《美国FDA农残分析手册》（第一卷英文版）APPENDIX I：PESTDATA

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Caution: Use this table only as a quick reference for tentative identification of residues found in samples analyzed by the most commonly used PAM I multiresidue methods. Always compare the residue to a standard chromatographed in your own gas chromatograph.

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理 APPENDIX I: PESTDATA 8 Caution: Use this table only as a quick reference for tentative identification of residues found in samples analyzed by the most com- nonly used PAM I multiresidue methods Always compare the residue to a standard chromatographed in your own gas chromatograph Apply appropriate confirmatory tests to verify tentative identification. Note that PESTDATA cannot and does not contain all details, consult PAM I tables that accompany each method for more definitive information about the behavior of the compound through the steps of the methods NOTATONS AND ABBREVIATONS USED IN PESTDATA (In all categories a hyphen indicates absen Name Preferred name for each chemical. ""indicates chemicals with multiple GlC peaks. Chlordane, Strobane, toxaphene and all Aroclors are listed only in the table ordered by name and do not appear in the tables ordered by relative retention times Molecular formula Numbers are not subscripted Averages are used for multicomponent chemicals RRT/ Columns list retention times(relative to chlorpyrifos)on GLC column indicated. Conditions under which these data were gathered are described in these section 302 DG modules GLC Column Section 302 DG modules DGI-DG OV-17 DG13-DG17 OV-225 DG18. DG19 Note that headers in these tables refer to GLC columns by the names used for packed columns, despite DGl-DG19's descriptions of wide bore capillary column systems, because so many of these rrts were developed using packed columns. Rrt data for equivalent packed and capillary columns are expected to be essentially identical and are combined in PESTDATA

Pesticide Analytical Manual Vol. I APPENDIX I Form FDA 2905a (6/92) Transmittal No. 2000-1 (10/1999) Appendix I–1 APPENDIX I: PESTDATA Caution: Use this table only as a quick reference for tentative identification of residues found in samples analyzed by the most commonly used PAM I multiresidue methods. Always compare the residue to a standard chromatographed in your own gas chromatograph. Apply appropriate confirmatory tests to verify tentative identification. Note that PESTDATA cannot and does not contain all details; consult PAM I tables that accompany each method for more definitive information about the behavior of the compound through the steps of the methods. NOTATIONS AND ABBREVIATIONS USED IN PESTDATA (In all categories a hyphen indicates absence of data) Name Preferred name for each chemical. “*” indicates chemicals with multiple GLC peaks. Chlordane, Strobane, toxaphene and all Aroclors are listed only in the table ordered by name and do not appear in the tables ordered by relative retention times. Molecular Formula Numbers are not subscripted. Averages are used for multicomponent chemicals. RRT/c Columns list retention times (relative to chlorpyrifos) on GLC column indicated. Conditions under which these data were gathered are described in these Section 302 DG modules: GLC Column Section 302 DG modules OV-101 DG1-DG5 OV-17 DG13-DG17 OV-225 DG18, DG19 Note that headers in these tables refer to GLC columns by the names used for packed columns, despite DG1-DG19’s descriptions of wide bore capillary column systems, because so many of these rrts were developed using packed columns. Rrt data for equivalent packed and capillary columns are expected to be essentially identical and are combined in PESTDATA

ata specify column and detector used Numbers refer to weight (ng) that causes detector response of approximately 50% full scale deflection(SD)on the recording device. Response values collected when the detector was combined with a wide bore capillary column include the notation"(WB). Codes refer to detectors and operating conditions described in these Section 302 DG modules, except that all response values are based on detector sensitivity of 50% FSD to 1.5 ng chlorpyrifos Code Detector Section 302 DG modules tritium electron capture none.obsolete detector thermionic(KCl) none- obsolete detector flame photometric, phosphorus DG2. DG14. DG19 FS flame phot DG15 6Ni electron capture DGl, DG13, DG18 trogen/phosphorus DG5. DG17 HX electroconductivity(halogen mode DG3. DG16 hn electroconductivity(1 DG4 MO microcoulometric none. obsolete detector NOTES: Response values are approximate and can vary dramatically on different chromatographs. Most response values represent rounded-off or averaged values; some were collected under conditions different from those suggested in references Recoveries Data on the recovery of the compound through several PAM I methods are listed in columns with the following headings. See the appropriate PAM I table(s) for more details, such as partial recoveries through Florisil Heading PAM I Secton PAM I Table 302 Luke (los angeles 302 E1-E3, no cleanup 302a Mills, Onley, Gaither 303 El-E5+ Cl or c2 303a Mills fatty food 304E1E5+C1C4 304 Ethers Florisil elution system 303Cl 304 Cl and c3 03a,304a alternative florisil elution 303 C2. 304 C2 and c4 303-a,304-a a>g I Recovery codes have the following meanings: C: complete(>80%); P: partial (50-80%): S: small(<50%); V: variable; R: recovered but a no quantitative information available; NR:not recovered

