong alkali (acid) titrate strong alkali(acid)3.6.2 Strong alkali (acid) titrate weak mono-acid (alkali)3.6.3 Titration of polyatomic acid and mixed acid3.6.4Applicationofacid-basetitrationKey Points:1. The contents and correlative calculations of dissociation degree of weak electrolytedilution law, acidity of solution and pH, dissociation equilibrium, common ion effect,buffersolutionand soon2. Basic concepts of acid-base titration (titration, end point, stoichiometric point, indicator,standard solution, standard substance)3. Principle of acid-base titration analysis, titrate curve, end point judgement, end pointerror4.Application of acid-base titration and calculation oftitration result.Nodus:1. The law of pH changing in various processes of acid-base titration and the way ofchoosing the right indicator.2.Distributionfactoranddistributioncurve,confirmationof protonbalanceequation3. Calculation of acidity of ampholyteric compound solution, and titration of the mixedacid and polyatomic acidChapter 4Precipitation-dissolution Equilibrium &Precipitation Testing MethodIn this chapter we can learn contents and relative calculations about precipitation-dissolutionequilibrium,solubility product principle and so on, learn how to judge whether precipitationor dissolution will come out with the solubility product principle, master calculation offractional precipitation,learn the principleof precipitation titration analysis,end point judge,understand the applicationof precipitationtitration analysis and calculation oftitrationresultlearn the feature of gravimetric method and its principle and process.Major Contents:4.1 Formation of precipitation and dissolution equilibrium4.1.1 Solubility product principle and solubility4.1.2Dominant factor for solubility4.2Solutionofprecipitation,fractionalprecipitationandinversionofprecipitation4.2.1Fractional precipitation4.2.2 Application of fractional precipitation4.2.3 Inversion of precipitation4
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 4 3.3.1 Distribution factor and distribution curve 3.3.2 Calculation about equilibrium concentrations of constituents 3.4 Calculation of solution acidity 3.4.1 Confirmation of proton balance equation 3.4.2 Calculation of acidity of weak mono-acid (alkali) 3.4.3 Calculation of acidity of ampholyteric compound solution 3.5 Control and detection of the solution acidity 3.5.1 Acid-base buffer solution 3.5.2 Acid-base indicator 3.6 Acid-base titration 3.6.1 Strong alkali (acid) titrate strong alkali(acid) 3.6.2 Strong alkali (acid) titrate weak mono-acid (alkali) 3.6.3 Titration of polyatomic acid and mixed acid 3.6.4 Application of acid-base titration Key Points: 1. The contents and correlative calculations of dissociation degree of weak electrolyte, dilution law, acidity of solution and pH, dissociation equilibrium, common ion effect, buffer solution and so on. 2. Basic concepts of acid-base titration (titration, end point, stoichiometric point, indicator, standard solution, standard substance) 3. Principle of acid-base titration analysis, titrate curve, end point judgement, end point error 4. Application of acid-base titration and calculation of titration result. Nodus: 1. The law of pH changing in various processes of acid-base titration and the way of choosing the right indicator. 2. Distribution factor and distribution curve, confirmation of proton balance equation 3. Calculation of acidity of ampholyteric compound solution, and titration of the mixed acid and polyatomic acid Chapter 4 Precipitation-dissolution Equilibrium & Precipitation Testing Method In this chapter we can learn contents and relative calculations about precipitation-dissolution equilibrium , solubility product principle and so on, learn how to judge whether precipitation or dissolution will come out with the solubility product principle, master calculation of fractional precipitation, learn the principle of precipitation titration analysis, end point judge, understand the application of precipitation titration analysis and calculation of titration result, learn the feature of gravimetric method and its principle and process. Major Contents: 4.1 Formation of precipitation and dissolution equilibrium 4.1.1 Solubility product principle and solubility 4.1.2 Dominant factor for solubility 4.2 Solution of precipitation ,fractional precipitation and inversion of precipitation 4.2.1 Fractional precipitation 4.2.2 Application of fractional precipitation 4.2.3 Inversion of precipitation
