Neelakanta, P.S. "Smart Materials" The Electrical Engineering Handbook Ed. Richard C. Dorf Boca raton crc Press llc. 2000
Neelakanta, P.S. “Smart Materials” The Electrical Engineering Handbook Ed. Richard C. Dorf Boca Raton: CRC Press LLC, 2000
58 Smart materials 58.2 Smart/Intelligent Structures 58.3 Objective-Based Classification of Smart/Intelligent Materials Smart Structural materials Smart Thermal Materials Smart 8.4 Material Properties Conducive for Smart Material Piezoelectric Effect. Magnetostrictive Effect. Electroplastic Effect - Memory Effects. Electrorheology Property.Nonlinear Electro-optic Properties.Nonlinear Electromagnetic Properties 8.5 State-of-the-Art Smart Materials Piezoelectric Smart Materials Magnetostrictive Smart Materials. Electroplastic Smart Materials. Shape-Memory Smart Materials. Electrorheological Smart Fluids.Electro-optic Smart Materials. Electroacoustic Smart Materials. Electromagnetic Smart Materials. Pyrosensitive Smart Materials 58.6 Smart Sensors gnetostriction-Based Sensors. Shape-Memory Effects-Based Sensors. Electromagnetics-Based Sensors Electroacoustic Smart Sensors 58.7 Examples of Smart/Intelligent Systems Structural Engineering Applications. Electromagnetic Applications P.S. Neelakanta 58.8 High-Tech Application Potentials Florida Atlantic University 58.9 Conclusions 58.1 Introduction Smart materials are a class of materials and/or composite media having inherent intelligence together with self-adaptive capabilities to external stimuli, Also known as intelligent materials, they constitute a few subsets of the material family that"manifest their own functions intelligently depending on environmental changes I Rogers and Rogers, 1992] Classically, such intelligent material systems have been conceived in the development of mechanical structures that contain their own sensors, actuators and self-assessing computational feasibilities in order to modify their structural (elastic) behavior via feedback control capabilities. The relevant concepts have stemmed from intel ligent forms of natural (material) systems, namely, living organisms; hence, in modern concepts smart or c 2000 by CRC Press LLC
© 2000 by CRC Press LLC 58 Smart Materials 58.1 Introduction 58.2 Smart/Intelligent Structures 58.3 Objective-Based Classification of Smart/Intelligent Materials Smart Structural Materials • Smart Thermal Materials • Smart Acoustical Materials • Smart Electromagnetic Materials • Pyrosensitive Smart Materials 58.4 Material Properties Conducive for Smart Material Applications Piezoelectric Effect • Magnetostrictive Effect • Electroplastic Effect • Shape-Memory Effects • Electrorheological Property • Nonlinear Electro-optic Properties • Nonlinear Electroacoustic Properties • Pyrosensitive Properties • Nonlinear Electromagnetic Properties 58.5 State-of-the-Art Smart Materials Piezoelectric Smart Materials • Magnetostrictive Smart Materials • Electroplastic Smart Materials • Shape-Memory Smart Materials • Electrorheological Smart Fluids • Electro-optic Smart Materials • Electroacoustic Smart Materials • Electromagnetic Smart Materials • Pyrosensitive Smart Materials 58.6 Smart Sensors Fiber-Optic-Based Sensors • Piezoelectric-Based Sensors • Magnetostriction-Based Sensors • Shape-Memory Effects-Based Sensors • Electromagnetics-Based Sensors • Electroacoustic Smart Sensors 58.7 Examples of Smart/Intelligent Systems Structural Engineering Applications • Electromagnetic Applications 58.8 High-Tech Application Potentials 58.9 Conclusions 58.1 Introduction Smart materials are a class of materials and/or composite media having inherent intelligence together with self-adaptive capabilities to external stimuli. Also known as intelligent materials, they constitute a few subsets of the material family that “manifest their own functions intelligently depending on environmental changes” [Rogers and Rogers, 1992]. Classically, such intelligent material systems have been conceived in the development of mechanical structures that contain their own sensors, actuators and self-assessing computational feasibilities in order to modify their structural (elastic) behavior via feedback control capabilities. The relevant concepts have stemmed from intelligent forms of natural (material) systems, namely, living organisms; hence, in modern concepts smart or P. S. Neelakanta Florida Atlantic University
E IGURE 58.1 Set of structures (Adapted from B. K. Wada, J. L. Fanson, and E. Crawley, "Adaptive structures, "J. Intell Mat. Syst. Struct, 1, 1990.) intelligent materials and systems are conceived as those that mimic the life functions of sensing, actuation, control, and intelligence. The inherent intelligence and self-adaptable control of artificial smart materials terms of the constituent processing, microstructural characteristics, and defects to permit the self-conditionings to adapt in a controlled manner to various types of stimuli. The dividing line between smart materials and the D-called intelligent structures is not, however, distinct. In simple terms, intelligent material systems are constructed of smart materials with a dedicated, discrete set of integrated actuators, sensors, and so on, and nart materials contain largely a built-in or embedded set of distributed sensors. In general, the term smart materials usually connotes the structural constituent in which the discrete functions of sensing, actuation, signal processing and control are tangibly integrated. Intelligent structures, as an extension, are constructed with mart materials to respond to the environment around them in a predetermined, desired manner Intelligent or smart materials that manifest their own functions intelligently vis-a-vis the changes in the Irroundings are capable of performing, in general( Chong et al., 1990) Primary functions specifying the adaptive roles of the sensor, the effector and processor capabilities Macroscopic functions that enclave the extensive or global aspects of the intelligence inherent in the Built-in social utility aspects with an instilled human-like intelligence with hyper-performance capabilities 58.2 Smart/Intelligent Structures The framework of intelligent structures as a subset in the gamut of conventional material-based syster illustrated in Fig. 58. 1. This general classification of material structures refer to [Chong et al, 1990] Sensory structures, which possess sensors that enable the determination or monitoring of system states characteristics"[Chong et al., 1990] Adaptive structures, which possess actuators that facilitate the alteration of system-states or character istics in a controlled manner Adaptive systems, which contain actuators, but no sensors Referring to Fig 58.1, the intersection of sensory versus adaptive structures depicts the controlled structures with a feedback architecture. That is, the active structure has an integrated controlled unit with sensors and/or ctuators that have structural as well as control functionality. Hence, the logical subset that defines an intelligent structure is a highly integrated unit(with controlled logic, electronics, etc. )that provides the cognitive element of a distributed or a hierarchic controlled structure c 2000 by CRC Press LLC