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–2 Responses Data specify column and detector used. Numbers refer to weight (ng) that causes detector response of approximately 50% full scale deflection (FSD) on the recording device. Response values collected when the detector was combined with a wide bore capillary column include the notation “(WB).” Codes refer to detectors and operating conditions described in these Section 302 DG modules, except that all response values are based on detector sensitivity of 50% FSD to 1.5 ng chlorpyrifos: Code Detector Section 302 DG modules TR tritium electron capture none - obsolete detector TI thermionic (KCl) none - obsolete detector FP flame photometric, phosphorus DG2, DG14, DG19 FS flame photometric, sulfur DG15 NI 63Ni electron capture DG1, DG13, DG18 NP nitrogen/phosphorus DG5, DG17 HX electroconductivity (halogen mode) DG3, DG16 HN electroconductivity (nitrogen mode) DG4 MC microcoulometric none - obsolete detector NOTES: Response values are approximate and can vary dramatically on different chromatographs. Most response values represent rounded-off or averaged values; some were collected under conditions different from those suggested in references. Recoveries Data on the recovery of the compound through several PAM I methods are listed in columns with the following headings. See the appropriate PAM I table(s) for more details, such as partial recoveries through Florisil. Heading Common Name PAM I Section PAM I Table 302 Luke (Los Angeles) 302 E1-E3, no cleanup 302-a 303 Mills, Onley, Gaither 303 E1-E5 + C1 or C2 303-a 304 Mills fatty food 304 E1-E5 + C1-C4 304-a Ethers Florisil elution system 303 C1, 304 C1 and C3 303-a, 304-a CH2 Cl2 alternative Florisil elution 303 C2, 304 C2 and C4 303-a, 304-a Recovery codes have the following meanings: C: complete (>80%); P: partial (50-80%); S: small (<50%); V: variable; R: recovered but no quantitative information available; NR: not recovered

a Appendix l: PESTDATA Chemicals in Order by ChemicalName Molecular RRT/c Rrt/c rrt/c Formula OV-101 ov-225 Ov-17 303 304 Ethers CH Cl, Bs I methoxybenzene 11, 2,3,4-tetrachlorobenzene C6H24 OV-17: NI0.2 1, 2,3,5-tetrachlorobenzene C6H204 P群 Responses: OV-17: N1O.I 乙22, 3, 5, 6tetrafluoro--hydroxymethyl= C8H40F4 x*Multipeak chemical Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a