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry4.3 Formation of precipitation4.3.1 Kinds of precipitation4.3.2 Formation of precipitation4.3.3Factorfor purityof precipitation4.3.4Measureforgoodpureprecipitation4.4 Precipitation testing method4.4.1Gravimetric method4.4.2Precipitation titration analysisKeyPoints:1. Precipitation-dissolution equilibrium, solubility product principle2. Judge whether precipitation or dissolution will come out with the solubility productprinciple, feature of gravimetric method and its principle and process.3.Application of precipitation titration analysis and calculation oftitration resultNodus:1.Fractional precipitation and relative calculation2.Principle of precipitation titration analysis and end point judge3.Application of precipitation titration analysis and calculation of titration resultChapter5RedoxEquilibriumandRedoxTitrationIn this chapter we can learn contents and relative calculations about redox equilibrium,electrode potential and so on, understand the principle of redox titration, learn the way ofchoosing the right condition for redox titration, master application of redox titration analysisand calculation of titrationresultMajor Contents:5.1 Redox reaction and electrode potential5.1.1Oxidation number5.1.2 Balancing of equation of redox reaction5.2.1 Primary battery5.2.2 Electrode potential5.2.3 Standard electrode potential5.2.4Factorforelectrodepotential5.2.5 Conditional potential5.3 Applicationofelectrodepotential5.3.1 Calculation of electromotive force of primary battery5.3.2 Judge the direction of redox reaction5.3.3Judgethelimitationof redoxreaction5.3.4Calculationofrelativeequilibriumconstant5.3.5Chart of standard electrodepotential ofelements5.4 Reaction rateofredoxreaction5.5 Redoxtitration5.5.1Redox titrate curve5.5.2Detectionoftheendofredoxtitration5.5.3 Redox titration analysis5.5.4 Calculation of redox titration resultKey Points:5
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 5 4.3 Formation of precipitation 4.3.1 Kinds of precipitation 4.3.2 Formation of precipitation 4.3.3 Factor for purity of precipitation 4.3.4 Measure for good pure precipitation 4.4 Precipitation testing method 4.4.1 Gravimetric method 4.4.2 Precipitation titration analysis Key Points: 1. Precipitation-dissolution equilibrium, solubility product principle 2. Judge whether precipitation or dissolution will come out with the solubility product principle, feature of gravimetric method and its principle and process. 3. Application of precipitation titration analysis and calculation of titration result Nodus: 1. Fractional precipitation and relative calculation 2. Principle of precipitation titration analysis and end point judge 3. Application of precipitation titration analysis and calculation of titration result Chapter 5 Redox Equilibrium and Redox Titration In this chapter we can learn contents and relative calculations about redox equilibrium, electrode potential and so on, understand the principle of redox titration, learn the way of choosing the right condition for redox titration, master application of redox titration analysis and calculation of titration result. Major Contents : 5.1 Redox reaction and electrode potential 5.1.1 Oxidation number 5.1.2 Balancing of equation of redox reaction 5.2.1 Primary battery 5.2.2 Electrode potential 5.2.3 Standard electrode potential 5.2.4 Factor for electrode potential 5.2.5 Conditional potential 5.3 Application of electrode potential 5.3.1 Calculation of electromotive force of primary battery 5.3.2 Judge the direction of redox reaction 5.3.3 Judge the limitation of redox reaction 5.3.4 Calculation of relative equilibrium constant 5.3.5 Chart of standard electrode potential of elements 5.4 Reaction rate of redox reaction 5.5 Redox titration 5.5.1 Redox titrate curve 5.5.2 Detection of the end of redox titration 5.5.3 Redox titration analysis 5.5.4 Calculation of redox titration result Key Points:
