Chemists use spectroscopy (Ir, UV-Vis, NMR) to determine molecular structure. spectroscopy: technique that measures the amount of radiation a substance absorbs at various wavelengths(based on the quantization of molecular energy levels Molecules exist in quantized energy states (rotational, vibrational, and electronic quantum states) Molecules absorb discrete amounts of energy(ae)and are excited to higher

equipment and supavision by appropriate individuak You bear the sol responsibility, liability, and risk for the implemcntation of such safety procedures a ares. MIT shall have no responsibility, liability, risk for the content or implementation of of the mat

described in these materials are potentially hazardous and require a high lcvel ofsafity training special facilitics and equipment, and supavision by approprinte duals. You bear the sol responsiblity, liability, and risk for the impkemcntation of such safety procedures and measures. MiT shall have no responsibility, liability, ar risk for the content ar implem of ay of the matcrial presented. Legal Notices

This is two-day- experiment. Do not start this experiment unless you have two free lab days to complete it.*** Techniques Checklist: Picking the correct eluent Adsorbtion of a crude mixture onto silica gel Separating complex mixtures using gradient elution Pre-lab Discussion: Suggest limited list of eluent solvent systems Discuss sample adsorption and gradient elution strategies

X-Ray diffraction is an important and powerful tool for determining the solid state structure of compounds. Modern advances have made data collection and structure solution almost routine for many small molecules To use this technique, however, good quality single crystals are still needed. In this exercise you will experiment with the art of growing single crystals

For a two-solvent recrystallization, you should have one solvent (solvent #1) in which your desired compound is soluble at the boiling point. The second solvent(solvent #)should induce crystallization when added to a saturated solution of your compound in the primary solvent. Reference:

Working on a vacuum manifold: See LLP chapter 9.2 for an excellent discussion on working with air-sensitive reagents, including how to use a two-way manifold. De-gassing solvents: The best way to remove water and oxygen from a solvent is to distill it over an appropriate drying agent (such as sodium). This can sometimes be a lengthy (and dangerous)task. Since we

Overview: A good 'H NMR sample contains about 10 mg of compound. The solution should contain no solids or paramagnetic impurities. Your deuterated NMR solvent should be free of water,and your NMR spectrum should contain no solvent peaks. Reference: Zubrick page 295 is relatively useful, but you should follow the specifics in this handout Also, keep in mind that we won't be running continuous wave spectrometers, so you should disregard any discussion of them. NMR Solvents:

WARNING NOTICE: The erperimants descnbed in these materials are potentially hao ardous and require a high level ofsafcty training special facilitics and equipment, and supervision by approprinte individuals. You bear the solc responsibility, liability, and risak for the implemcntation of such safdty procedunes and measures. MrT shall have no responsiblity, liability, risk for the content or implemcutation of amy of the matcrial presented. Legal Notices

《高等数学 F1》 《高等数学 F2》 《大学物理 E》 《无机化学 1》 《无机化学实验 1》 《现代化学导论》 《无机化学 2》 《无机化学实验 2》 《分析化学》 《分析化学实验》 《有机化学 1》 《有机化学实验 1》 《高分子材料概论》 《物质结构》 《物理化学 A1》 《物理化学实验 1》 《有机化学 2》 《有机化学实验 2》 《物理化学 2》 《物理化学实验 2》 《高分子材料仪器分析》 《高分子化学》 《高分子化学实验》 《高分子物理》 《高分子物理实验》 《化学工程基础及实验》 《高分子材料仪器分析实验》 《专业英语》 《高分子合成工艺学》 《功能高分子材料及实验》 《高分子材料加工工艺学》 《高分子材料加工工程实验 1》 《高分子材料加工工程实验 2》 《聚合物改性》 《塑料助剂与配方设计技术》 《计算机辅助高分子材料工程》 《化工安全工程管理》 《专业英语与文献检索》 《聚合物合成原理及工艺学》 《纤维材料加工设备》 《高分子流变学》 《纤维材料工艺学》 《专业基础实验》 《专业综合实验》 《高技术纤维》 《纺织工程与纺织品》 《认识实习》 《生产实习》 《毕业设计(论文)及答辩》