© 2000 by CRC Press LLC intelligent materials and systems are conceived as those that mimic the life functions of sensing, actuation, control, and intelligence. The inherent intelligence and self-adaptable control of artificial smart materials should be programmable in terms of the constituent processing, microstructural characteristics, and defects to permit the self-conditionings to adapt in a controlled manner to various types of stimuli. The dividing line between smart materials and the so-called intelligent structures is not, however, distinct. In simple terms, intelligent material systems are constructed of smart materials with a dedicated, discrete set of integrated actuators, sensors, and so on, and smart materials contain largely a built-in or embedded set of distributed sensors. In general, the term smart materials usually connotes the structural constituent in which the discrete functions of sensing, actuation, signal processing and control are tangibly integrated. Intelligent structures, as an extension, are constructed with smart materials to respond to the environment around them in a predetermined, desired manner. Intelligent or smart materials that manifest their own functions intelligently vis-à-vis the changes in their surroundings are capable of performing, in general (Chong et al., 1990): • Primary functions specifying the adaptive roles of the sensor, the effector and processor capabilities (including the memory functions) • Macroscopic functions that enclave the extensive or global aspects of the intelligence inherent in the materials • Built-in social utility aspects with an instilled human-like intelligence with hyper-performance capabilities 58.2 Smart/Intelligent Structures The framework of intelligent structures as a subset in the gamut of conventional material-based systems is illustrated in Fig. 58.1. This general classification of material structures refer to [Chong et al., 1990]: • Sensory structures, “which possess sensors that enable the determination or monitoring of system states or characteristics” [Chong et al., 1990] • Adaptive structures, which possess actuators that facilitate the alteration of system-states or characteristics in a controlled manner • Sensory systems, which may contain sensors, but no actuators • Adaptive systems, which contain actuators, but no sensors Referring to Fig. 58.1, the intersection of sensory versus adaptive structures depicts the controlled structures with a feedback architecture. That is, the active structure has an integrated controlled unit with sensors and/or actuators that have structural as well as control functionality. Hence, the logical subset that defines an intelligent structure is a highly integrated unit (with controlled logic, electronics, etc.) that provides the cognitive element of a distributed or a hierarchic controlled structure. FIGURE 58.1 Set of structures. (Adapted from B. K. Wada, J. L. Fanson, and E.F. Crawley, “Adaptive structures,” J. Intell. Mat. Syst. Struct., 1, 1990.)
58.3 Objective-Based Classification of Smart/Intelligent Materials Smart Structural materials Itelligent structural engineering materials are the classical versions of smart systems in which the mechanical (elastic) properties of a structure can be modified adaptively by means of an imbedded distribution of smart material(s), and an associated (integral)set of sensors and actuators together with an external control syster to facilitate adaptive changes in the elastic behavior of structures so that motion, vibration, strength, stiffness, redistribution of load path in response to damage, etc. are controlled Smart Thermal materials A smart thermal material, in response to environmental demands, can self-adaptively influence its thermal states(temperature or such thermal properties as conductivity, diffusivity, absorptivity), by means of an integrated conglomeration of thermal sensors, heaters, or actuators with an associated control system Smart Acoustical materials Smart acoustical materials can be classified as those that have self-adaptive characteristics on theiracousticalbehavior such as transmission, reflection, and absorption of acoustical energy) by means of sensors that assess the acoustical states(intensity, frequency, response, etc. ),along with a set of actuators(dampers, exciters)with an associated control system. Again, the self-adaptive behavior of these materials is in response to ambient acoustical changes Smart electromagnetic materials Smart Magnetic shielding materials As warranted by the surroundings, the self-adaptive shielding effectiveness to magnetic fields at low frequencies (power frequencies such as 60 or 50 Hz) can be achieved by means of an integrated set of magnetic field sensors and actuators(magnetic biasing, current elements, etc. )plus a control system arrangement[Neelakanta and High-Frequency Smart Shielding Materials Corresponding to radio and higher frequency environments, the shielding requirement warrants curtailing both electric and magnetic fields. Hence, the relevant self-adaptive intelligent shielding system would consist of an array of distributed electromagnetic sensors with appropriate elements(actuators )and a control system Smart Radar- Absorbing materials Absorption of microwave/millimeter wave energy at radar frequency is useful in radar stealth applications. Adap- tively controllable smart radar-absorbing materials(smart RAMs) can be synthesized with integrated distrib uNion of electromagnetic detectors(sensors)with appropriate actuators and control system [Neelakanta et al., 1992] Smart Optical Surface Materials Smart optical surface materials can be envisioned as those in which the surface optical properties(hue, intensity, etc. )can be adaptively controlled by means of an intelligent sensor/actuator combinational control system. Pyrosensitive Smart Materials Electromagnetic active surfaces constituted by pyrosensitive inclusions have been successfully developed to manage the electromagnetic reflection and/or absorption characteristics from the active surface by means of thermal actu ation of the pyrosensitive nodes imbedded in the medium[Neelakanta et al., 1992]. With the inclusion of a feedback systems, smart operation in adaptively manipulating the active surface characteristics can be achieved. 58.4 Material Properties Conducive for Smart Material applications Certain specific characteristics of materials make them suitable for smart material applications. These properties are:
© 2000 by CRC Press LLC 58.3 Objective-Based Classification of Smart/Intelligent Materials Smart Structural Materials Intelligent structural engineering materials are the classical versions of smart systems in which the mechanical (elastic) properties of a structure can be modified adaptively by means of an imbedded distribution of smart material(s), and an associated (integral) set of sensors and actuators together with an external control system to facilitate adaptive changes in the elastic behavior of structures so that motion, vibration, strength, stiffness, redistribution of load path in response to damage, etc. are controlled. Smart Thermal Materials A smart thermal material, in response to environmental demands, can self-adaptively influence its thermal states (temperature or such thermal properties as conductivity, diffusivity, absorptivity), by means of an integrated conglomeration of thermal sensors, heaters, or actuators with an associated control system. Smart Acoustical Materials Smart acoustical materials can be classified as those that have self-adaptive characteristics on their acoustical behavior (such as transmission,reflection, and absorption of acoustical energy) by means of sensors that assess the acoustical states (intensity, frequency, response, etc.), along with a set of actuators (dampers, exciters) with an associated control system. Again, the self-adaptive behavior of these materials is in response to ambient acoustical changes. Smart Electromagnetic Materials Smart Magnetic Shielding Materials As warranted by the surroundings, the self-adaptive shielding effectiveness to magnetic fields at low frequencies (power frequencies such as 60 or 50 Hz) can be achieved by means of an integrated set of magnetic field sensors and actuators (magnetic biasing, current elements, etc.) plus a control system arrangement [Neelakanta and Subramaniam, 1992]. High-Frequency Smart Shielding Materials Corresponding to radio and higher frequency environments, the shielding requirement warrants curtailing both electric and magnetic fields. Hence, the relevant self-adaptive intelligent shielding system would consist of an array of distributed electromagnetic sensors with appropriate elements (actuators) and a control system. Smart Radar-Absorbing Materials Absorption of microwave/millimeter wave energy at radar frequency is useful in radar stealth applications. Adaptively controllable smart radar-absorbing materials (smart RAMs) can be synthesized with integrated distribution of electromagnetic detectors (sensors) with appropriate actuators and control system [Neelakanta et al., 1992]. Smart Optical Surface Materials Smart optical surface materials can be envisioned as those in which the surface optical properties (hue, intensity, etc.) can be adaptively controlled by means of an intelligent sensor/actuator combinational control system. Pyrosensitive Smart Materials Electromagnetic active surfaces constituted by pyrosensitive inclusions have been successfully developed to manage the electromagnetic reflection and/or absorption characteristics from the active surface by means of thermal actuation of the pyrosensitive nodes imbedded in the medium [Neelakanta et al., 1992].With the inclusion of a feedback systems, smart operation in adaptively manipulating the active surface characteristics can be achieved. 