Inorganic and Analytical ChemistrySyllabus of Zhejiang University of Science and Technology1. Contents and relative calculations about redox equilibrium, electrode potential etc.2.Basic concepts of redox titration analysis (titration, end point, stoichiometric point,indicator, standard solution, standard substance)3. Principle of redox titration analysis, titrate curve, end point judge, end point error andfeasibilityoftitration4. Application ofredox titration analysis and calculation oftitration result.Nodus1.Ways of choosingtheright conditionforredoxtitration2. Principles of redox titration analysis ,titrate curve, end point judge, end point error andfeasibilityoftitration3.Applications ofredox titration analysis and calculation oftitration resultChapter 6Atomic Structureand PeriodicProperties of theElementsIn this chapter, we need to know about some concepts of atomic structure, such as themovement of extranuclear electron,atomic energylevel,probabilitydensity,atomic orbital,and wavefunction.Alsounderstandhowtodescriptthemovementofextranuclear electronwith the four quantum numbers, as well as the configurations and directions of s, p, and dorbital.Moreover,we should master somegeneral rulesoftheconfiguration ofextra-nuclearelectron,characteristicsofvalenceelectronofmaingroupandtransitionelements,andlearnto estimate the properties of the elements according to its electronic shell structures. In thischapter, we also need to know the periodic variation of atomic radius, ionization energy,electron affinity energy as well as electronegativity, and to understand the formation,characteristic (directivity and saturation), and types of bonding (o bond and bond) in theview of valence bond theory. Further more, we should master the types of hybrid orbitals (sp,sp2, sp'), which are relative with the molecular configurations. To illustrate molecularstructures and magnetic properties,we also should understand some concepts of molecularorbitals. Finally, we should known some types of crystals and its structural characteristics,Born-Haber cycle, and that how crystal lattice influences the melting point and hardness ofionic compounds, and that how to effect the properties of matter by the means of ionicpolarization,intermolecularforcesandhydrogenbondMajorContents:6.1 The Models of Atomic Structure6.1.1The Bohr Model of Atomic Hydrogen6.1.2TheQuantumMechanicsModel6.2TheMovementofExtranuclearElectron6.2.1TheSchroodingerEquation6.2.2 The Wave Functions and the Atomic Orbitals6.2.3 The Four Quantum Numbers6.2.4 The Angular Distribution Pattern of Atomic Orbital6.2.5PatternsofElectronCloud6.3TheElectronic Shell Structures of theAtoms and The Periodic System6.3.1 The Configuration of Extra-nuclear Electron of polyelectron Atoms6.3.2 The Electronic Shell Structures of the Atoms and the Periodic System6.3.3Periodic Properties ofthe Elements6.4 Covalent Compounds6
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 6 1. Contents and relative calculations about redox equilibrium, electrode potential etc. 2. Basic concepts of redox titration analysis (titration, end point, stoichiometric point, indicator, standard solution, standard substance). 3. Principle of redox titration analysis, titrate curve, end point judge, end point error and feasibility of titration 4. Application of redox titration analysis and calculation of titration result. Nodus: 1. Ways of choosing the right condition for redox titration 2. Principles of redox titration analysis ,titrate curve, end point judge, end point error and feasibility of titration 3. Applications of redox titration analysis and calculation of titration result. Chapter 6 Atomic Structure and Periodic Properties of the Elements In this chapter, we need to know about some concepts of atomic structure, such as the movement of extranuclear electron, atomic energy level, probability density, atomic orbital, and wave function. Also understand how to descript the movement of extranuclear electron with the four quantum numbers, as well as the configurations and directions of s, p, and d orbital. Moreover, we should master some general rules of the configuration of extra-nuclear electron, characteristics of valence electron of main group and transition elements, and learn to estimate the properties of the elements according to its electronic shell structures. In this chapter, we also need to know the periodic variation of atomic radius, ionization energy, electron affinity energy as well as electronegativity, and to understand the formation, characteristic (directivity and saturation) , and types of bonding (ı bond and ʌ bond) in the view of valence bond theory. Further more, we should master the types of hybrid orbitals (sp, sp2 , sp3 ), which are relative with the molecular configurations. To illustrate molecular structures and magnetic properties, we also should understand some