上海交通大学：《材料热力学 Thermodynamics of materials》课程教学资源（PPT课件讲稿）Chapter9 Phase Diagram（3/3）

•Freezing point depression •The lever rule •Simple Eutectic diagram •Cooling curves

Nonideal Solutions 非理想溶液 Gibbs-Duhem Relation 吉布斯-杜海姆 Dilute solution 稀溶液 Colligative properties 依数性 Regular Solution 规则溶液 Osmotic pressure (渗透压）

1. Macrosates and Microstates宏观状态与微观状态 2. 微观状态数与最可几分布 3. Boltzmann假定与配置熵 4. 理想固溶体熵 5. 第三定律 6. Gibbs 公式 7. Boltzmann 分布* 8. 配分函数* 9. Fermi-Dirac 分布*

上海交通大学：《材料热力学 Thermodynamics of materials》课程教学资源（课件讲稿）Chapter8 Phase rule

Review Solutions Thermodynamic activity Partial molar quantities Relative partial molar quantities Entropy of mixing: ideal solution Enthalpy of mixing: ideal solution Graphical representation etc

上海交通大学：《材料热力学 Thermodynamics of materials》课程教学资源（实验）粉体材料比表面积的测定

Property relation Functions F and G Partial molar quantities Property relation derived from U, H, F, and G etc

Second law Functions F and G Property relation Property relation derived from U, H, F, and G etc

1th law continuous Adiabatic process: Joule-Thomson expansion 绝热过程 Equations of state 状态方程 Adiabatic compression or expansion 绝热压缩与膨胀 Enthalpies of formation 生成焓 Enthalpy changes in chemical reactions 焓变与化学反应 Adiabatic temperature change in chemical reactions 化学反 应的绝热温度 etc