LnCl3/MCl熔体中,库仑效应、Van der Waals效应和极化效应起着主导作用,导致溶液热力学性质相对理想溶液呈负偏差,并在xLnCL≈0.2处,形成最大有序,用扩展的似化学理论模型能较好地描述这一特点.阐述了发展新热力学模型时应考虑到次近邻粒子及诸如空穴等似离子的作用,结合熔体结构研究,探讨熔体粒子间的相互作用机理
Chapter 3 Pressure-activated membrane processes M. J. LEWIS, Department of Food Science and Technology, The University of Reading, Reading RG6 6AP 3.1 INTRODUCTION Over the last 30 years, a number of membrane processes have evolved, which make use of a pressure driving force and a semi-permeable membrane in order to effect a separa- tion of components in a solution or colloidal dispersion. The separation is based mainly on molecular size, but to a lesser extent on shape and charge. The three main processes