concepts of molecular orbitals. Finally, we should known some types of crystals and its structural characteristics, Born-Haber cycle, and that how crystal lattice influences the melting point and hardness of ionic compounds, and that how to effect the properties of matter by the means of ionic polarization, intermolecular forces and hydrogen bond. Major Contents: 6.1 The Models of Atomic Structure 6.1.1 The Bohr Model of Atomic Hydrogen 6.1.2 The Quantum Mechanics Model 6.2 The Movement of Extranuclear Electron 6.2.1 The Schroodinger Equation 6.2.2 The Wave Functions and the Atomic Orbitals 6.2.3 The Four Quantum Numbers 6.2.4 The Angular Distribution Pattern of Atomic Orbital 6.2.5 Patterns of Electron Cloud 6.3 The Electronic Shell Structures of the Atoms and The Periodic System 6.3.1 The Configuration of Extra-nuclear Electron of polyelectron Atoms 6.3.2 The Electronic Shell Structures of the Atoms and the Periodic System 6.3.3 Periodic Properties of the Elements 6.4 Covalent Compounds
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry6.4.1 Valence Bond Theory6.4.2 Hybrid Orbital Theory6.4.3Molecular Orbital Theory6.5Intermolecular Forces and Hydrogen Bond6.5.1ThePolarityandDeformabilityofMolecules6.5.2 Intermolecular Forces6.5.3 Hydrogen Bond6.6 lonic Compounds6.6.1Formation and Characteristics of Ionic Bond6.6.2 lonic Solids6.6.3 Ionic Radius and Crystal Configurations6.6.4 Lattice Energy of lonic Solids6.6.5 lonic Polarization6.6.6 Other SolidsKey Points:1,Description of the movement ofextranuclear electron with the four quantum numbers2. General rules ofthe configuration of extra-nuclear electron, and characteristics ofvalence electron of main group and transition elements3. Configuration and direction of s, P, d orbitals4. The atomic radius, ionization energy, electron affinity energy, periodic variation ofelectronegativity5. To understand the formation, characteristics (directivity and saturation), and types ofbonding (αbond and π bond) in the view of Valence Bond Theory.6. The types of hybrid orbitals (sp, sp2, sp') and their relationship with molecularconfigurations7. The types of crystals and its structural characteristicNodus:1.Modern concepts ofthe movement ofextranuclear electron, atomic energy level,probability density and electron cloud, atomic orbitals and Wave Functions.2. Description of the movement of extranuclear electron with the four quantum numbers3.Theconceptsofmolecularorbitals,andillustrationofmolecularstructureandmagneticproperty4.The polarity and deformability of moleculesChapter7CoordinationCompound&ComplexometryIn this chapter,we can master complex equilibrium, including cascade complex equilibrium,andsomecalculationsaboutitandcancomputeequilibriumcompositionswhenligandsexceed. We should be acquainted with titration of EDTA when various equilibriums exist. Andmaster how to select the acidity of titration and methods for increasing sensitivity of titration.Major Contents:7.1 Coordination Compounds and Chelate Compounds7.1.1TheElementsofCoordinationCompounds7.1.2 The Nomenclature of Coordination Compounds7.1.3ChelateCompounds7.2 ValenceBond Theory ofCoordination Compounds7
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 7 6.4.1 Valence Bond Theory 6.4.2 Hybrid Orbital Theory 6.4.3 Molecular Orbital Theory 6.5 Intermolecular Forces and Hydrogen Bond 6.5.1 The Polarity and Deformability of Molecules 6.5.2 Intermolecular Forces 6.5.3 Hydrogen Bond 6.6 Ionic Compounds 6.6.1 Formation and Characteristics of Ionic Bond 6.6.2 Ionic Solids 6.6.3 Ionic Radius and Crystal Configurations 6.6.4 Lattice Energy of Ionic Solids 6.6.5 Ionic Polarization 6.6.6 Other Solids Key Points: 1. Description of the movement of extranuclear electron with the four quantum numbers 2. General rules of the configuration of extra-nuclear electron, and characteristics of valence electron of main group and transition elements 3. Configuration and direction of s, p, d orbitals 4. The atomic radius, ionization energy, electron affinity energy, periodic variation of electronegativity 5. To understand the formation, characteristics (directivity and saturation), and types of bonding (ı bond and ʌ bond) in the view of Valence Bond Theory. 6. The types of hybrid orbitals (sp, sp2 , sp3 ) and their relationship with molecular configurations 7. The types of crystals and its structural characteristic Nodus: 1. Modern concepts of the movement of extranuclear electron, atomic energy level, probability density and electron cloud, atomic orbitals and Wave Functions. 