58.4 Material Properties Conducive for Smart Material Applications Certain specific characteristics of materials make them suitable for smart material applications. These properties are:
1. Piezoelectric effect 3. Electroplastic effect 5. Electrorheological properties 6. Nonlinear electro-optic properties 7. Nonlinear electroacoustic properties 8. Nonlinear electromagnetic properties 9. Pyrosensitive properti iezoelectric effect Piezoelectric property of a material refers to the ability to induce opposite charges at two faces (correspondingly, to exhibit a voltage difference between the faces)of the material as a result of the strain due to mechanical force(either tension or compression) applied across the surfaces. This process is also reversible in the sense that a mechanical strain would be experienced in the material when subjected to opposite electric charging at the two faces by means of an applied potential. In the event of such an applied voltage being alternating, the material specimen will experience vibrations likewise, an applied vibration on the specimen would induce an alternating potential change between the two faces. The most commonly known materials that exhibit piezoelectric properties are natural materials like quartz and a number of crystalline and polycrystalline compounds The strain versus the electric phenomenon perceived in piezoelectric materials is dictated by a coefficient that has components referred to a set of orthogonal coordinate axes(which are correlated to standard crystal lographic axes). For example, denoting the piezoelectric coefficient(ratio between piezoelectric strain compo- nent to applied electric field component at a constant mechanical stress or vice versa) as dmm, the subscript n (1 to 3)refers to the three euclidian orthogonal axes, and m= l to 6 specifies the mechanical stress-strain components. The unit for dmm is meter/volt which is the same as coulomb/newton energy impressed on the material. Being a reversible process, a relevant inverse ratio is also applicable Magnetostrictive Effect Magnetostrictive effect refers to the structural strain experienced in a material subjected to a polarizing magnetic flux. A static strain of Al/l is produced by a dc polarizing magnetic flux density B, such that Al/l CB,, where C is a material constant expressed in(meter/weber )taking the units for B, as weber/meter The magnetic stress constant(A)in(newton/weber)is given by A=2CB Y, where Y, refers to the Youngs modulus of a linearly strained free bar. The coefficient(A)could be both positive or negative. For examp nickel contracts with increasing B, whereas magnetic alloys such as 45 Permalloy(45% Ni 55% Fe), Alfer (13%AL, 87%Fe)exhibit positive magnetostrictive coefficient [Reed, 1988 Electroplastic Effect The electroplastic effect(EPE)refers to the plastic deformation of metals with the application of high-density electric current with an enhanced deformation rate(that persists in addition to that caused by the side effects of the current such as joule-heating and the magnetic pinch effect). The plastic strain rate resulting from a current pulse is given by Eye=a F exp(Bn) where E, is the strain rate occurring during the current pulse, Ea is the strain rate in the absence of the current pulse, J is the current density and a and B are material constants Typically the EPe has been observed in zinc, niobium, titanium, etc Shape-Memory Effects The mechanism by which a plastically deformed object in the low-temperature martensitic condition reg its original shape when the external stress is removed and heat is applied is referred to as the shape-m c 2000 by CRC Press LLC
© 2000 by CRC Press LLC 1. Piezoelectric effect 2. Magnetostrictive effect 3. Electroplastic effect 4. Shape-memory effects 5. Electrorheological properties 6. Nonlinear electro-optic properties 7. Nonlinear electroacoustic properties 8. Nonlinear electromagnetic properties 9. Pyrosensitive properties Piezoelectric Effect Piezoelectric property of a material refers to the ability to induce opposite charges at two faces (correspondingly, to exhibit a voltage difference between the faces) of the material as a result of the strain due to mechanical force (either tension or compression) applied across the surfaces. This process is also reversible in the sense that a mechanical strain would be experienced in the material when subjected to opposite electric charging at the two faces by means of an applied potential. In the event of such an applied voltage being alternating, the material specimen will experience vibrations. Likewise, an applied vibration on the specimen would induce an alternating potential change between the two faces. The most commonly known materials that exhibit piezoelectric properties are natural materials like quartz and a number of crystalline and polycrystalline compounds. The strain versus the electric phenomenon perceived in piezoelectric materials is dictated by a coefficient that has components referred to a set of orthogonal coordinate axes (which are correlated to standard crystallographic axes). For example, denoting the piezoelectric coefficient (ratio between piezoelectric strain component to applied electric field component at a constant mechanical stress or vice versa) as dmn, the subscript n (1 to 3) refers to the three euclidian orthogonal axes, and m = 1 to 6 specifies the mechanical stress-strain components. The unit for dmn is meter/volt which is the same as coulomb/newton. In the piezoelectric phenomenon, there is an electromechanical synergism expressed as a coupling factor K defined by K2 , which quantifies the ratio of mechanical energy converted into electric charges to the mechanical energy impressed on the material. Being a reversible process, a relevant inverse ratio is also applicable. Magnetostrictive Effect Magnetostrictive effect refers to the structural strain experienced in a material subjected to a polarizing magnetic flux. A static strain of Dl/l is produced by a dc polarizing magnetic flux density Bo such that Dl/l = CBo 2 , where C is a material constant expressed in (meter4 /weber2 ) taking the units for Bo as weber/meter2 . The magnetic stress constant (L) in (newton/weber) is given by L = 2CBoYo where Yo refers to the Young’s modulus of a linearly strained free bar. The coefficient (L) could be both positive or negative. For example, nickel contracts with increasing Bo, whereas magnetic alloys such as 45 Permalloy (45% Ni + 55% Fe), Alfer (13% Al, 87% Fe) exhibit positive magnetostrictive coefficient [Reed, 1988]. Electroplastic Effect The electroplastic effect (EPE) refers to the plastic deformation of metals with the application of high-density electric current with an enhanced deformation rate (that persists in addition to that caused by the side effects of the current such as joule-heating and the magnetic pinch effect). The plastic strain rate resulting from a current pulse is given by eI /eA = a J2 exp(bJ) where eI is the strain rate occurring during the current pulse, eA is the strain rate in the absence of the current pulse, J is the current density and a and b are material constants. Typically the EPE has been observed in zinc, niobium, titanium, etc. Shape-Memory Effects The mechanism by which a plastically deformed object in the low-temperature martensitic condition regains its original shape when the external stress is removed and heat is applied is referred to as the shape-memory