Pesticide Analytical Manual Vol. I APPENDIX I Form FDA 2905a (6/92) Transmittal No. 2000-1 (10/1999) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2Cl2 Appendix I–3 Appendix I: PESTDATA Chemicals in Order by Chemical Name Recoveries * Multipeak chemical. # Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a. 1,1'-(2,2-dichloroethylidene)bis(2- C16H16Cl2O2 2.9 - 3.7 - R - - - methoxybenzene) Responses: 1,2,3,4-tetrachlorobenzene C6H2Cl4 - - 0.09 - - - - - Responses: OV-17: NI0.2 1,2,3,5-tetrachlorobenzene C6H2Cl4 - - 0.07 - P # - 6 1 Responses: OV-17: NI0.1 1,2,3-trichlorobenzene C6H3Cl3 0.08 - - - C P 6 1 Responses: OV-101: TR2 1,2,4,5-tetrachloro-3-(methylthio)= C7H4Cl4S 0.49 0.35 0.48 R C - 6 1 benzene Responses: OV-101: NI0.3 OV-17: HX(WB)0.3 OV-225: NI0.3 1,2,4,5-tetrachlorobenzene C6H2Cl4 - - 0.07 - - - - - Responses: OV-17: NI0.2 1,2,4-triazole C2H3N3 0.2 - 0.27 V NR NR 6-15-50 1-2-3 Responses: DEGS: NP3 1-hydroxychlordene C10H6Cl6O 0.99 1.63 1.07 - R - 15 - Responses: OV-101: NI(WB)7 OV-17: NI1 OV-225: NI1 1-methyl cyromazine C7H13N6 - - 0.72 - - - - - Responses: OV-17: NP1000 10,10-dihydromirex C10H2Cl10 2.67 - - - C - 6 - Responses: OV-101: NI7 10-monohydromirex C10HCl11 4.26 - - - C - 6 - Responses: OV-101: NI7 2,3,5,6-tetrachloroanisidine C7H5Cl4NO 0.59 0.73 0.66 - C - 6 2 Responses: OV-101: NI0.5 OV-17: HX(WB)0.6 OV-225: NI0.5 2,3,5,6-tetrachloroanisole C7H4Cl4O 0.24 0.15 0.22 - C - 6 1 Responses: OV-101: NI0.2 OV-17: HX(WB)0.3 OV-225: NI0.2 2,3,5,6-tetrachloronitroanisole C7H3Cl4NO3 0.56 0.63 0.56 - C - 6 1+2 Responses: OV-101: NI0.4 OV-17: HX(WB)0.5 OV-225: NI0.4 2,3,5,6-tetrafluoro-4-hydroxymethyl= C8H4OF4 - - - - - - - - benzoic acid Responses:

P Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued Molecular RRT/c Rrt/c rrt/c Recoveries Formula OV-101 ov-225 Ov-17 3304 2.3.5-trimethacarb ClIHINO2 S群 1-23 Responses: OV-101: NP8 OV-17: NP4 OV-225: NP10 Responses: OV-101: FS25/N14 OV-17: FS54/N4.5 OV-225: FS63/NI10 2.4.5-T BEP ester* CI7H23C130 16 0.l4 108 3.28 Responses: OV-101: TR35 2.4.5-T butoxvethyl ester* C14HI7C1304 3.3 sponses: OV-101: TR4 2, 4, 5-T butyl esters C12H130303 105 2, 4, 5-Tethylhexyl ester Cl6H211303 3.38 2.62 2. 4.5-T isobutyl ester Cl2H130303 Responses: OV-101: TRI 2.4.5-T isooctyl esters C16H2IC303 3.4 Responses: OV-101: TR20 2, 4, 5-I isopropyl ester ClIHIlC30% 0.67 Responses: OV-101: TR2 a 2,4,3-T methyl ester C9H7CI303 Responses: OV-101: TRI 2.4.5-T n-butyl ester Cl2H13C303 Responses: OV-101: TRI o 2, 4, 5-T propylene glycol butyl Cl5H1913O4 品二己二≤一