2. Description of the movement of extranuclear electron with the four quantum numbers 3. The concepts of molecular orbitals, and illustration of molecular structure and magnetic property 4. The polarity and deformability of molecules. Chapter 7 Coordination Compound & Complexometry In this chapter, we can master complex equilibrium, including cascade complex equilibrium, and some calculations about it and can compute equilibrium compositions when ligands exceed. We should be acquainted with titration of EDTA when various equilibriums exist. And master how to select the acidity of titration and methods for increasing sensitivity of titration. Major Contents: 7.1 Coordination Compounds and Chelate Compounds 7.1.1 The Elements of Coordination Compounds 7.1.2 The Nomenclature of Coordination Compounds 7.1.3 Chelate Compounds 7.2 Valence Bond Theory of Coordination Compounds
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry7.2.1 Summary of Valence Bond Theory of Coordination Compounds7.2.2CoordinateCovalent Bonds and Steric Configuration7.2.3 Outer Orbital Complexes and Inner Orbital Complexes7.2.4 Stability and Magnetic Properties ofCoordination Compounds7.3Complex Equilibrium and its Influencing Factors7.3.1 Complex Equilibrium and Equilibrium Constant7.3.2EDTAandCoordinationCompoundsofMetallicIons7.3.3MajorFactorsEffectedonComplexEquilibrium7.4Complexometry7.4.1 Complexometry Curve and Titration Conditions7.4.2 Indicators for ComplexFormation Titration7.4.3 Selective Titration of Mixed Ions7.4.4Modes of ComplexometryKey Points:1. Basic Concepts of Coordination Compounds and Valence Bond Theory2.Calculation of equilibrium composition when ligands exceed, Selection of acidity,andmethods for increasing selectivity3.Principles of complexometry,complexometry Curve, recognition ofend point errorand feasibility4. The application of complexometry and the methods for the calculation of titrationresultNodus:1.ValenceBond Theoryof Coordination Compounds2. Calculation of equilibrium composition when ligands exceed, selection of acidity, andmethods for increasing selectivity3. Applications of complexometry and methods for calculation of the result of titrationChapter8TheCommonElements ofpBlockandRelativeCompoundsInthis Chapter,we can gettoknowaboutthetypical properties ofthemaingroup compounds(Halogens, Oxygen, Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead), such asacidic-basic properties, oxidizing-reducing properties, and isolation and identification of ions.Major Contents:8.1The Halogens and Halide Compounds8.1.1 The Halogens and General Properties of Simple Substances8.1.2 The Main Halogens8.2The Elements of Oxygen Group and its Compounds8.2.1 General Properties of the Oxygen Group8.2.2 Oxygen, Sulfur and its Compounds8.3The Elements of Nitrogen Group and its Compounds8.3.1 General Properties of the Nitrogen Group8.3.2The Main Compounds of Nitrogen Group8.4The Elements of Carbon, Boron Groups and its Compounds8.4.1 The Common Elements of Carbon Group and its Compounds8.4.2The Common Elements of Boron Group and its Compounds
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 8 7.2.1 Summary of Valence Bond Theory of Coordination Compounds 7.2.2 Coordinate Covalent Bonds and Steric Configuration 7.2.3 Outer Orbital Complexes and Inner Orbital Complexes 7.2.4 Stability and Magnetic Properties of Coordination Compounds 7.3 Complex Equilibrium and its Influencing Factors 7.3.1 Complex Equilibrium and Equilibrium Constant 7.3.2 EDTA and Coordination Compounds of Metallic Ions 7.3.3 Major Factors Effected on Complex Equilibrium 7.4 Complexometry 7.4.1 Complexometry Curve and Titration Conditions 7.4.2 Indicators for Complex Formation Titration 7.4.3 Selective Titration of Mixed Ions 7.4.4 Modes of Complexometry Key Points: 1. Basic Concepts of Coordination Compounds and Valence Bond Theory 2. Calculation of equilibrium composition when ligands exceed, Selection of acidity, and methods for increasing selectivity 3. Principles of complexometry, complexometry Curve, recognition of end point error and feasibility 4. The application of complexometry and the methods for the calculation of titration result Nodus: 1. Valence Bond Theory of Coordination Compounds 2. Calculation of equilibrium composition when ligands exceed, selection of acidity, and methods for increasing selectivity. 