SMART/INTELLIGENT MATERIALS STRUCTURAL APPLICATIONS Nonli near ferromagnetic effect Pyrosensftive effect Electroplastic effect ACOUSTICAL APPLICATIONS OPTICAL APPLICATIONS Magnetostrictive effect (Kerr effect and Pockel's effect) Electrochromic effect Reman active effect FIGURE 58.2 Applicatio ific classification of smart/intelligent materials effect(SME) [Jackson et al., 1972]. It is a memory mechanism that is the result of a martensitic transformation taking place during heating Alhough the exact mechanism by which the shape-memory effect occurs is still under study, the process by which the original shape is regained is associated with a reverse transformation of the deformed martensitic phase to the higher temperature austenite phase. A group of nickel-titanium alloys(referred to as Nitinol)of proper composition exhibit the shape-memory property and are widely used in smart material applications [Jackson et al., 1972] Electrorheological Property Electrorheological property is the property exhibited by certain fluids that are capable of altering their flow haracteristics depending on an external applied electric field. These fluids have a fast response time, only a few milliseconds. Once the external field is applied, there is a form of progressive gelling of the fluid proportional to the applied field strength. Without the applied field, the fluid flows freely. If the electrified electrorheological (ER)fluid is sheared by an applied force larger than a certain critical value, it flows. Below this critical value of applied shear force, the electrified fluid remains in the gel phase [gandhi and Thompson, 1989] An electrorheological fluid requires particles(1 to 100 mm in diameter)dispersed in a carrier fluid. Sometimes a surfactant is also added to help the dispersion of particles in the fluid. The surfactant is used to prevent particle interaction that could otherwise result in a tendency for the particulates to clump together when the fluid is allowed to stand still over a stretch of time. The tendency of the particles to clump together is referred to as settling The applied electric field to perceive the electrorheological phenomenon is usually in the order of 4 kv/mm. When the electric field is applied, the positive and negative charges on the suspended particles are separated, forming a dipole of charges. These dipoles then align(polarize)themselves by mutual forces of attraction and repulsion to other similar dipoles, resulting in unique flow characteristics. In the absence of an electric there is no dipole separation of charges, and hence the fluid returns to its normal flow An ideal electrorheological fluid is one that has a low viscosity in the absence of an applied field and that which transforms into a high-viscosity gel capable of withstanding high shear stresses when the field is on. Further, it must also have a low power consumption. The first reported ER fluid consisted of finely dispersed suspensions of starch or silica gel in mineral oil nearly 40 years ago. Nonlinear Electro-optic Properties In certain materials that are optically transparent when subjected to an external electric field, the refractive index of the material changes. Invariably the electric field versus optical effect thus experienced is nonlinear, c 2000 by CRC Press LLC
© 2000 by CRC Press LLC effect (SME) [Jackson et al., 1972]. It is a memory mechanism that is the result of a martensitic transformation taking place during heating. Alhough the exact mechanism by which the shape-memory effect occurs is still under study, the process by which the original shape is regained is associated with a reverse transformation of the deformed martensitic phase to the higher temperature austenite phase.A group of nickel-titanium alloys (referred to as Nitinol) of proper composition exhibit the shape-memory property and are widely used in smart material applications [Jackson et al., 1972]. Electrorheological Property Electrorheological property is the property exhibited by certain fluids that are capable of altering their flow characteristics depending on an external applied electric field. These fluids have a fast response time, only a few milliseconds. Once the external field is applied, there is a form of progressive gelling of the fluid proportional to the applied field strength. Without the applied field, the fluid flows freely. If the electrified electrorheological (ER) fluid is sheared by an applied force larger than a certain critical value, it flows. Below this critical value of applied shear force, the electrified fluid remains in the gel phase [Gandhi and Thompson, 1989]. An electrorheological fluid requires particles (1 to 100 mm in diameter) dispersed in a carrier fluid. Sometimes a surfactant is also added to help the dispersion of particles in the fluid. The surfactant is used to prevent particle interaction that could otherwise result in a tendency for the particulates to clump together when the fluid is allowed to stand still over a stretch of time. The tendency of the particles to clump together is referred to as settling. The applied electric field to perceive the electrorheological phenomenon is usually in the order of 4 kV/mm. When the electric field is applied, the positive and negative charges on the suspended particles are separated, forming a dipole of charges. These dipoles then align (polarize) themselves by mutual forces of attraction and repulsion to other similar dipoles, resulting in unique flow characteristics. In the absence of an electric field, there is no dipole separation of charges, and hence the fluid returns to its normal flow. An ideal electrorheological fluid is one that has a low viscosity in the absence of an applied field and that which transforms into a high-viscosity gel capable of withstanding high shear stresses when the field is on. Further, it must also have a low power consumption. The first reported ER fluid consisted of finely dispersed suspensions of starch or silica gel in mineral oil nearly 40 years ago. Nonlinear Electro-optic Properties In certain materials that are optically transparent when subjected to an external electric field, the refractive index of the material changes. Invariably the electric field versus optical effect thus experienced is nonlinear, FIGURE 58.2 Application-specific classification of smart/intelligent materials
