Review Solutions Thermodynamic activity Partial molar quantities Relative partial molar quantities Entropy of mixing: ideal solution Enthalpy of mixing: ideal solution Graphical representation etc

• What is Materials Science and Engineering? • The role of thermodynamics in MSE. •Cases • Introduction to the course / Syllabus • Review / Keywords

上海交通大学：《材料热力学 Thermodynamics of materials》课程教学资源（实验）粉体材料比表面积的测定

Condition of equilibrium Phase equilibrium Clapeyron equation in vapor equilibria Variation of vapor pressure with particle size Second-order transition

Property relation Functions F and G Partial molar quantities Property relation derived from U, H, F, and G etc

Entropy 2nd law Heat engine etc

Second law Functions F and G Property relation Property relation derived from U, H, F, and G etc

Continue / Review previous 2nd law Entropy Reversible process Carnot cycle etc

第二章流体的PVT关系 一、P、V、T、C是流体的最基本性质,是热力 二、PV数据的计算

一、是否题 1.体系经过一绝热可逆过程,其熵没有变化。 2.吸热过程一定使体系熵增,反之,熵增过程也是吸热的。 3.热力学基本关系式dH=dS+VdP只适用于可逆过程。 4.象du=Tds-dV等热力学基本方程只能用于气体,而不能用于液体或固相。 5.当压力趋于零时,M(T,P)-M(T,P)=0(M是摩尔性质)