3. Applications of complexometry and methods for calculation of the result of titration Chapter 8 The Common Elements of p Block and Relative Compounds In this Chapter, we can get to know about the typical properties of the main group compounds (Halogens, Oxygen, Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead), such as acidic-basic properties, oxidizing-reducing properties, and isolation and identification of ions. Major Contents: 8.1 The Halogens and Halide Compounds 8.1.1 The Halogens and General Properties of Simple Substances 8.1.2 The Main Halogens 8.2 The Elements of Oxygen Group and its Compounds 8.2.1 General Properties of the Oxygen Group 8.2.2 Oxygen, Sulfur and its Compounds 8.3 The Elements of Nitrogen Group and its Compounds 8.3.1 General Properties of the Nitrogen Group 8.3.2 The Main Compounds of Nitrogen Group 8.4 The Elements of Carbon, Boron Groups and its Compounds 8.4.1 The Common Elements of Carbon Group and its Compounds 8.4.2 The Common Elements of Boron Group and its Compounds
Syllabus of Zhejiang University of Science and TechnologyInorganic and Analytical ChemistryKey Points:1. Master the typical properties of the main group compounds (Halogens, Oxygen,Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead), such as acidic-basicproperties, oxidizing-reducing properties and isolation and identification of ions2.Learn to evaluate the products of chemical reactions and write out reaction equationcorrectly.Nodus:Typical properties of the main group compounds, such as acidic-basic properties,oxidizing-reducing properties and isolation and identification of ionsChapter9TheCommonElementsofs,ds andd Blocks and Relative CompoundsIn this chapter, we can get to know about thetypical properties of the transition elements (CrMn Fe Co Ni Cu Ag Zn Cd Hg) and its main compounds(Halogens, Oxygen, Silicon,Nitrogen,Arsenic,Stibium, Bismuth, Calcium, Lead ),such as acidic-basic propertiesoxidizing-reducing properties and isolation and identification of ions, and learn about systemanalytic methods of qualitative analysis.MajorContents:9.1The Common Elements of s Block and Main Compounds9.1.1GeneralPropertiesoftheElementsofthesBlock9.1.2The Main Compounds of s Block9.2The Common Elements of ds Block and Main Compounds9.2.1 Cu, Ag and its Main Compounds9.2.2Zn,Cd,Hgand itsMainCompounds9.3TheCommonElementsofdBlockandMainCompounds9.3.1GeneralPropertiesoftheElementsofthedBlock9.3.2 The Main Compounds of Gr9.3.3 The Main Compounds of Mn9.3.4The Main Compounds of Fe, Co and Ni9.4IsolationandIdentificationofCommonMetallicIons9.4.1 Summary of Inorganic QualitativeAnalysis9.4.2SvstemAnalyticMethodsforCommonMetallicIonsKey Points:1.The typical properties ofthe transition elements (Cr Mn Fe Co Ni Cu AgZn Cd Hg) and its main compounds (Halogens, Oxygen, Silicon, Nitrogen, Arsenic,Stibium, Bismuth, Calcium, Lead ), such as acidic-basic properties, oxidizing-reducingproperties and isolation and identification of ions.2.System analytic methods ofqualitative analysisNodus:Acidic-basic properties, oxidizing-reducing properties, and isolation and identification ofions of the transition elements and its main compounds9
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 9 Key Points: 1. Master the typical properties of the main group compounds (Halogens, Oxygen, Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead), such as acidic-basic properties, oxidizing-reducing properties and isolation and identification of ions 2. Learn to evaluate the products of chemical reactions and write out reaction equation correctly. Nodus: Typical properties of the main group compounds, such as acidic-basic properties, oxidizing-reducing properties and isolation and identification of ions Chapter 9 The Common Elements of s, ds and d Blocks and Relative Compounds In this chapter, we can get to know about the typical properties of the transition elements (Cr Mn Fe Co Ni Cu Ag Zn Cd Hg) and its main compounds ( Halogens, Oxygen, Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead ), such as acidic-basic properties, oxidizing-reducing properties and isolation and identification of ions, and learn about system analytic methods of qualitative analysis. Major Contents: 9.1 The Common Elements of s Block and Main Compounds 9.1.1 General Properties of the Elements of the s Block 9.1.2 The Main Compounds of s Block 9.2 The Common Elements of ds Block and Main Compounds 9.2.1 