with the result that a time-varying electric field will modulate the refractive index, and hence a phase shift is experienced by the light passing through the medium. In materials that have a central symmetry, this phenomenon is called the Kerr effect; in noncentrosymmetric materials, it is referred to as Pockel's effect [ Kaminow, 1965] Nonlinear Electroacoustic Properties Electroacoustic synergism is experienced in certain classes of materials in which the mechanical atomic vibrations re influenced by the electronic polarizability, with the result that nonlinear interaction between the atomic dis- placements versus the electric field causes modulation effects resulting in the generation of new sideband frequencies uch sidebands(labeled Raman frequencies)and the response function of a Raman active medium have the form H(u)=A1E(u)+A2E2(u)+A3E3(o)+ Pyrosensitive properties The pyrosensitive property is governed by a class of materials known as solid electrolytes. On thermally energizing such materials, they exhibit superionic electric conduction(also known as fast ion conduction) with the result that the medium, which is dielectric under cold conditions, becomes conducting at elevated temperatures. Correspondingly, the media that are embedded with solid electrolytes show different extents of electromagnetic reflection/transmission characteristics at low and high temperatures and hence can be manip- ulated thermally (Neelakanta et al., 1992 e Typical solid electrolytes that can be adopted for such pyrosensitive applications are, for example, Agl and rbAgIs. materials like B-Agl and B-alumina show increasing conductivity with increasing temperature. The compound B-AgI exhibits superionic conductivity, with an abrupt transition at a temperature close to 147"C. This transition is known as the B-to a-phase transition, and there are a host of other materials that exhibit this phenomenon. For example, the material RbAg I, has a high electrical conductivity even at room temperature. It has also been observed that solid electrolytes provide sufficiently high electrical conductivity in the a-phase even when included in low volume fractions in a mixture with a nonsolid-electrolyte host[Neelakanta et al., 1992] Nonlinear Electromagnetic Properties Basically, the nonlinear electromagnetic properties can manifest as two subsets of material characteristics, namely, nonlinear dielectric properties and nonlinear magnetic properties Nonlinear Dielectric Properties are referred to as active or nonlinear dielectrics. Such materials demonstrate very high values of permittivity (in the order of several thousand), pronounced dependence of dielectric parameters on the temperature, and a loop of electric hysteresis under the action of an alternating voltage. Ferroelectrics are the most typical example of nonlinear dielectrics. Rochelle's salt(potassium sodium artrate)was the first substance in which nonlinearity was discovered. All ferroelectrics, however, possess nonlinear properties only within a definite temperature range. The temperature transition points over which the ferroelectric materials gain or lose their ferroelectric properties are referred to as Curie points. The arsenates and dihydrogen phosphates of alkali metals are also examples of ferroelectric materials. Piezoelectrics also fall under the category of active dielectrics. Electrets, which are capable of preserving an electric charge for a long period of time(hence regarded analogous to permanent magnets), exhibit highly nonlinear dielectric properti Nonlinear Magnetic Properties Ferromagnetic materials are materials in which the permanent magnetic dipoles align themselves parallel to each other. These materials have a characteristic temperature below and above which their properties differ greatly. This temperature is referred to as the Curie temperature. Above the Curie temperature they behave as paramagnetic materials, while below it they exhibit the well known hysteresis B versus H curves. Examples of such ferromagnetic materials are iron, Mu-metal, and Supermalloy Ferrimagnetic materials are similar in their hysteresis properties to ferromagnetic materials but differ from them in that their magnetic dipoles aligi c 2000 by CRC Press LLC
© 2000 by CRC Press LLC with the result that a time-varying electric field will modulate the refractive index, and hence a phase shift is experienced by the light passing through the medium. In materials that have a central symmetry, this phenomenon is called the Kerr effect; in noncentrosymmetric materials, it is referred to as Pockel’s effect [Kaminow, 1965]. Nonlinear Electroacoustic Properties Electroacoustic synergism is experienced in certain classes of materials in which the mechanical atomic vibrations are influenced by the electronic polarizability, with the result that nonlinear interaction between the atomic displacements versus the electric field causes modulation effects resulting in the generation of new sideband frequencies. Such sidebands (labeled Raman frequencies) and the response function of a Raman active medium have the form H(v) = A1E(v) + A2E 2(v) + A3E 3(v) + · · · Pyrosensitive Properties The pyrosensitive property is governed by a class of materials known as solid electrolytes. On thermally energizing such materials, they exhibit superionic electric conduction (also known as fast ion conduction), with the result that the medium, which is dielectric under cold conditions, becomes conducting at elevated temperatures. Correspondingly, the media that are embedded with solid electrolytes show different extents of electromagnetic reflection/transmission characteristics at low and high temperatures and hence can be manipulated thermally [Neelakanta et al., 1992]. Typical solid electrolytes that can be adopted for such pyrosensitive applications are, for example,AgI and RbAg4I5. The materials like b-AgI and b-alumina show increasing conductivity with increasing temperature. The compound b-AgI exhibits superionic conductivity, with an abrupt transition at a temperature close to 147°C. This transition is known as the b- to a-phase transition, and there are a host of other materials that exhibit this phenomenon. For example, the material RbAg4I5 has a high electrical conductivity even at room temperature.It has also been observed that solid electrolytes provide sufficiently high electrical conductivity in the a-phase even when included in low volume fractions in a mixture with a nonsolid-electrolyte host [Neelakanta et al., 1992]. Nonlinear Electromagnetic Properties Basically, the nonlinear electromagnetic properties can manifest as two subsets of material characteristics, namely, nonlinear dielectric properties and nonlinear magnetic properties. Nonlinear Dielectric Properties Dielectric materials whose permittivity has a distinct dependence on the intensity of the applied electric field are referred to as active or nonlinear dielectrics. Such materials demonstrate very high values of permittivity (in the order of several thousand), pronounced dependence of dielectric parameters on the temperature, and a loop of electric hysteresis under the action of an alternating voltage. Ferroelectrics are the most typical example of nonlinear dielectrics. Rochelle’s salt (potassium sodium tartrate) was the first substance in which nonlinearity was discovered. All ferroelectrics, however, possess nonlinear properties only within a definite temperature range. The temperature transition points over which the ferroelectric materials gain or lose their ferroelectric properties are referred to as Curie points. The arsenates and dihydrogen phosphates of alkali metals are also examples of ferroelectric materials. Piezoelectrics also fall under the category of active dielectrics. Electrets, which are capable of preserving an electric charge for a long period of time (hence regarded analogous to permanent magnets), exhibit highly nonlinear dielectric properties. Nonlinear Magnetic Properties Ferromagnetic materials are materials in which the permanent magnetic dipoles align themselves parallel to each other. These materials have a characteristic temperature below and above which their properties differ greatly. This temperature is referred to as the Curie temperature. Above the Curie temperature they behave as paramagnetic materials, while below it they exhibit the well known hysteresis B versus H curves. Examples of such ferromagnetic materials are iron, Mu-metal, and Supermalloy. Ferrimagnetic materials are similar in their hysteresis properties to ferromagnetic materials but differ from them in that their magnetic dipoles align