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–4 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2 Cl2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 2,3,5-trimethacarb C11H15NO2 0.35 0.6 0.38 C S # NR 50 1-2-3 Responses: OV-101: NP8 OV-17: NP4 OV-225: NP10 2,3-dihydro-3,3-methyl-2-oxo-5- C11H12O5S 0.68 2.89 0.93 - - - - - benzofuranyl methyl sulfonate Responses: OV-101: FS25/NI4 OV-17: FS54/NI4.5 OV-225: FS63/NI10 2,4,5-T BEP ester* C17H23Cl3O3 0.16 0.14 - - - - - - 0.68 0.66 - 1.08 0.91 - 2.85 1.19 - 3.3 2.78 - 5.3 3.28 - 7 7.7 - Responses: OV-101: TR35 2,4,5-T butoxyethyl ester* C14H17Cl3O4 - 2.66 - - - - - - 2.91 3.3 - Responses: OV-101: TR4 2,4,5-T butyl esters* C12H13Cl3O3 - - 1.05 - - - - - - - 0.86 Responses: 2,4,5-T ethylhexyl ester C16H21Cl3O3 3.38 - 2.62 - - - - - Responses: OV-101: NI5 2,4,5-T isobutyl ester C12H13Cl3O3 0.94 - - - - - - - Responses: OV-101: TR1 2,4,5-T isooctyl ester* C16H21Cl3O3 - 2.69 - - - - - - 2.56 3.1 - 2.96 3.4 - 3.25 3.8 - Responses: OV-101: TR20 2,4,5-T isopropyl ester C11H11Cl3O3 0.67 0.65 - - - - - - Responses: OV-101: TR2 2,4,5-T methyl ester C9H7Cl3O3 0.49 0.63 0.47 - - - - - Responses: OV-101: TR1 2,4,5-T n-butyl ester C12H13Cl3O3 1.1 - - - - - - - Responses: OV-101: TR1 2,4,5-T propylene glycol butyl C15H19Cl3O4 2.37 - - - - - - - ether esters Responses:

a Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued) Molecular RRT/c Rrt/c rrt/c Formula OV-101 ov-225 Ov-17 03 304 Ethers CH,CL, |24m 0.34 82,4DBEP ester* Cl7H24C1204 69 Responses: OV-101: TR6O 2. 4-D butoxvethyl ester* Cl4Hl8CI204 182 sponses: OV-101: TRI2 OV-17: N5 2,4 D ethyl hexyl ester李 Cl6H22120 2. 4-D isobutyl ester C12HI4C203 0.62 0.49 Responses: OV-101: TR5 2, 4-D isooctyl esters Cl6H2201203 OV-101: TR50 OV-17: NI5 2, 4-D isopropyl ester* ClIHI2C1203 0.62 42 0.74 0.33 sponses: OV-101: TRIO 2.4-D methyl ester C9H8C203 0.38 Responses: OV-101: TR6 2.4-D n-butyl ester C12Hl4203 0.72 2,4-D propylene glycol butyl ether CI5H2OC1204 1.42 OV-101: TR20 D2,4-DB methyl ester ClIHI2c1203 62 Responses: OV-101: TR28 52, 4-dichloro-6-nitrobenzenamine C6H4C12N202 OV-101:HX2/Nl0.4/NP8

P Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued Molecular RRT/c Rrt/c rrt/c Recoveries Formula OV-101 ov-225 Ov-17 3304 2. 6-dichlorobenzamide C7H5NOC2 6-15-50 1-23 2. 8-dihvdrom CIOH2CI1O C8H15CI02 2-chloroethyl laurate C14H27CI02 Responses: OV-101: HX2 C20H35C102 OV-101: HXl5 2-chloroethyl myristate Cl6HS1CIO2 1.17 oV-101: HX4 CI8H35C102 V-101: HX10 2-hydroxy-2, 3-dihydro-3, 3-methyl-8- CIlH1403S benzofuranol methyl sulfonate Responses: OV-101: FS48/NT135 OV-17: FS88/N196 OV-225: FSI75/N1400 2-methoxy-3, 5, 6-trichloropyridine C6H1CI3NO 0.19 P群 15 Responses: OV-101: NIO.5/NI(WB)0.4/NP(WB)9 OV-17: HX1.5 3,5,6-trichloro-2-pyridinol methyl C6H1C13NO 0.32 OV-10l:N(WB)0.6 3.4.5-trimethacarb ClIHINO2 0.5 1-23 Responses: OV-101: NP25 OV-17: NP10 OV-225: NP200 C6H5C12N Responses: OV-101: HXO.6/N116/NPI OV-17: NI13/NP8 OV-225: NIS0 3, +dichlorophenylurea C7H6CI2N20 0.22 6-1550 Responses: OV-101: HX9/NII8/NP60 OV-17: N4 OV-225: NI6 Responses: OV-101: HN(WB)1/HX0.5/N19/NI(WB)16/NP0. 9/NP(WB)1 OV-17: HN(WB)0. 3/HX(WB)2/NIS/NI(WB)IMMe/8 C6H5C12N NP(WB)0. 4 OV-225: NI20/NI(WB)2 3-(3 +dichlorophenyl)-l NRNR 6-15-50 Responses: OV-101: HX9/N125 OV-17: NP250 83-aminophenol 品二己二≤一