Cu, Ag and its Main Compounds 9.2.2 Zn, Cd, Hg and its Main Compounds 9.3 The Common Elements of d Block and Main Compounds 9.3.1 General Properties of the Elements of the d Block 9.3.2 The Main Compounds of Gr 9.3.3 The Main Compounds of Mn 9.3.4 The Main Compounds of Fe, Co and Ni 9.4 Isolation and Identification of Common Metallic Ions 9.4.1 Summary of Inorganic Qualitative Analysis 9.4.2 System Analytic Methods for Common Metallic Ions Key Points: 1. The typical properties of the transition elements (Cr Mn Fe Co Ni Cu Ag Zn Cd Hg) and its main compounds ( Halogens, Oxygen, Silicon, Nitrogen, Arsenic, Stibium, Bismuth, Calcium, Lead ), such as acidic-basic properties, oxidizing-reducing properties and isolation and identification of ions. 2. System analytic methods of qualitative analysis Nodus: Acidic-basic properties, oxidizing-reducing properties, and isolation and identification of ions of the transition elements and its main compounds
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical ChemistryChapter 10 Spectrophotometric MethodIn this chapter, we should understand the selective adsorption of lights by substance, masterLambert-Beer Law, know about methods and instruments of spectrophotometry,selection ofchromogenic reaction and measurement conditions, and acquaintance with approach forincrease sensitivity and accuracy of instrument.Major Contents:10.1 Basic Principles of Spectrophotometric Method10.1.1 Selective Adsorption of Lights by Substance10.1.2 Lambert-Beer Law10.1.3Factors Influencing Deviation fromLambert-Beer Law10.2SpectrophotometricMethod10.2.1 Colorimetric and Specrophotometric Methods10.2 2 Chromogenic Reaction and its Influencing Factors10.3Applications of Spectrophotometric MethodKey Points:1.Basicprinciplesofspectrophotometricmethod2.Lambert-BeerLaw3. Applications of spectrophotometric methodNodus:1. Structure and principle of instrument2.Selection of chromogenic reaction conditions3. Selection of reference solutionsNo.ContentsPeriod01Introduction31Stoichiometry and error,data processing24Basic principleof chemical reaction38Acid-baseequilibrium&acid-basetitrationPrecipitation-dissolution equilibrium & precipitation testing48method5Redox Equilibrium and Redox Titration106Substance structure78Coordinationcompound&complexometry84TheElementsofPBlockandrelativecompoundsTheCommonElementsof SddsBlocksandrelative98compounds, Isolation & identification of common mixed-ionssolution610Spectrophotometric MethodD.Arrangementand Examination Methods for Teaching Segment1. Classroom Lecturing().Lecturing:Systematical lecturingshall becarried outforthepart ofbasictheoryof thiscourse.10
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 10 Chapter 10 Spectrophotometric Method In this chapter, we should understand the selective adsorption of lights by substance, master Lambert-Beer Law, know about methods and instruments of spectrophotometry, selection of chromogenic reaction and measurement conditions, and acquaintance with approach for increase sensitivity and accuracy of instrument. Major Contents: 10.1 Basic Principles of Spectrophotometric Method 10.1.1 Selective Adsorption of Lights by Substance 10.1.2 Lambert-Beer Law 10.1.3 Factors Influencing Deviation from Lambert-Beer Law 10.2 Spectrophotometric Method 10.2.1 Colorimetric and Specrophotometric Methods 10.2 2 Chromogenic Reaction and its Influencing Factors 10.3 Applications of Spectrophotometric Method Key Points: 1. Basic principles of spectrophotometric method 2. Lambert-Beer Law 3. Applications of spectrophotometric method Nodus: 1. Structure and principle of instrument 2. Selection of chromogenic reaction conditions 3. Selection of reference solutions No. Contents Period 0 Introduction 1 1 Stoichiometry and error , data processing 3 2 Basic principle of chemical reaction 4 3 Acid-base equilibrium & acid-base titration 8 4 Precipitation-dissolution equilibrium & precipitation testing method 8 5 Redox Equilibrium and Redox Titration 8 6 Substance structure 10 7 Coordination compound & complexometry 8 8 The Elements of P Block and relative compounds 4 9 The Common Elements of S d ds Blocks and relative compounds, Isolation & identification of common mixed-ions solution 8 10 Spectrophotometric Method 6 D. Arrangement and Examination Methods for Teaching Segment 1. Classroom Lecturing (1). Lecturing: Systematical lecturing shall be carried out for the part of basic theory of this course