themselves antiparallel to each other. Ferrites are the most popular ferrimagnetic materials, and they are of the greatest interest in electrical engineering applications. 58.5 State-of-the-Art Smart materials Piezoelectric smart Materials Piezoelectric smart materials find applications primarily in intelligent structures deploying electroelastic syn ergism, and a class of ceramics(popularly known as ferroelectric ceramics)have emerged in recent times for uch applications. Typically, such ceramics include the base polycrystalline piezoelectrics such as BaTio CdTiO,, PbZrO,, and PbTiOj, formulated with various stoichiometric proportions. Another class of piezoelec- tric flexible composite that has the pot for smart applications is a compound consisting of PbTiO, and hloroprene rubber. A set of glass ceramic composites containing the crystalline phases of Li2 SiO3, Li Si2O Ba2TiSi2Os, Ba, TiGe,Og, Li, B,O,, etc are also emerging samples in smart material engineering I Chong et al, 1990] Piezoelectric smart materials can also be made from the family of polymers, namely, polyvinylidene fluoride (PVDF). The main advantages of using this polymer are that it can be formed into very thin sheets and has excellent mechanical strength combined with high sensitivity to pressure changes. Another piezoelectric material recently developed in the ntK Research facility in Japan is a kind of rubber based material referred to as piezoelectric rubber. This material is composed of a base material of synthetic ubber, namely, chloroben, dispersed with fine particles of a popular piezoelectric ceramic, called PZT (lead zirconium titanate). Piezoelectric rubber combines the favorable properties of PZT, namely, high sensitivity, chemical inertness, linearity, and simplicity, with that of the rubber base, namely, flexibility. The main drawback with the piezoelectric rubber is in making an electrical contact with it. This problem has been circumvented by the development of a coaxial cable connection that is easier to use [Ting, 1990] Magnetostrictive Smart Materials Materials with a high degree of magnetostriction are deployed in modern intelligent structures. Typically, the amount of strain inducible with intelligent materials in the current state of the art is 2000 ppm. These are alle made with iron and rare earth materials such as terbium(Te), dysprosium(Dy), and niobium (Nb).A commercially known material of this category is Terfenol [ Reed, 1988]. Magnetostrictive transducers for smart applications have also been developed with a certain class of metallic glass materials. Electroplastic Smart Materials Electroplastic materials are useful as smart elastic media inasmuch as the stimulus that modifies the elastic deformation is the electric current that can be controlled externally. The usefulness of these materials for smart systems under room temperature conditions is still under investigation Shape-Memory Smart Materials shape-memory smart materials include three categories, namely shape-memory alloys( SMA), shape-memory hybrid composites(SMHC), and shape-memory polymers(SMP) Nickel-titanium(Nitinol)alloys of proper composition exhibit unique memory, or shape-restoration force characteristics, and are the most popular shape-memory alloys. When the material is plastically deformed in low-temperature phase and then heated above its characteristic transition temperature, the original config uration or shape is restored. Deformations up to 6-8% can be completely restored by heating the material. It is this property that is used in smart electromechanical actuations shape-memory hybrid composites are composite materials that contain SMA fibers or films in such a way that they can be mechanically controlled by heat. These materials can be heated by passing a current through the fibers. SMHCs offer a wide scope of applications in material-structure interaction. The fibers used in these composites are also made of Nitinol alloys The third form of shape-memory materials are the shape-memory polymers. These materials have an elastic memory, meaning that a large reversible change in the elastic modulus exists across the glass-transition c 2000 by CRC Press LLC
© 2000 by CRC Press LLC themselves antiparallel to each other. Ferrites are the most popular ferrimagnetic materials, and they are of the greatest interest in electrical engineering applications. 58.5 State-of-the-Art Smart Materials Piezoelectric Smart Materials Piezoelectric smart materials find applications primarily in intelligent structures deploying electroelastic synergism, and a class of ceramics (popularly known as ferroelectric ceramics) have emerged in recent times for such applications. Typically, such ceramics include the base polycrystalline piezoelectrics such as BaTiO3, CdTiO3, PbZrO3, and PbTiO3, formulated with various stoichiometric proportions. Another class of piezoelectric flexible composite that has the potential for smart applications is a compound consisting of PbTiO3 and chloroprene rubber. A set of glass ceramic composites containing the crystalline phases of Li2SiO3, Li2Si2O5, Ba2TiSi2O8, Ba2TiGe2O8, Li2B4O7, etc. are also emerging samples in smart material engineering [Chong et al., 1990]. Piezoelectric smart materials can also be made from the family of polymers, namely, polyvinylidene fluoride (PVDF). The main advantages of using this polymer are that it can be formed into very thin sheets and has excellent mechanical strength combined with high sensitivity to pressure changes. Another piezoelectric material recently developed in the NTK Research facility in Japan is a kind of rubberbased material referred to as piezoelectric rubber. This material is composed of a base material of synthetic rubber, namely, chloroben, dispersed with fine particles of a popular piezoelectric ceramic, called PZT (lead zirconium titanate). Piezoelectric rubber combines the favorable properties of PZT, namely, high sensitivity, chemical inertness, linearity, and simplicity, with that of the rubber base, namely, flexibility. The main drawback with the piezoelectric rubber is in making an electrical contact with it. This problem has been circumvented by the development of a coaxial cable connection that is easier to use [Ting, 1990]. Magnetostrictive Smart Materials Materials with a high degree of magnetostriction are deployed in modern intelligent structures. Typically, the amount of strain inducible with intelligent materials in the current state of the art is 2000 ppm. These are alloys made with iron and rare earth materials such as terbium (Te), dysprosium (Dy), and niobium (Nb). A commercially known material of this category is Terfenol [Reed, 1988]. Magnetostrictive transducers for smart applications have also been developed with a certain class of metallic glass materials. Electroplastic Smart Materials Electroplastic materials are useful as smart elastic media inasmuch as the stimulus that modifies the elastic deformation is the electric current that can be controlled externally. The usefulness of these materials for smart systems under room temperature conditions is still under investigation. Shape-Memory Smart Materials Shape-memory smart materials include three categories, namely shape-memory alloys (SMA), shape-memory hybrid composites (SMHC), and shape-memory polymers (SMP). Nickel–titanium (Nitinol) alloys of proper composition exhibit unique memory, or shape-restoration force characteristics, and are the most popular shape-memory alloys. When the material is plastically deformed in its low-temperature phase and then heated above its characteristic transition temperature, the original configuration or shape is restored. Deformations up to 6–8% can be completely restored by heating the material. It is this property that is used in smart electromechanical actuations. Shape-memory hybrid composites are composite materials that contain SMA fibers or films in such a way that they can be mechanically controlled by heat. These materials can be heated by passing a current through the fibers. SMHCs offer a wide scope of applications in material–structure interaction. The fibers used in these composites are also made of Nitinol alloys. The third form of shape-memory materials are the shape-memory polymers. These materials have an elastic memory, meaning that a large reversible change in the elastic modulus exists across the glass-transition