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–6 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2 Cl2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 2,6-dichlorobenzamide C7H5NOCl2 0.39 1.3 0.52 C NR NR 6-15-50 1-2-3 Responses: 2,8-dihydromirex C10H2Cl10 2.41 - - - C - 6 - Responses: OV-101: NI4 2-chloroethyl caprate C8H15ClO2 0.32 - - - C C 15 2 Responses: OV-101: HX2 2-chloroethyl laurate C14H27ClO2 0.59 - - - C C 15 2 Responses: OV-101: HX2 2-chloroethyl linoleate C20H35ClO2 4.1 - - - V P 15 2 Responses: OV-101: HX15 2-chloroethyl myristate C16H31ClO2 1.17 - - C V V 15 2 Responses: OV-101: HX4 2-chloroethyl palmitate C18H35ClO2 2.35 - - - V P 15 2 Responses: OV-101: HX10 2-hydroxy-2,3-dihydro-3,3-methyl-5- C11H14O5S 1 6.6 1.46 - - - - - benzofuranyl methyl sulfonate Responses: OV-101: FS48/NI135 OV-17: FS88/NI96 OV-225: FS175/NI400 2-methoxy-3,5,6-trichloropyridine C6H4Cl3NO 0.19 0.08 0.1 C P # C 6+15 1+2 Responses: OV-101: NI0.5/NI(WB)0.4/NP(WB)9 OV-17: HX1.5 3, 5, 6-trichloro-2-pyridinol methyl C6H4Cl3NO 0.32 0.44 0.36 - - - - - ester Responses: OV-101: NI(WB)0.6/NP(WB)5 3,4,5-trimethacarb C11H15NO2 0.45 0.78 0.5 C NR NR 50 1-2-3 Responses: OV-101: NP25 OV-17: NP10 OV-225: NP200 3,4-dichloroaniline C6H5Cl2N 0.2 0.32 0.16 V S - 15 - Responses: OV-101: HX0.6/NI16/NP1 OV-17: NI13/NP8 OV-225: NI30 3,4-dichlorophenylurea C7H6Cl2N2O 0.22 0.14 0.1 - NR NR 6-15-50 - Responses: OV-101: HX9/NI18/NP60 OV-17: NI4 OV-225: NI6 3,5-dichloroaniline C6H5Cl2N 0.18 0.27 0.14 S S S 6+15 1+2 Responses: OV-101: HN(WB)1/HX0.5/NI9/NI(WB)16/NP0.9/NP(WB)1 OV-17: HN(WB)0.3/HX(WB)2/NI8/NI(WB)14/NP8/ NP(WB)0.4 OV-225: NI20/NI(WB)25 3-(3,4-dichlorophenyl)-1- C8H8Cl2N2O2 0.21 - 1.36 R NR NR 6-15-50 - methoxyurea Responses: OV-101: HX9/NI25 OV-17: NP250 3-aminophenol C6H7NO - - - - - - - - Responses:

a Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued) Molecular RRT/c Rrt/c rrt/c Formula OV-101 ov-225 Ov-17 303 304 Ethers CH Cl, Responses: OV-101: NII70/NP40 OV-17: NI160/NP30 OV-225: NIIOO DEGS: N200/NP40 8schloro-3-methyl-A-nitro-H- CAH4CIN302 107 B-desmethyl sulfentrazone CIoHSCI2F2N4O3S 7.5 N 615-501-23 Responses: OV-101: NI(WB)0. 1/NP(WB)37 OV-17: FS(WB)1500/NI(WB)O 1/NP(WB)73 乙2< 3-hydroxycarbofuran CI2HI5NO4 thylphenyl CIIHISNO3 1.03 615-501-23 methylcarbamate Responses: OV-101: NP200 OV-17: NP600 S-ketocarbofura CI2H12NO4 Responses: OV-101: HN(WB)17/NI(WB)15/NP(WB)9 OV-17: HN(WB)15/NI(WB)80/NP(WB)$0 OV-225: NI(WB)80 C7H7O3N Responses: OV-101: NI13/NP50 OV-17: NI5/NP20 OV-225: N1250 3-methyl-f-nitrophenol methyl ether C8H9O3N 0.13 Responses: OV-101: NIS/NP7 OV-17: NII/NP2 OV-225: NI2 3-phenoxybenzenemethanol C13H1202 128 Responses: OV-101: NI1000 OV-17: NI1000 C9HI3CIN203 6-1550 1-23 nses: OV-101: HN(B)4/HX(WB)40/N(WB)67/NP(WB)39 OV-17: HN(WB )13/HX(WB)99/N(WB)35NP(WB)290 ON-225:NI(WB)630 4,-dichlorobiphenyl CI2HSC12 0.51 +(2, 4-dichlorophenoxy) CI2H9CI2NO benzenamine Responses: OV-101: TR60 ro= C10HI5CI2NO2 3 Responses: OV-101: NIl.4/NP34 OV-17: NIL.I/NP1.2 OV-225: N1.6 H-chloro-b-methoxyindole C9H8NOCI 0.54 66 Responses: OV-101: HX2.5/NI1000 OV-17: HX( +-chlorobenzeneamine C6H6CIN 6-1550

Pesticide Analytical Manual Vol. I APPENDIX I Form FDA 2905a (6/92) Transmittal No. 2000-1 (10/1999) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2Cl2 Appendix I–7 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 3-carboxy-5-ethoxy-1,2,4-thiadiazole C3H2N2O3S 0.22 0.25 0.2 NR - - - - Responses: OV-101: NI170/NP40 OV-17: NI160/NP30 OV-225: NI100 DEGS: NI200/NP40 3-chloro-5-methyl-4-nitro-1H- C4H4ClN3O2 1.07 - - C - - - - pyrazole Responses: 3-desmethyl sulfentrazone C10H8Cl2F2N4O3S 3.3 - 7.5 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)0.1/NP(WB)37 OV-17: FS(WB)1500/NI(WB)0.1/NP(WB)73 3-hydroxycarbofuran C12H15NO4 - - - - - - - - Responses: 3-hydroxymethyl-2,5-dimethylphenyl C11H15NO3 0.8 - 1.03 - NR NR 6-15-50 1-2-3 methylcarbamate Responses: OV-101: NP200 OV-17: NP600 3-ketocarbofuran C12H12NO4 0.55 1.41 0.9 S NR NR 6 1 Responses: OV-101: HN(WB)17/NI(WB)15/NP(WB)9 OV-17: HN(WB)15/NI(WB)80/NP(WB)30 OV-225: NI(WB)80 3-methyl-4-nitrophenol C7H7O3N 0.38 0.63 0.26 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI13/NP50 OV-17: NI5/NP20 OV-225: NI250 3-methyl-4-nitrophenol methyl ether C8H9O3N 0.17 0.22 0.13 - - - - - Responses: OV-101: NI3/NP7 OV-17: NI1/NP2 OV-225: NI2 3-phenoxybenzenemethanol C13H12O2 1.28 - 1.6 - - - - - Responses: OV-101: NI1000 OV-17: NI1000 3-tert-butyl-5-chloro-6-hydroxy= C9H13ClN2O3 1.35 2.27 2.55 - NR NR 6-15-50 1-2-3 methyluracil Responses: OV-101: HN(WB)4/HX(WB)40/NI(WB)67/NP(WB)39 OV-17: HN(WB)13/HX(WB)99/NI(WB)35/NP(WB)290 OV-225: NI(WB)630 4,4'-dichlorobiphenyl C12H8Cl2 - - 0.51 - - - - - Responses: 4-(2,4-dichlorophenoxy)= C12H9Cl2NO 1.44 - - - - - - - benzenamine Responses: OV-101: TR60 4-(dichloroacetyl)-1-oxa-4-azapiro= C10H15Cl2NO2 0.5 0.69 0.48 C P - 50 3 [4.5]decane Responses: OV-101: NI1.4/NP34 OV-17: NI1.1/NP1.2 OV-225: NI1.6 4-chloro-6-methoxyindole C9H8NOCl 0.54 - 0.66 - R - 15 - Responses: OV-101: HX2.5/NI1000 OV-17: HX0 4-chlorobenzeneamine C6H6ClN - - 0.07 S NR NR 6-15-50 1-2-3 Responses:OV-17:NP(WB)1.5

P Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued Molecular RRT/c Rrt/c rrt/c Recoveries Formula OV-101 ov-225 Ov-17 3304 f-chlorobenzyimethyl sulfone C8H9CIO2S 615-501-23 Responses: OV-101: NI(WB)0. 4 OV-17: NI(WB)0. 8 OV-225: NI(WB)2 A-chlorobenzylmethyl sulfoxide C8H9CIOS 615501-23 +-chlorobiphenyl CI2H9CI +-chlorophenoxyaniline CI2HIOCINO 087 107 1.3l1 Responses: OV-101: HX7/Nl100 C7H7CIN20 OV-101: N(WB)15 OV-17:NI(WB )40 A-hydroxymethyl-3, 5-dimethylphenyl CllHISNO3 0.18 0.22 1550 1-23 methylcarbamate 0.31 Responses: OV-101: NI200 OV-17: N150 6-chloro-2,3-dihydro-3,3, 7-methyl- C9HI3CN2O 0.43 34 6-15-501-23 Responses: OV-101: HN(WB)O4/NI(WB)26/NP(WB)3 OV-17: HN(WB)0. 4/HX(WB)4/NI(WB)36/NP(WB)2 OV-225: NI(WB) C9HI3CIN20 6-1550 ethyl-3.3-methyl-5H-oxazolo= ses: OV-101: HN(WB)4/HX(WB)II/NI(WB)28/NP(WB)17 OV-17: HN(WB)3/HX(WB)17/N(WB)19/NP(WB)12 (3, 2-a)pyrimidin-g-one 6-chloronicotinic acids C6H4NO2C1 NR615-501-23 DEGS: HX40/NII/NP66 CIOHCIll 3.74 acephate CAHIONOSPS 0.15 19 Responses: OV-101: FP(WB)0.9/NP3 OV-17: FP(WB)0.6 OV-225: FP5 acetochlor C14H20NO2CI 3 acifluorfe Cl4H7CIFSNO3 105 147 615501-23 Responses: OV-101: HN(WB)170/HX(WB)980/NI(WB)40/NP(WB)270 OV-17: HN(WB)48/HX(WB)390/NI(WB)27/NP(WB)1000 OV-225:NI(wB)300 o acrinathrin C26H2IF6NO5 10.4 Responses: OV-101: NI15/NP125 OV-17: N125/NP100 OV-225: N40 品二己二≤一

