INFRARED SPECTROSCOPY Visible Ultraviolet Infrared M
INFRARED SPECTROSCOPY
Highest energy Lowest energy Wavelength (nm) 10Γ2 10p 102 104 105 108 1010 102 Gamma iUlra- ray X-ray Iviolet Infrared Microwave Radio frequency 1020 108 1016 1014 102 1010 10 105 104 Frequency(s-1) 400 500 600 700 750nm Visible region
Electromagnetic Spectrum Wavelength (A) Energy Molecular effects higher frequency cm kcal/mol shorter wavelength 10-9 gamma rays 106 10-7 X rays 104 ionization vacuum UV 102 10-5 near UV electronic transitions 10-4 visible 10 infrared 10-3 1 molecular vibrations (IR) 10-2 10-1 microwave 10-4 rotational motion 102 lower frequency radio 10-6 104 nuclear spin transitions longer wavelength
Electromagnetic Spectrum
Bond Stretching spring force spring force ○Y000○ equilibrium stretched compressed bond length ○y0000○
Bond Stretching
High Frequency Stretching Low Frequency Bending symmetric stretching antisymmetric stretching bending(scissoring)
High Frequency Stretching Low Frequency Bending
Frequency of Absorption Measured in cm1(Wavenumbers) Wavelength units typically microns (um) 10,000μm=1cmor1μm=10-4cm Frequency units typically measured in cm-1 =waves or cycles in 1 cm (wavenumbers) Mid-Infrared frequency range is 4000-400 cm-] (2.5-25um)
Frequency of Absorption Measured in cm-1 (Wavenumbers) Wavelength units typically microns ( m) 10,000 m = 1 cm or 1m = 10-4 cm Frequency units typically measured in cm-1 = # waves or cycles in 1 cm (wavenumbers) Mid-Infrared frequency range is 4000 - 400 cm-1 (2.5 - 25 m)
High Frequency to Low Frequency wavelength (um) 5.56 910 1213141516 1-butanol CH(CH3OH -O stretch (unreliable) saturated C-H stretch 4000 3500 3000 2500 200018001600140012001000 800 600 wavenumber(cm) Functional Groups Region Fingerprint Region 4000-1400cm-1 1400-600cm-1
High Frequency to Low Frequency Functional Groups Region 4000 - 1400 cm-1 Fingerprint Region 1400-600 cm-1
General Trends: i)Stretching frequencies are higher than corresponding bending frequencies.(It is easier to bend a bond than to stretch or compress it.) ii)Bonds to hydrogen have higher stretching frequencies than those to heavier atoms. iii)Triple bonds have higher stretching frequencies than corresponding double bonds, which in turn have higher frequencies than single bonds.(Except for bonds to hydrogen)
General Trends: i) Stretching frequencies are higher than corresponding bending frequencies. (It is easier to bend a bond than to stretch or compress it.) ii) Bonds to hydrogen have higher stretching frequencies than those to heavier atoms. iii) Triple bonds have higher stretching frequencies than corresponding double bonds, which in turn have higher frequencies than single bonds. (Except for bonds to hydrogen)
TABLE 12-1 Bond Stretching Frequencies Bond Energy Stretching Frequency Bond [kcal (kJ)] (cm-) Frequency dependence on atomic masses C一H 100(420) 3000 C一D heavier 100(420) 2100 decreases C一C atoms 83 (350) 1200↓ Frequency dependence on bond energies C-C 83 (350) 1200 stronger C=C 146 (611) bond 1660 7 increases CC 200 (840) 2200V C-N 73 (305) 1200 C=N 147 (615) 1650 C=N 213 (891) 2200J C-0 86 (360) 1100 C=0 178 (745)↓ 1700↓ Note:In a group of bonds with similar bond energies,the frequency decreases with increasing atomic weight.In a group of bonds between similar atoms,the frequency increases with bond energy.Bond energies and frequencies are approximate
-wavelength(microns)- 2,5 3 8 9 10111213141516 C二N 0-H,N-H C二0 C,N,O ◆-。(C-C.C-0,c-N) = 50084000J60034001200300028002600240020020001900180017001600150014001300120011501001050100095090085080070700650 cm-1 e一frequency()