temperature. In other words, across the glass-transition temperature, the material can change from a glass to rubbery state, allowing significant deformation in response to temperature changes. Shape-memory polymers general, are durable, lightweight, and transparent. Nippon Zeon Company and Mitsubishi Company have developed high-performance SMPs in the recent past [Chong et al., 1990]. While the SMP of Nippon Zeon Company is polynorborene based, Mitsubishis SMP is polyurethane based, which overcomes crucial weaknesses such as poor processability and limited-temperature operating range. In their applications SMPs can be used either as an elastic memory material or a shape-memory material. Depending on which of these possibilities are used, the range of applications differs. Electrorheological Smart Fluids Current research on electrorheological fluids is focused toward development of carrier-particle combinations that result in the desirable characteristics to achieve smart elastic behavior [Gandhi and Thompson, 1989]. The earlier versions of electrorheological fluids contained adsorbed water, which their operating temperat change(up to 80C) Particles in the newer electrorheological fluids are, however, based on polymers, minerals, and ceramics, which have a higher operating range(200%C). Also, the increase in power consumption is less with temperature increments in the recent anhydrous systems. The most commonly used carrier fluids are silicone oil, mineral oil, and chlorinated paraffin, which offer good insulation and compatibility for particulate disp Electro-optic Smart Materials Typically potassium dihydrogen phosphate(KDP)exhibits electro-optic behavior. Synthetic materials that have the ability to alter their refractive index(and hence the optical transmission and reflection characteristics)in the presence of an electric stimulus can be comprehended as viable smart sensor applications. Electroacoustic smart materials Although classically the nonlinear interaction of a vibrational(acousticwave and an electromagnetic wave has been studied in reference to Raman active media, relevant concepts can be exercised for smart engineering applications using those materials that exhibit strong vibrational versus piezoelectric characteristics. The NTK piezorubber, PZT ceramics, LiNBO3, PZT with donor additives, insolvent additives, etc are viable candidates for smart applications in addition to piezoelectric polymers. Electromagnetic smart Materials In recent times a number of materials that possess ferroelectric properties have been discovered, the most popular of which is barium titanate(BaTiO3 ) Barium titanate has an excellent prospect as a smart material because of the several advantages it offers, such as high mechanical strength, resistance to heat and moisture, and ease of manufacturing. BaTiO, and other similar materials are frequently referred to as ferroelectric ceramics. Also, electrets such as polymethylmethacrylate offer promise for smart applications. Among the nonlinear magnetic materials, ferromagnetic materials such as alnico V, platinum-cobalt, and a variety of ferrites are possible smart materials Pyrosensitive Smart Materials Pyrosensitive smart materials are useful in realizing intelligent electromagnetic active surfaces, radar materials, electromagnetic shielding, and so on. For example, it has been demonstrated [Neelakanta et that the microwave reflection characteristics at a surface of a composite medium comprised of controllable, solid-electrolytic zones(made of AgI pellets)show broadband microwave absorption/reflection characteristics under elevated temperatures. This principle can be adopted in conjunction with an electromag netic sensor to provide a controllable feedback for thermal activation of fast-ion zones reconfigurably in order to acheive smart active-surface characteristics. Exclusive for this application, depending on the temperature limited conditions, the solid electrolyte can be chosen on the basis of its a-to B-phase transition characteristics In order to keep the cost of the system low, a mixture phase can also be adopted, in which, commensurate with the elevated temperature operation, the host medium of the mixture could be a ceramic( dielectric) C 2000 by CRC Press LLC
© 2000 by CRC Press LLC temperature. In other words, across the glass-transition temperature, the material can change from a glass to rubbery state, allowing significant deformation in response to temperature changes. Shape-memory polymers, in general, are durable, lightweight, and transparent. Nippon Zeon Company and Mitsubishi Company have developed high-performance SMPs in the recent past [Chong et al., 1990]. While the SMP of Nippon Zeon Company is polynorborene based, Mitsubishi’s SMP is polyurethane based, which overcomes crucial weaknesses such as poor processability and limited-temperature operating range. In their applications SMPs can be used either as an elastic memory material or a shape-memory material. Depending on which of these possibilities are used, the range of applications differs. Electrorheological Smart Fluids Current research on electrorheological fluids is focused toward development of carrier–particle combinations that result in the desirable characteristics to achieve smart elastic behavior [Gandhi and Thompson, 1989]. The earlier versions of electrorheological fluids contained adsorbed water, which limited their operating temperature change (up to 80°C). Particles in the newer electrorheological fluids are, however, based on polymers, minerals, and ceramics, which have a higher operating range (200°C). Also, the increase in power consumption is less with temperature increments in the recent anhydrous systems. The most commonly used carrier fluids are silicone oil, mineral oil, and chlorinated paraffin, which offer good insulation and compatibility for particulate dispersion. Electro-optic Smart Materials Typically potassium dihydrogen phosphate (KDP) exhibits electro-optic behavior. Synthetic materials that have the ability to alter their refractive index (and hence the optical transmission and reflection characteristics) in the presence of an electric stimulus can be comprehended as viable smart sensor applications. Electroacoustic Smart Materials Although classically the nonlinear interaction of a vibrational (acoustic) wave and an electromagnetic wave has been studied in reference to Raman active media, relevant concepts can be exercised for smart engineering applications using those materials that exhibit strong vibrational versus piezoelectric characteristics. The NTK piezorubber, PZT ceramics, LiNBO3, PZT with donor additives, insolvent additives, etc. are viable candidates for smart applications in addition to piezoelectric polymers. Electromagnetic Smart Materials In recent times a number of materials that possess ferroelectric properties have been discovered, the most popular of which is barium titanate (BaTiO3). Barium titanate has an excellent prospect as a smart material because of the several advantages it offers, such as high mechanical strength, resistance to heat and moisture, and ease of manufacturing. BaTiO3 and other similar materials are frequently referred to as ferroelectric ceramics. Also, electrets such as polymethylmethacrylate offer promise for smart applications. Among the nonlinear magnetic materials, ferromagnetic materials such as Alnico V, platinum– cobalt, and a variety of ferrites are possible smart materials. Pyrosensitive Smart Materials Pyrosensitive smart materials are useful in realizing intelligent electromagnetic active surfaces, radar-absorbing materials, electromagnetic shielding, and so on. For example, it has been demonstrated [Neelakanta et al., 1992] that the microwave reflection characteristics at a surface of a composite medium comprised of thermally controllable, solid-electrolytic zones (made of AgI pellets) show broadband microwave absorption/reflection characteristics under elevated temperatures. This principle can be adopted in conjunction with an electromagnetic sensor to provide a controllable feedback for thermal activation of fast-ion zones reconfigurably in order to acheive smart active-surface characteristics. Exclusive for this application, depending on the temperature limited conditions, the solid electrolyte can be chosen on the basis of its a- to b-phase transition characteristics. In order to keep the cost of the system low, a mixture phase can also be adopted, in which, commensurate with the elevated temperature operation, the host medium of the mixture could be a ceramic (dielectric)