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–8 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2 Cl2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 4-chlorobenzylmethyl sulfone C8H9ClO2S 0.41 1.91 0.66 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)0.4 OV-17: NI(WB)0.8 OV-225: NI(WB)2 4-chlorobenzylmethyl sulfoxide C8H9ClOS 0.39 1.16 0.54 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)20 OV-17: NI(WB)16 OV-225: NI(WB)55 4-chlorobiphenyl C12H9Cl - - 0.2 - - - - - Responses: 4-chlorophenoxyaniline* C12H10ClNO 0.87 - 1.07 S - - - - 1.28 - 1.31 Responses: OV-101: HX7/NI1100 4-chlorophenylurea C7H7ClN2O 0.54 - 1.07 NR NR NR 6-15-50 1-2-3 Responses:OV-101:NI(WB)15 OV-17:NI(WB)40 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 0.18 - 0.22 - NR NR 15-50 1-2-3 methylcarbamate* 0.27 - 0.31 Responses: OV-101: NI200 OV-17: NI150 6-chloro-2,3-dihydro-3,3,7-methyl- C9H13ClN2O2 0.43 1.34 0.6 - NR NR 6-15-50 1-2-3 5H-oxazolo(3,2-a)pyrimidin-5-one Responses: OV-101: HN(WB)0.4/NI(WB)26/NP(WB)3 OV-17: HN(WB)0.4/HX(WB)4/NI(WB)36/NP(WB)2 OV-225: NI(WB)51 6-chloro-2,3-dihydro-7-hydroxy= C9H13ClN2O3 0.86 - 1.55 - NR NR 6-15-50 1-2-3 methyl-3,3-methyl-5H-oxazolo= Responses: OV-101: HN(WB)4/HX(WB)11/NI(WB)28/NP(WB)17 OV-17: HN(WB)3/HX(WB)17/NI(WB)19/NP(WB)12 (3,2-a)pyrimidin-5-one 6-chloronicotinic acid* C6H4NO2Cl - - - - NR NR 6-15-50 1-2-3 - -- Responses: DEGS: HX40/NI11/NP66 8-monohydromirex C10HCl11 3.74 - - - C - 6 - Responses: OV-101: NI5 acephate C4H10NO3PS 0.15 0.64 0.19 C - - - - Responses: OV-101: FP(WB)0.9/NP3 OV-17: FP(WB)0.6 OV-225: FP5 acetochlor C14H20NO2Cl 0.75 0.88 0.67 C C # P 50 3 Responses: OV-101: HX5/NI9/NP5 OV-17: NI5 OV-225: NI5 acifluorfen C14H7ClF3NO3 1.05 1.47 0.88 - NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)170/HX(WB)980/NI(WB)40/NP(WB)270 OV-17: HN(WB)48/HX(WB)390/NI(WB)27/NP(WB)1000 OV-225: NI(WB)300 acrinathrin C26H21F6NO5 10.4 12.8 8.9 V V V # 15 2 Responses: OV-101: NI15/NP125 OV-17: NI25/NP100 OV-225: NI40

a Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued) Molecular RRT/c Rrt/c rrt/c Formula OV-101 ov-225 Ov-17 303 304 Ethers CH Cl, 8 alachlor C14H20CINO2 0.72 C# Responses: OV-101: NI(WB)7 OV-17: NI6 OV-225: NI6 aldrin 12H8CI6 oV-101: TRO. 8 OV-17: NIl allethrin Cl9H2603 allidochlor C8H12CINO Responses: OV-101: TR5 C22H19C1203N OV-101: HX9/NI2 C9HI7N5S aminocarb ClIHI6N202 Responses: OV-101: NP1O CI9H23N3 C9H5CI3N4 15+50 Responses: OV-101: HX(WB)8/N4 OV-17: NP20 Cl5H25CIO4S 2 .14 3.05 OV-101: FP600/TR10000 Aroclor 1016 CHCI (mix) 0.24 0.39 087 1.07 Responses:

P Appendix l: PESTDATA Chemicals in Order by Chemical Name(continued Molecular RRT/c Rrt/c rrt/c Recoveries Formula OV-101 ov-225 Ov-17 303304 C12H8.8Cll2 0.15 21 0.77 l01 0.43 589 2.12 223 16 Responses: OV-101: TR40 odor 1242* B8乃8 124 1.42 0.98 152 187 2.24 1.75 2.6l 2.01 OV-101: TR50 品二己二≤一

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–10 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH2 Cl2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Aroclor 1221* C12H8.8Cl1.2 0.21 - - - C C 6 1 0.27 - - 0.32 - - 0.37 - - 0.4 - - 0.53 - - 0.6 0.15 - 0.65 0.21 - 0.7 0.24 - 0.77 0.3 - 0.9 0.4 - 1.01 0.43 - 1.3 0.46 - 1.45 0.5 - 1.55 0.54 - 1.8 0.61 - 1.9 0.68 - 2.12 0.92 - 2.26 1.04 - 2.7 1.16 - 3.16 1.24 - Responses: OV-101: TR40 Aroclor 1242* C12H7Cl3 0.4 0.24 - - C C 6 1 0.52 0.3 - 0.58 0.4 - 0.68 0.46 - 0.73 0.54 - 0.88 0.61 - 0.98 0.68 - 1.05 0.85 - 1.24 0.9 - 1.42 0.98 - 1.52 1.1 - 1.77 1.36 - 1.87 1.59 - 2.24 1.75 - 2.61 2.01 - Responses: OV-101: TR50

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