58.6 Smart Sensors Fiber-Optic- Based Sensors The field of sensing technology has been revolutionized in the past decade by the entry of fiber optics. The properties of fiber optics that have made the technology suitable for communications are responsible for being successful as a sensor as well. Fiber-optic sensors are of two types, namely, extrinsic and intrinsic. In the extrinsic type, the fiber itself acts only as a transmitter and does no part of the sensing. In an intrinsic type, however,the fiber acts as a sensor by using one of its intrinsic properties, such as induced birefringence or electrochromatism, to detect a phenomenon or quantify a measurement. Relevant to smart systems, the use of fiber optics in conjunction with optical(sensors) is based on changes in optical effects such as refractive index, ptical absorption, luminescence, and chromic properties due to alterations in the environment in which the fiber is imbedded. Such alterations refer to strain or other elastic characteristics and thermal and/or electro- magnetic properties [Claus, 1991]. Surfaces located with smart fiber sensors are known as smart skins Piezoelectric- Based Sensors The most conventional form of sensing technology is that of piezoelectric materials, which generate an electrical response to a stimulus. In recent times piezoelectric materials have been greatly improved in mechanical strength and sensitivity. Pressure and vibration can be directly sensed as a one-to-one transduction effect resulting from the elastic-to-piezoelectric effect Bending, on the other hand, can be sensed via piezoabsorption characteristics Magnetostriction-Based Sensors The use of metallic glass as a distributive magnetostrictive sensor has been studied. Typically, in the imbedded smart sensing applications using the magnetostrictive property, the magnetic field is in the submicrogauss regime, and the nonlinearity associated with the hysteresis of magnetostriction provides a detectable sensor ignal Pressure and force, which cause static or quasi-static magnetic fields, as well as vibrations, which induce alternating magnetic fields, can be regarded as direct magnetostrictive sensor responses In the bending mode, corresponding magnetostrictive absorption can also be sensed via reduction in the Q-factor due to absorption losses in a magnetostrictively tunable syster hape Memory Effects Based Sensors The latest form of sensing technology utilizes shape-memory materials, namely, Nitinol alloys. The Nitinol sensors are used to measure strain and consist of superelastic Nitinol wires. The basic concept is to measure the change in resistance of a Nitinol wire used as an unbalanced arm of a Wheatstone bridge as a function of the strain. The desirable properties of Nitinol in such a sensing application are its high sensitivity and super elastic nature(which permits strains up to 6%to be accurately and repeatedly measured). The piezoelectric and Nitinol sensing materials can also be used for actuation applications. Electromagnetics- Based Se Smart electromagnetic sensors are simple deviations of classic electric/magnetic probes, more properly known as antennas or pickups. Depending on changes in the surroundings vis-a-vis the electromagnetic characteristics, hese sensors respond and yield a corresponding signal. Again, the environmental changes refer to possible alterations caused by elastic, thermal, optical, magnetic, electric, and/or chemical influences. Electroacoustic smart sensors Electroacoustic smart sensors are embedded acoustic (vibration) sensors(similiar to a microphone) that adaptively yield a signal proportional to the acoustic input. Such inputs could result from changes in the alterations in the surroundings caused by elastic or thermal effects. c 2000 by CRC Press LLC
© 2000 by CRC Press LLC 58.6 Smart Sensors Fiber-Optic-Based Sensors The field of sensing technology has been revolutionized in the past decade by the entry of fiber optics. The properties of fiber optics that have made the technology suitable for communications are responsible for it being successful as a sensor as well. Fiber-optic sensors are of two types, namely, extrinsic and intrinsic. In the extrinsic type, the fiber itself acts only as a transmitter and does no part of the sensing. In an intrinsic type, however, the fiber acts as a sensor by using one of its intrinsic properties, such as induced birefringence or electrochromatism, to detect a phenomenon or quantify a measurement. Relevant to smart systems, the use of fiber optics in conjunction with optical (sensors) is based on changes in optical effects such as refractive index, optical absorption, luminescence, and chromic properties due to alterations in the environment in which the fiber is imbedded. Such alterations refer to strain or other elastic characteristics and thermal and/or electromagnetic properties [Claus, 1991]. Surfaces located with smart fiber sensors are known as smart skins. Piezoelectric-Based Sensors The most conventional form of sensing technology is that of piezoelectric materials, which generate an electrical response to a stimulus. In recent times piezoelectric materials have been greatly improved in mechanical strength and sensitivity. Pressure and vibration can be directly sensed as a one-to-one transduction effect resulting from the elastic-to-piezoelectric effect. Bending, on the other hand, can be sensed via piezoabsorption characteristics. Magnetostriction-Based Sensors The use of metallic glass as a distributive magnetostrictive sensor has been studied. Typically, in the imbedded smart sensing applications using the magnetostrictive property, the magnetic field is in the submicrogauss regime, and the nonlinearity associated with the hysteresis of magnetostriction provides a detectable sensor signal. Pressure and force, which cause static or quasi-static magnetic fields, as well as vibrations, which induce alternating magnetic fields, can be regarded as direct magnetostrictive sensor responses. In the bending mode, corresponding magnetostrictive absorption can also be sensed via reduction in the Q-factor due to absorption losses in a magnetostrictively tunable system. Shape-Memory Effects-Based Sensors The latest form of sensing technology utilizes shape-memory materials, namely, Nitinol alloys. The Nitinol sensors are used to measure strain and consist of superelastic Nitinol wires. The basic concept is to measure the change in resistance of a Nitinol wire used as an unbalanced arm of a Wheatstone bridge as a function of the strain. The desirable properties of Nitinol in such a sensing application are its high sensitivity and superelastic nature (which permits strains up to 6% to be accurately and repeatedly measured). The piezoelectric and Nitinol sensing materials can also be used for actuation applications. Electromagnetics-Based Sensors Smart electromagnetic sensors are simple deviations of classic electric/magnetic probes, more properly known as antennas or pickups. Depending on changes in the surroundings vis-à-vis the electromagnetic characteristics, these sensors respond and yield a corresponding signal. Again, the environmental changes refer to possible alterations caused by elastic, thermal, optical, magnetic, electric, and/or chemical influences. Electroacoustic Smart Sensors Electroacoustic smart sensors are embedded acoustic (vibration) sensors (similiar to a microphone) that adaptively yield a signal proportional to the acoustic input. Such inputs could result from changes in the alterations in the surroundings caused by elastic or thermal effects